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In order to evaluate the ecological hazard of 4-tert-butylphenol (4-TBP), species abundances and physicochemical properties were monitored for 63 days in a microcosm system containing planktonic algae, rotifers, shrimps and Daphnia. The 63 days-NOEC (no observed effect concentration) of 4-TBP for this system was calculated. At the same time, species sensitivity distribution curves were constructed based on the toxicity data of EC10, EC50 and NOEC derived from laboratory single-species toxicity tests, which further gives no obvious hazard concentrations for 95% species in the ecosystem (HC5). In both the microcosm and the single-species tests, the shrimp (Neocaridina sp.) was the most sensitive species to 4-TBP exposure, while most algae species were relatively insensitive compared to the zooplankton. For the microcosm exposed to 4-TBP, significant changes occurred to the community structure instead of the community function, resulting in a NOECmicrocosm of 265.38?μg?L–1 which approached the EC10-based HC5 (0.376?mg?L–1). Nevertheless, EC50-based HC5 was higher than the NOECmicrocosm, and the NOEC-based HC5 was lower. The data showed that the EC10-based HC5 was protective at the similar level with the result of microcosm for 4-TBP, providing supportive data for chemical risk assessment. 相似文献
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To overcome adoption barriers and promote battery electric vehicles (BEVs) as an energy efficient consumer transportation option, a number of states offer subsidies to consumers for BEVs. We use a national data set of vehicle registrations and state-level financial incentives to assess the impact of vehicle purchase subsidies on adoption using both difference-in-differences and synthetic controls methods. We find that incentives offered as direct purchase rebates generate increased levels of new BEV registrations at a rate of approximately 8 percent per thousand dollars of incentive offered. Between 2011 and 2015, vehicle rebate incentives are associated with an increase in overall BEV registrations of approximately 11 percent. Our findings indicate incentives offered as state income tax credits do not have a statistically significant effect on BEV adoptions, though we caution this may be a result of limited temporal variation in BEV incentives across our sample. Responses to rebate incentives do not differ significantly by the make of the vehicle purchased (i.e., Tesla and non-Tesla vehicles). We combine our results with recent assessments of marginal environmental costs of electric vehicle charging and measure net welfare effects of BEV subsidy programs. Our analysis indicates these programs are not welfare-improving if only considering benefits associated with avoided emissions. Additional benefits associated with long-term market growth, production cost savings, network externalities, or accelerated innovation could substantially impact the net welfare outcomes. 相似文献
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2-氯联苯与4-氯联苯的超声降解研究 总被引:3,自引:0,他引:3
以 2 氯联苯 ( 2CB)与 4 氯联苯 ( 4CB)为对象 ,研究了污染物结构对超声降解的影响 .在 2 0kHz,30 8W·cm- 2 的超声波作用下 ,2CB与 4CB的准一级降解速率常数分别达到 0 1 2 8min- 1 和 0 0 98min- 1 .其反应速率的差异来自不同取代基位置导致的挥发性之差 .在 95 %的母体去除后 ,~ 80 %的有机氯转化成无机氯离子 . 1h后 2CB与 4CB溶液的TOC去除率分别达到 40 %和 35 % . 相似文献
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菌株NKS-3对溴氨酸脱色特性探讨 总被引:12,自引:1,他引:11
从受溴氨酸污染地筛选出菌株NKS- 3 ,它对溴氨酸有脱色作用。菌株生长随碳源浓度增加而旺盛,溴氨酸能刺激菌株生长。溴氨酸浓度即使达到1000 mg/L 也能被菌株基本脱色。研究发现,盐度抑制菌生长,在含盐培养液中溴氨酸的脱色过程被抑制 相似文献
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利用石墨电极进行了多种条件下对氯苯酚水溶液的电解研究。研究结果表明,CODCr去除率和脱氯率随电压的升高呈先升高后下降的趋势、随对氯苯酚质量浓度的升高呈指数下降、随溶液pH的升高而升高。碱性条件下电解效果明显优于中性和酸性条件。在电压为10V,pH≈12,电解100mg L的对氯苯酚溶液2h后,CODCr去除率可达52 94%,脱氯率达52 8%。由脉冲辐解瞬态吸收光谱可知,中性、酸性条件下降解机制均为OH·自由基的作用,经过瞬态分子OH-adducts(OH加合物)的中间产物进一步氧化降解;碱性条件下通过OH·自由基和对氯苯酚氧基负离子的阳极直接失电子氧化作用2种降解机制,经过瞬态分子氯代酚氧自由基中间产物氧化降解对氯苯酚,产物分析结果显示生成了对苯二酚和苯醌等中间产物。 相似文献