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11.
Ciucani G Mosbaek H Trapp S 《Environmental science and pollution research international》2004,11(4):267-272
BACKGROUND: Organotins have been used world-wide as antifoulants in ship paints. Repeatedly, severe effects on aquatic species have resulted. The use of organotins for this purpose was ruled out, and dumping of contaminated harbor sludge into the sea was prohibited. Land-based dumping is seen as an alternative. OBJECTIVE: This study investigates sorption, uptake and translocation of tributyltin (TBT) to willow trees in order to evaluate phytoremediation as treatment option. The study considers the influence of pH on the plant uptake of organotins. EXPERIMENTAL SET-UP: Chemicals investigated were the weak base tributyltin chloride (TBTCl) and the neutral tributyltin hydride (TBTH). Organotins were extracted from solution and plant material with toluene, and analyzed as tin by AAS with graphite oven. The pH in solution varied from pH 4 to pH 7. The sorption to living and dead roots, stems and leaves was measured in shaking experiments. The uptake into intact trees was measured at nominal levels of 1 and 10 mg TBT/l for TBTH and TBTCl at low and high pH. RESULTS: The sorption to roots and leaves dropped for dead tissue, but did not vary much with pH. The sorption to stems increased for dead stems and with pH. The solubility of TBTCl in water was below 10 mg/l and lowest at pH 4. Concentrations of TBTCl and TBTH in solutions with trees dropped rapidly to low values. Highest TBT contents in trees were found in roots and lower stems. The concentrations followed the concentrations in solution. The pH had only a small effect on the plant uptake of TBTCl, and no effect on the uptake of TBTH. No effective translocation to higher stems or leaves was found. DISCUSSION: An ion trap mechanism that accumulates the weak base TBTCl in the xylem sap of plants and leads to upward translocation could not be detected. Neither TBTCl at low or high pH, nor the neutral lipophilic chemical TBTH, were translocated effectively to leaves. The TBT+ cation sorbed strongly to plant tissue. The exact mechanism for the strong sorption of the cation is unknown, but similar effects have been observed for algae, liposomes and isolated biomembranes. CONCLUSIONS: Both the uptake of the neutral TBTH and the uptake of the neutral molecule form of TBTCl into willows was as is to be expected from theory. The cation TBT+ showed an unexpected behavior which has been observed before. No ion trap occurs, and the phytoextraction of TBT is not feasible. OUTLOOK: Planting trees, or other appropriate vegetation, could have a beneficial remediation effect by aeration of the TBT-contaminated soil or sludge. In a follow-up paper, the toxicity of TBT to willow trees will be described. 相似文献
12.
Lisbeth M. Ottosen Eduardo Arevalo Heinz Stichnothe Wolfgang Calmano 《Environmental Chemistry Letters》2006,3(4):164-168
Wastewater from wash down of boat hulls contains typically Cu, Zn and organometallic biocides, e.g. tributyltin (TBT). In
some cases this wastewater is led directly into the marine system. In the present paper, a cheap flocculation method (iron
flocculants) for removal of Cu and Zn from the wastewater is investigated and the method was shown successful. TBT concentration
in a sample from a German dockyard was also decreased during flocculation, but the TBT removed was already associated with
small particulates in the original sample. Low concentrations of heavy metals were obtained by flocculation: <0.05 mg Cu/l
and 0.2 mg Zn/l.
An erratum to this article can be found at 相似文献
13.
多壁碳纳米管对三丁基锡的吸附行为及其细胞毒性效应研究 总被引:1,自引:0,他引:1
研究了多壁碳纳米管对三丁基锡(TBT)吸附行为,主要考察了溶液pH和盐度的影响作用.同时比较了无机锡、四丁基锡(TeBT)与三丁基锡在多壁碳纳米管上吸附行为的差异,并探讨了在多壁碳纳米管存在下三丁基锡的细胞毒性作用.研究结果表明多壁碳纳米管对丁基锡具有较强的吸附能力,吸附平衡时问短,能很快达到吸附平衡.溶液pH能影响这种吸附作用.三丁基锡在多壁碳纳米管上的吸附符合Langmuir和Freundlich吸附等温式,主要为疏水作用.在与多壁碳纳米管的共存体系中三丁基锡的细胞毒性效应有所削弱,这可能与多壁碳纳米管对三丁基锡的吸附作用有关. 相似文献
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15.
TBT的污染及控制措施的分析 总被引:5,自引:0,他引:5
综合分析了含TBT船舶防污漆的防污机理及产生危害的原因,概括论述了国际社会对TBT的控制措施以及立法的趋势。 相似文献
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17.
