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451.
In this study, selective methods were developed for isolation, purification, separation and determination of 4-nonylphenol (4NP) in biological samples. Several methods such as high-performance liquid chromatography (HPLC) with fluorescence and diode array detection and gas chromatography coupled to mass spectromotry (GC-MS) are described for the simultaneous determination of 4NP. The nonylphenols in the plasma of fish were extracted through solid phase process by using octadecyl, polymeric and octadecyl endcapping sorbents. The average recoveries in plasma samples spiked with 4NP of levels 1?µg?mL?1 were between 80–95% using added surrogate standards. The aim of this study was to determine whether trace amounts of 4NP in fish plasma samples could be detected by solid phase extraction and chromatographic methods (HPLC, GC-MS). This technique of monitoring the levels of endocrine-disruptors in plasma samples is consistent, reliable as well as inexpensive. 相似文献
452.
In this study, we investigated the effects of Matricaria chamomilla L. extract (MCE) on lipid peroxidation, antioxidant enzyme systems, and several liver enzymes in carbon tetrachloride (CCl4)-treated rats. Rats were divided into five groups. The first group (control group) was fed on standard feed. The rats in the other groups (CCl4, MCE50, MCE100, and MCE200) were injected intraperitoneally with 0.8?mL?kg?1 CCl4. Moreover, rats in the MCE50, MCE100, and MCE200 groups were gavaged with 50?mg?kg?1, 100?mg?kg?1, and 200?mg?kg?1 MCE, respectively. Serum aspartate aminotransferase (AST) and alanine aminotransferase (ALT) levels, whole blood malondialdehyde (MDA) and glutathione (GSH) levels, and erythrocyte superoxide dismutase (SOD), glutathione peroxidase (GPx), and catalase (CAT) activity levels were measured after 14 days of exposure. ALT and AST in the CCl4 group increased significantly in comparison to the control group (p?0.001). MCE decreased MDA levels and increased GSH, SOD, and GPx activities. Decreases were observed in CAT activity levels in the CCl4, MCE50, MCE100, and MCE200 groups at different significance levels. In conclusion, the findings suggest that, depending on the dose administered, MCE decreases CCl4-induced damage and consequent oxidative stress in rats; it affects the antioxidant system positively. 相似文献
453.
P. Van Der Sluis G. W. H. Moes H. Behm C. Smykalla P. T. Beurskens A. T. H. Lenstra 《毒物与环境化学》2013,95(2-3):121-127
A method for the preparation of single crystals of PCB 35 suitable for single crystal X‐ray structure determination was developed. This method has already been proven suitable for 2,4'‐dichlorobiphenyl and may prove useful for other PCBs or related compounds. The crystals of PCB 35 are orthorhombic, spacegroup P21221 (a= 10.665(8), 6 = 3.825(3), c= 14.086(9) Å) and the structure was refined to R = 0.094 for 156 unique observed reflections and 43 parameters. Although the crystals were of poor quality, the structure determination unequivocally confirmed the substitution pattern of the biphenyl moiety by Cl atoms inferred previously from spectroscopic methods. The dihedral angle between the planes of the two phenyl rings is 33(2)°. 相似文献
454.
455.
