全文获取类型
收费全文 | 1981篇 |
免费 | 331篇 |
国内免费 | 1081篇 |
专业分类
安全科学 | 130篇 |
废物处理 | 99篇 |
环保管理 | 134篇 |
综合类 | 1977篇 |
基础理论 | 513篇 |
污染及防治 | 420篇 |
评价与监测 | 77篇 |
社会与环境 | 32篇 |
灾害及防治 | 11篇 |
出版年
2024年 | 6篇 |
2023年 | 29篇 |
2022年 | 82篇 |
2021年 | 123篇 |
2020年 | 81篇 |
2019年 | 117篇 |
2018年 | 191篇 |
2017年 | 105篇 |
2016年 | 122篇 |
2015年 | 122篇 |
2014年 | 143篇 |
2013年 | 179篇 |
2012年 | 229篇 |
2011年 | 247篇 |
2010年 | 168篇 |
2009年 | 209篇 |
2008年 | 155篇 |
2007年 | 158篇 |
2006年 | 144篇 |
2005年 | 106篇 |
2004年 | 89篇 |
2003年 | 101篇 |
2002年 | 80篇 |
2001年 | 80篇 |
2000年 | 67篇 |
1999年 | 60篇 |
1998年 | 31篇 |
1997年 | 29篇 |
1996年 | 23篇 |
1995年 | 37篇 |
1994年 | 20篇 |
1993年 | 19篇 |
1992年 | 10篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 4篇 |
1982年 | 4篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1978年 | 1篇 |
排序方式: 共有3393条查询结果,搜索用时 764 毫秒
341.
342.
Minh TB Watanabe M Tanabe S Miyazaki N Jefferson TA Prudente MS Subramanian A Karuppiah S 《Environmental pollution (Barking, Essex : 1987)》2000,110(3):735-468
For understanding global distribution, transport and behavior of tris(4-chlorophenyl)methane (TCPMe) and tris(4-chlorophenyl)methanol (TCPMOH), the two newly identified microcontaminants, the present study determined their concentrations and other persistent organochlorines (OCs) in the blubber of nine species of adult male cetaceans collected from various locations in the North Pacific Ocean and coastal waters of some Asian countries, during 1985-97. Concentrations of TCPMe and TCPMOH were found to be highest in northern right whale dolphins, which may be attributable to wide distribution of this species, including some heavily polluted areas such as coastal California. Elevated residue levels of TCPMe and TCPMOH were observed in both off-shore and coastal species, suggesting widespread contamination of these compounds in the marine environment. Higher contamination of TCPMe and TCPMOH was found in cetaceans from temperate and cold waters than those from tropical regions. The latitudinal distribution of TCPMe and TCPMOH in cetaceans from the North Pacific and Asian coastal waters was similar to that of DDTs, suggesting less transportable nature of TCPMe and TCPMOH in the marine environment. Data on the occurrence of TCPMe and TCPMOH further indicated high bioaccumulation potential of these compounds, which was comparable to DDTs. Relative concentrations of TCPMe/TCPMOH in cetaceans were apparently higher than those observed in seals, suggestive of lower metabolic capacity for these compounds in cetaceans than in pinnipeds, which is similar to classic contaminants like polychlorinated biphenyls and DDTs. 相似文献
343.
Baseline study of methane emission from open digesting tanks of palm oil mill effluent treatment 总被引:1,自引:0,他引:1
Anthropogenic release of greenhouse gases, especially CO2 and CH4 has been recognized as one of the main causes of global warming. Several measures under the Kyoto Protocol 1997 have been drawn up to reduce the greenhouse gases emission. One of the measures is Clean Development Mechanisms (CDM) that was created to enable developed countries to cooperate with developing countries in emission reduction activities. In Malaysia, palm oil industry particularly from palm oil mill effluent (POME) anaerobic treatment has been identified as an important source of CH4. However, there is no study to quantify the actual CH4 emission from the commercial scale wastewater treatment facility. Hence, this paper shall address the CH4 emission from the open digesting tanks in Felda Serting Hilir Palm Oil Mill. CH4 emission pattern was recorded for 52 weeks from 3600 m3 open digesting tanks. The findings indicated that the CH4 content was between 13.5% and 49.0% which was lower than the value of 65% reported earlier. The biogas flow rate ranged between 0.8 l min−1 m−2 and 9.8 l min−1 m−2. Total CH4 emission per open digesting tank was 518.9 kg day−1. Relationships between CH4 emission and total carbon removal and POME discharged were also discussed. Fluctuation of biogas production was observed throughout the studies as a result of seasonal oil palm cropping, mill activities, variation of POME quality and quantity discharged from the mill. Thus only through long-term field measurement CH4 emission can be accurately estimated. 相似文献
344.
