Determination of PCDDs,PCDFs, PCBs and HCB emissions from the metallurgical sector in Poland

Background The aim of the project was to measure the actual emissions of PCDD/F, PCBs and HCB from 20 selected metallurgical installations in Poland, in order to update the national inventory of dioxin emission from metallurgical industry for developing a strategy for dioxins and furans emission abatement from the subject facilities (UNEP 2005). Methods Sampling methodology used in this work was developed at the Cracow University of Technology because of the complexity of simultaneous sampling and determining PCDFs, PCDDs, PCB and HCB. For the determination a GC-MS/MS system was used. Results and Discussion Results from the work indicate that the highest dioxins and PCB concentrations were recorded for iron ore sintering plants at 1.10–1.32 ng total¹ TEQ/Nm³ followed by aluminium scrap melting at 0.03–0.66 ng total TEQ/Nm³. The highest HCB concentrations at 613–1491 ng/Nm³ were also recorded for iron ore sintering plants, whereas at aluminium plants the HCB concentrations were in the range of only 10.1–22.7 ng/Nm³. Conclusions The above investigations indicate that secondary aluminium production is the most significant dioxins source, if calculated as emission factor values. However, iron ore sintering plants are operating at much higher production capacity, causing this process to become the major source of dioxins, PCB and HCB pollution to the atmosphere in Poland. Recommendations and Perspectives Based on the performed tests and the environmental reviews of selected plants several recommendations were formulated for the reduction of generation or of emission of these pollutants from iron ore sintering plants, electric arc furnace steel production processes, hot-blast furnace operations, secondary aluminium smelting and primary zinc production from zinc cathodes.     

交叉口机动车尾气污染扩散模型综述

文章介绍了美国主要的交叉口尾气污染扩散模型,并对模型进行了比较评价,探讨了传统交叉口扩散模型的缺陷;介绍了国内外交叉口尾气扩散研究的最新发展动态,最后提出了提高模型精度和发展新模型的几点建议。     

广西重点行业二氧化碳减排潜力分析

为加快CDM项目的开发,以广西为试点,采用自下而上的方法针对其重点行业的二氧化碳减排潜力进行评价,具体地包括:高耗能工业(冶金、有色金属、建材、化工、制糖、造纸等)、电力(火电、水电、风电)、户用沼气池、木薯制燃料酒精、有机废液利用等。结果表明到2010年广西上述领域的碳减排潜力(以碳计)可达1623万t。为促进广西的可持续发展,不仅应在水电、风电、提高能效等已有方法学的领域积极开展CDM项目,还应加强其它领域如木薯制燃料酒精、户用沼气池等CDM方法学以及CDM项目的开发。     

速度场常数及其自动检测装置

通过对烟道“速度场常数”的研究,提出利用速度场常数监测烟道烟气平均流速的方法,同时研制出速度场常数自动检测装置。解决烟道烟气平均流速自动监测的技术难题。     

生物柴油发动机颗粒排放物粒径及其分布试验研究

为获取燃用不同比例生物柴油的发动机排放颗粒物粒径及其分布特性,对1台增压直喷式车用柴油机进行了台架测试.用80 L/min定量泵和装有直径90 mm的玻纤滤膜采样器在排气管内采样10 min,用激光粒度仪测量与分析颗粒粒径和分布.结果表明,随着发动机转速提高,排放颗粒粒径变小且分布更集中.干法众数对应的粒径级较大（约10～12 μm）且较集中,湿法众数的较小（约4～10 μm）且分散.用干法分析,发动机低速时,B100的Sauter平均直径d₃₂最大,纯柴油最小,而B20的结果介于二者之间.而高速时B20的粒径最大,纯柴油次之,B100最小.中数粒径d(0.5)的结果也反映这一趋势.用湿法分析,除了2?000 r/min点外, B20的d₃₂最大,B100次之,柴油最小.湿法众数比干法分散,因而d₃₂也较大.     

Relationships of nitrous oxide fluxes with water quality parameters in free water surface constructed wetlands

The effects of chemical oxygen demand (COD) concentration in the influent on nitrous oxide (N₂O) emissions, together with the relationships between N₂O and water quality parameters in free water surface constructed wetlands, were investigated with laboratoryscale systems. N₂O emission and purification performance of wastewater were very strongly dependent on COD concentration in the influent, and the total N₂O emission in the system with middle COD influent concentration was the least. The relationships between N₂O and the chemical and physical water quality variables were studied by using principal component scores in multiple linear regression analysis to predict N₂O flux. The multiple linear regression model against principal components indicated that different water parameters affected N₂O flux with different COD concentrations in the influent, but nitrate nitrogen affected N₂O flux in all systems.     

我国“十二五”期间推进清洁生产工作的思考

在末端治理日臻完善的时代,清洁生产是人类污染治理方式和生产力发展方式上的一次革命。我国推行清洁生产已有10余年,但进展较缓慢。本文在阐释清洁生产内涵的基础上分析了我国在推行清洁生产过程中存在的部分问题及其原因,提出了相应的对策和建议。     

关于推进三明市节能减排的对策建议

我国上世纪五、六十年代新兴的工业城市,工业结构大多以重化工业为主,节能减排任务十分艰巨。本文选择福建省三明市这一极具有代表性的地方工业城市进行调研剖析,阐述了三明市当前节能减排的形势与任务,分析了在推进节能减排工作中存在的主要问题,并提出了应对措施和建议。     

关于排污权的一级市场和二级市场问题

在分析建立和完善排污权市场机制必要性的基础上,提出了排污权一级市场和二级市场的概念,阐述了参与主体不同、实施手段不同、风险大小不同和作用效果不同是一级市场与二级市场的主要区别;指出排污权一级市场需要解决的核心是公平问题,二级市场需要解决的核心是效率问题,并提出了保证排污权一级市场的公平性和提高二级市场效率的若干重要措施.这对于当前我国实施排污权有偿取得与排污交易,建立排污权市场机制具有重要借鉴意义.     

我国排污权交易落实的现实要求及有效性分析

从排污权基本概念出发，在分析我国进行排污权交易必要性的基础上，提出进行交易还存在的问题，并给出相应的建议。