饮用水源中三卤甲烷含量及与遗传毒性的相关性研究

通过对某市饮用水源中不同点位的三卤甲烷浓度测试,同时采用SOS/ Umu 试验对水体进行生物遗传毒性分析,结果表明:采用液氯消毒工艺的地表水厂在消毒后水样和用户端水样中检出的三卤甲烷含量较高,而采用二氧化氯消毒的地下水厂的出水中挥发性有机物仅略有上升;进行三卤甲烷浓度和生物遗传毒性之间的相关性分析得知,三卤甲烷和间接遗传毒性的相关性较好.     

离子强度、pH值和Ca2+/Al3+对马尾松幼苗的铝毒影响

测定了在不同溶液酸度、不同离子强度和Ca~(2+)/Al~(3+)比下,铝对马尾松幼苗生长状况的影响。结果表明,溶液酸度增加,离子强度减小时,铝的毒害作用增大。钙对铝毒有明显缓解作用,当Ca~(2+)/Al~(3+)增大时,铝的毒性减小,但其缓解作用与铝浓度有关,当铝浓度增加,钙的缓解能力下降。     

微絮凝双层滤料过滤处理含油废水试验研究

针对机电和机械加工行业排水中含油废水的特性 ,提出了微絮凝双层滤料过滤法处理工艺。通过实验 ,肯定了其良好的除油效果 ,并对影响除油率的因素进行了分析讨论 ,确定了处理工艺流程及合理的设计参数     

Effects of simulated acid rain on cation release in soils of South China

This paper deals with the release of base cations and Al3+ at the treatment with simulated acid rain (SAR) in main soil types collected from South China. Results showed that the amounts of base cations increased obviously when the pH value of simulated acid rain was lower than 3.0 or 3.5. Compared with the leaching of K+ and Na+, the leaching of Ca2+ and Mg2+ was affected by the pH value of SAR. Only when the amounts of base cations leached from soils exceeded the cation exchange capacity, the pH value of leaching solutions decreased sharply and the amounts of released Al3+ increased. The H+ buffering mechanisms, which were affected notonly by the pH values of SAR, but also by the types and solid components of soils, were proposed for the main soils studied.     

Efficient degradation of organic pollutants by S-NaTaO3/biochar under visible light and the photocatalytic performance of a permonosulfate-based dual-effect catalytic system

Removing large concentrations of organic pollutants from water efficiently and quickly under visible light is essential to developing photocatalytic technology and improving solar energy efficiency. This study used a simple hydrothermal method to prepare a non-metallic, S-doped NaTaO₃ (S-NTO) photocatalyst, which was then loaded onto biochar (BC) to form a S-NTO/BC composite photocatalyst. After uniform loading onto BC, the S-NTO particles transformed from cubic to spherical. The photogenerated electron-hole pair recombination probability of the composite photocatalyst was significantly lower than those of the NTO particles. The light absorption range of the catalyst was effectively widened from 310 nm UV region to visible region. In addition, a dual-effect catalytic system was constructed by introducing peroxymonosulfate (PMS) into the environment of the pollution to be degraded. The Rhodamine B, Methyl Orange, Acid Orange 7, tetracycline, and ciprofloxacin degradation efficiency at 40 mg/L reached 99.6%, 99.2%, 84.5%, 67.1%, and 70.7%, respectively, after irradiation by a 40 W lamps for 90 min. The high-efficiency visible-light catalytic activity of the dual-effect catalytic system was attributed to doping with non-metallic sulfur and loading of catalysts onto BC. The development of this dual-effect catalytic system provides new ideas for quickly and efficiently solving the problem of high-concentration organic pollution in aqueous environments, rationally and fully utilizing solar energy, and expanding the application of photocatalytic technology to practice.     

In-situ-reduced synthesis of cyano group modified g-C3N4/CaCO3 composite with highly enhanced photocatalytic activity for nicotine elimination

Graphite carbon nitride has many excellent properties as a two-dimensional semiconductor material so that it has a wide application prospect in the field of photocatalysis. However, the traditional problems such as high recombination rate of photogenerated carriers limit its application. In this work, we introduce nitrogen deficiency into g-C₃N₄ to solve this problem a simple and safe in-situ reduction method. g-C₃N₄/CaCO₃ was obtained by a simple and safe one-step calcination method with industrial-grade micron particles CaCO₃. Cyano group modification was in-situ reduced during the thermal polymerization process, which would change the internal electronic structure of g-C₃N₄. The successful combination of g-C₃N₄ and CaCO₃ and the introduction of cyanide have been proved by Fourier transform infrared spectroscopy and X-ray photoelectron spectrometer. The formation of the cyano group, an electron-absorbing group, promotes the effective separation of photogenic electron hole pairs and inhibits the recombination of photogenic carriers. These advantages result in the generation of more •O₂⁻ and ¹O₂ in the catalytic system, which increases the photocatalytic efficiency of nicotine degradation by ten times. Furthermore, the degradation process of nicotine has been studied in this work to provide a basis for the degradation of nicotine organic pollutants in the air.     

清洁的胡椒基T醚生产工艺的研究I,5-丙基-1,3-苯并二氧杂茂的氯甲基化废水的处理

报道了胡椒基丁醚生产中５－丙基－１，３－苯并二氧杂茂的氯甲基化的废水处理，该废水经蒸馏可回收９４％的盐酸，此酸吸收氯化氢后浓度在３６％以上，可再用于氯甲基化反应。蒸馏残液经分油、Ｆｅｎｔｏｎ试剂处理和五次生炭柱吸附后ＣＯＤＣｒ等项指标均可国家二类污染物的一级排放标准。     

Upgrading of organic waste: production of the copolymer poly-3-hydroxybutyrate-co-valerate by Ralstonia eutrophus with organic waste as sole carbon source

Two types of fermented organic waste (trade and industry waste and fruit and vegetable waste) were successfully used as a sole carbon source to produce poly-3-hydroxybutyrate-co-valerate (PHBV) by Ralstonia eutrophus (formerly Alcaligenes eutrophus) via oxygen limitation.The production of PHBV could be optimized by optimizing the oxygen transfer through the fermentor. Thereby, a peak concentration of 1.1 g PHBV per liter cell suspension, 40 w% of cell dry weight, was obtained at an aeration rate of 0.24 mol O₂/h·kg biomass. The yield of PHBV on the fatty acid concentration in the organic waste was 0.16 g polymer/g volatile organic matter. The process obtained, compares well with the commercial production process of PHBV based on glucose.     

Effects of lead , cadmium , mercury chlorides and aquaticenvironmental samples on the growth of Escherichia coli

In this paper it was reported that PbCl₂ , CdCl₂ , HgCl₂, and aquatic environmental samples containing Al, Cd, Cu, Pb, Sr, Zn and other heavy metal ions as well as organic chemicals suppressed thegrowth of E. coli only at higher exposed concentrations. The stimulative effects of PbCl₂ and HgCl₂ on thegrowth of E. coli were clearly showed at lower concentrations and longer time. It suggested that the toxic effects of heavy metal ions and other pollutants on the growth of E. coli are variable according to the differentexposed levels.     

县域生态功能区划研究——以桐柏县为例

结合桐柏县的实例,对县域生态功能区划分的原则和方法进行初步探讨.综合利用3S技术对县域生态敏感性和生态服务功能重要性的分析和评价,提出桐柏县生态服务功能区划的初步方案.将桐柏县划分为生态支持区,产品供给区,生态调节区.简要分析了各功能区在桐柏县经济可持续发展中的地位和作用,指出各区协调发展的方向和途征.