Studies were carried out to investigate the metabolism of herbicide chlortoluron in the microsomal fractions and whole cells of Saccharomyces cerevisiae expressing human cytochrome P450 3A4. Both whole cells and microsomal fractions of yeast expressing human cytochrome P450 3A4 exhibited a typical dithionite-reduced, CO-difference absorbance spectrum with maximum absorbance at 448 nm. Chlortoluron produced a type I binding spectrum with cytochrome P450 3A4 with a Ks value of 200 μM. Chlortoluron was metabolised into four metabolites; hydroxylated-N-monodemethylated, hydroxylated ring methylated, N-didemethylated and N-monodemethylated products. Chlortoluron metabolism was absolutely dependent on NADPH and no metabolism was observed in control transformants. 相似文献
345.
Yoshitaka Yonezawa Manabu Fukui Shigeki Masunaga Yoshikuni Urushigawa 《Chemosphere》1994,28(12):2179-2184
The relation between dechlorination activities of 1,2,4-trichlorobenzene and anaerobic microbial activity were studied in the sediment collected at three sites in Ise Bay in Japan. The degradation rate of spiked 1,2,4-trichlorobenzene (3nmol ml−1) ranged from 15 to 35 pmol day−1 ml−1 wet sediment and about 1/3 to 1/2 of degraded the trichlorobenzene was recovered as dechlorinated products. Among the dichlorobenzenes, the 1,2-isomer had the highest and 1,3-isomer had the lowest production rate. Comparing the three sampling sites, the trichlorobenzene degradation and dichlorobenzenes production rates were related to the sulfate reducing activity for the unit number of sulfate reducing bacteria. Production rates of dichlorobenzenes were completely inhibited by adding molybdate (20 mM), nitrate (60 mM), and formaldehyde solution (4 %). These results indicated that dechlorination activity in the Ise Bay sediment was supported by sulfate reduction activity in the sediment, and not supported by any other anaerobic microbial activity. 相似文献
346.
347.
Biodegradation of 2,4,6-trichlorophenol in the presence of primary substrate by immobilized pure culture bacteria 总被引:8,自引:0,他引:8
In this study, pure strains that are capable of utilizing 2,4,6-trichlorophenol have been isolated from the mixed culture grown on substrates containing chlorophenolic compounds. Studies have been carried out on the capability of these isolated pure strains in suspended and immobilized forms to decompose 2,4,6-trichlorophenol. Additionally, the influence of primary substrates (e.g., phenol, 2-chlorophenol, 3-chlorophenol, 4-chlorophenol, 2,4-dichlorophenol) on the decomposition of 2,4,6-trichlorophenol by the isolated pure strains grown in immobilized form is also investigated. The results are: Through bacterial isolation and identification, three pure strains have been obtained: Pseudomonas spp. strain 01, Pseudomonas spp. strain 02 and Agrobacterium spp. Whether in suspended or immobilized forms, all strains have poor removal efficiencies of 2,4,6-trichlorophenol. However, addition of 200 mg/l phenol will enable the immobilized Pseudomonas spp. strain 01, and Pseudomonas spp. strain 02 to achieve 65% and 48% removal of 2,4,6-trichlorophenol, respectively. Addition of phenol will assist the immobilized Pseudomonas spp. strain 02 in achieving removal of 2,4,6-trichlorophenol but the removal efficiency is not good if the phenol concentration is too low. The optimum phenol concentration should be between 200 and 400 mg/l. 相似文献
348.