Xu Q Barrios CA Cutright T Newby BM 《Environmental science and pollution research international》2005,12(5):278-284
- Goal, Scope, Background. The traditional solution for keeping unwanted organisms from attaching to submerged surfaces is to
apply anti-fouling coatings. The most common antifoulant was tributyltin (TBT). TBT systems were highly effective but were
also toxic to non-target organisms. The use of the TBT based coatings will be completely banned by January 1, 2008. Therefore,
there is an urgent need to seek out suitable non-toxic alternatives.
Methods The aim of this work was to evaluate the effectiveness of capsaicin and zosteric acid as natural product antifoulants (NPAs)
in deterring bacterial attachment. Two fresh water bacteria systems Pseudomonas putida (Pp) and bacteria isolated from Lake
Erie (LE) were used to assess the attachment when the NPAs dispersed in the water. Effectiveness was ascertained based on
the decrease in microbial attachment, limited toxicity, and minimum alteration of the coatings properties.
Results and Discussion A significant inhibition of bacteria attachment was achieved when aqueous capsaicin concentration was increased from 0 to
40 mg/L. For instance, after 14 days the LE system depicted 93.5% and 98.5% less biofilm coverage for 20 mg/L and 40 mg/L
capsaicin, respectively when compared to systems without NPA. Biofilm coverage was reduced by 92.5% and 98.2%, respectively
with 50 mg/L and 500 mg/L zosteric acid.
Conclusions Both capsaicin and zosteric acid was effective at preventing bacteria attachment. As the NPA aqueous concentration increased,
biofilm formation decreased. Evaluating changes in aqueous pH, conductivity, dissolved oxygen, aqueous microbial population
and biofilm formation suggested that the primary antifoulant mechanism of these two NPAs was to block the bacteria's active
sites versus posing a lethal level.
Recommendation and Perspective From the attachment study, zosteric acid appeared to be more effective in preventing bacterial attachment when the NPAs were
dispersed in the aqueous environment. For practical applications, the antifoulant needs to be incorporated into a coating
and have a slow release rate. Thus the ability to successfully incorporate zosteric acid into a coating, without deterring
bacterial attachment, needs to be investigated. 相似文献
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19.
Kurunthachalam Senthilkumar Carolyn A. Duda Daniel L. Villeneuve Kurunthachalam Kannan Jerzy Falandysz John P. Giesy 《Environmental science and pollution research international》1999,6(4):200-206
Concentrations of mono- (MBT), di- (DBT), and tri-(TBT) butyltin compounds were measured in eggs, liver, and muscle of nine
species of fish from four regions of the Baltic Sea - the Firth of Vistula, the Gulf of Gdańsk, Puck Bay, and the mouth of
the Vistula River. The overall concentration ranges among all the fish sampled from the four sites were: < 7 to 79 ng/g for
MBT, 6 to 1100 ng/g for DBT, 7 to 3600 ng/g for TBT, and 16 to 4800 ng/g for total BTs, on a wet wt basis. The highest concentration
of total BTs was found in herring liver from the Firth of Vistula (4800 ng/g, wet wt) and in roach muscle from Puck Bay (3300
ng/g, wet wt), while the least concentration was found in burbot eggs and liver from the Vistula River (39 and 32 ng/g, wet
wt, respectively). TBT was the major form of BTs present in most samples analyzed. Sediment samples collected from shipyards
in the Gulf of Gdańsk contained butyltin concentrations ranging from 1.2 to 46 μg/g (dry wt) for MBT, 2.0 to 42 μg/g for DBT,
and 2.6 to 40 μg/g for TBT. As with the fish, the majority of the BTs in sediment were present as TBT, which suggested recent
exposure of the aquatic environment of the region to TBT. 相似文献
20.
Biomagnification profiles of tributyltin (TBT) and triphenyltin (TPT) in Japanese coastal food webs elucidated by stable nitrogen isotope ratios 总被引:1,自引:0,他引:1
The measurement of organotins in the various biotas of coastal food webs with stable nitrogen isotope ratios (δ15N), which increase 3.4‰ per trophic level, can provide a biomagnification profile of organotins through food web. In this study, various biological samples were collected from three localities in Western Japan between 2002 and 2003 for analyses. Tributyltin (TBT) and triphenyltin (TPT) were still detected with a maximum of 99.5 and 8.7 ng wet weight g−1, respectively. Unlike TBT, significant biomagnification of TPT through the food web (expressed by δ15N) was found in all three localities. The log transformed octanol–water partition coefficient (log Kow) of TPT of 2.11–3.43 was overlapped by, but was slightly lower than, that of TBT of 3.70–4.70. Thus, this study demonstrates that although these chemicals have a log Kow lower than 5, at least TPT undergoes significant biomagnification through the food web. 相似文献