The estrogenic pollutants 4-tert-octylphenol (OP), 4-nonylphenol (NP) and bisphenol A (BPA) were determined in surface water samples from the Haihe River, Tianjin, China. The analytes were extracted and concentrated from 300 ml acidified water samples by liquid–liquid extractions using dichloromethane, derivatized with trifluoroacetic anhydride, and quantified by gas chromatography–mass spectrometry (GC–MS) with selected ion monitoring (SIM). Among the samples collected from 14 sampling sites, only one sample was found to have a relatively high concentration of BPA (8.30 μg l−1) and NP (0.55 μg l−1). The concentrations of OP, NP and BPA in the other samples were in the range of 18.0–20.2, 106–296 and 19.1–106 ng l−1, respectively. Recoveries for OP, NP and BPA in the spiked water samples were all over 80%. 相似文献
349.
The fluorescence spectroscopic behavior of bromadiolone (anticoagulant rodenticide), a substituted 4-hydroxycoumarin derivative, was investigated in water and in organized media like micelles and cyclodextrins. A detailed study on various photophysical parameters like fluorescence intensity (IF), quantum yield (), lifetime (τ) and steady state fluorescence anisotropy (r) of bromadiolone in aqueous and in organized media was carried out. Bromadiolone in aqueous solution was observed to be in an aggregated state, thereby showing weak emission due to self-quenching. Marked enhancement of fluorescence intensity was observed in organized media like micelles and β-cyclodextrin. A preliminary investigation has been done to find out whether this enhancement of fluorescence can be used to develop a sensitive analytical method for determination of bromadialone in aqueous media. A linear relationship between the fluorescence intensity and concentration of bromadiolone was observed in the range of 0.15–7.9 μg ml−1 in cetyltrimethylammonium bromide (CTAB) and 0.5–26.4 μg ml−1 in β-cyclodextrin medium. The lower detection limit was found to be 37 ng ml−1 in presence of CTAB and 23 ng ml−1 in β-cyclodextrin. Comparison with 4-hydroxycoumarin, an unsubstituted analogue, was made. 相似文献
350.
利用最新的AIRS卫星观测资料分析了2002年12月~2016年11月全球和东亚地区(70°~140°E,10°~55°N)CH4浓度的时空变化分布特征.研究发现,2003~2016年,全球CH4年平均浓度从1774.2×10-9增加到1789.1×10-9,年增长率约为1.1×10-9/a;东亚地区CH4年平均浓度从1811.5×10-9增加到1841.0×10-9,年增长率约为2.0×10-9/a.在美国西南部、南美洲南部、澳大利亚东南部、中国青藏高原和东北地区等地上空,CH4浓度增幅比较明显,而在北美洲的东北部上空,CH4浓度出现负增长.北美洲东北部和俄罗斯东部等地上空CH4浓度的变化与温度变化呈正相关;如在冬季,该地区温度与周围地区相比更低,同时CH4浓度更低.本文利用近10a的卫星数据获得了CH4浓度的垂直廓线,显示不同纬度带CH4浓度均随着高度的升高逐渐减小,且高纬度地区CH4浓度减小的最快.近年来,在低纬度地区对流层中低层CH4浓度变化较为明显.在对流层低层(850hPa),北半球CH4浓度随着纬度增加逐渐变大;在南半球则随着纬度增加先减小后变大.而在平流层内,CH4浓度在赤道处最大,且随着纬度的升高逐渐减小.此外,CH4的浓度分布存在明显的季节变化:在北半球,大部分地区夏季CH4浓度高于冬季(约20×10-9~40×10-9),但在撒哈拉沙漠和中国新疆塔里木盆地等地区上空,冬季CH4浓度高于夏季(约40×10-9~60×10?9).在冬季,中国四川西部上空的CH4浓度要比青藏高原上空高(约100×10-9~120×10-9). 相似文献