Abstract Distributions of 210Pb and 7Be in the aerosol particles of different size fractions were measured around Taiwan offshore areas from October, 1994 to October, 1995. the size distribution and abundance of the aerosol particles showed both spatial and temporal variations. the particle concentrations off northwestern Taiwan were more than twice as those off northeastern Taiwan both in November and March, and the values were much higher in November than in March for both areas. the measured particle concentrations, except for one sample with an unusually high value, ranged from 10 to 83 μOgm ?3 in the study areas. the 210Pb concentrations in the aerosol particles filtered from the air mass varied between 20 × 10?3 and 72 × 10?3 dpm m?3 (1dpm = 0.45 pCi). the 210Pb concentrations in the area off southwestern Taiwan appeared somewhat higher than in other areas and were probably contributed by the land air from Taiwan which contains higher 210Pb in winter. the 210Pb concentrations off northern Taiwan were low in November when the aerosol concentrations were high, but they were high in March when the aerosol concentrations were low. Based on the 7Be monitoring records of 20 years on the aerosol particles of the island by the Taiwan Radiation Monitoring Center, the mean settling rate averaged 0.91, 0.79 and 0.68 cm s?1, respectively, in northern, central and southern Taiwan. with these values and the 210Pb concentrations in the aerosols, the 210Pb flux was determined to be between 0.58 and 2.30 dpm cm?2y?1, with an average of 1.19 dpm cm?2y?1. Excluding the highest value due to its extremely high 210Pb and aerosol concentrations, the average is reduced to 1.05 dpm cm?2y?1. the activity median diameters (AMD) for 210Pb in the study areas were between 0.69 and < 0.49 μM with a mean of 0.5 öm based on 210Pb distributions in different particle size fractions. Thus, 210Pb was preferentially adsorbed on to the submicron particles. 7Be in the study areas showed a good correlation with 210Pb in total activity although the two nucides had different sources. 相似文献
456.
S. V. Raman Rao B. Padmavathi K. Sathyavelu Reddy K. Indira 《Chemistry and Ecology》2013,29(4):207-212
Exposure of a freshwater teleost, Sarotherodon mossambicus, to a sublethal concentration (26 ppm) of carbon tetrachloride for periods up to 30 days led to significant changes in the soluble protein fractions (albumin and globulins) and free amino acid content. the decrease in total protein content was greater in liver than in muscle. the protein loss was expected due to the impairement of protein synthetic activity during stress conditions. 相似文献
457.
The thermodynamic equilibrium of the C‐H‐O‐Cl system has been calculated to elucidate the generation and decomposition behavior of dioxins, and is discussed from the viewpoint of the oxygen and hydrogen chloride potential. The dioxins behavior is greatly dependent on the oxygen potential, i.e. higher temperature and oxygen potential lead to the complete decomposition of dioxins, while low hydrogen chloride potential under insufficient oxygen condition leads to an increase of multi‐chlorine displacement of dioxins. 相似文献
458.
湿地生态系统对全球碳平衡和气候变化起着极其重要的作用,而水位波动将影响湿地生物地球化学过程,导致温室气体通量变化,为了明确湿地生态系统温室气体通量以及土壤微生物活性对水位梯度的生态响应,通过野外盆栽培养试验,设T1:-5 cm,T2:0 cm,T3:5 cm,T4:10 cm 4种水位梯度,T1和T2模拟湿地非淹水的水分状况,T3和T4模拟淹水状况,研究了不同水位梯度下小叶章(Calamagrostis angustifolia)湿地CO2、CH4通量、土壤微生物量碳、氮及土壤酶活性的变化规律.结果表明:不同水位条件下,小叶章湿地系统CO2和CH4通量差异较大,-5 cm水位时小叶章湿地CO2通量为(643.35±61.89) mg·m-2·h -1,随着水位增加,CO2通量依次降低6.9%、12.1%、40.0%,且水位升高到10 cm时,小叶章湿地CO2排放量显著降低(P<0.05);而CH4通量则随水位增加呈显著增加趋势,通量变化为(1.52±0.12)~(5.34±0.61) mg·m-2·h-1;水位对微生物活性影响显著,非淹水条件下小叶章湿地土壤微生物量碳、氮含量以及土壤蔗糖酶、淀粉酶活性高于淹水土壤,且随着淹水位增加,微生物活性显著降低. 相似文献
459.
Xue BAI Hanchang SHI Zhengfang YE Qiujin SUN Qing WANG Zhongyou WANG 《Frontiers of Environmental Science & Engineering》2013,7(6):844-850
In this study, microorganisms (named B111) were immobilized on polyvinyl alcohol microspheres prepared by the inverse suspension crosslinked method. The biodegradation of bisphenol A (BPA) and 4-hydro- xybenzaldehyde, a degradation product of BPA, by free and immobilized B lll was investigated. The BPA degradation studies were carried out at initial BPA concentrations ranging from 25 to 150 mg·L^-1. The affinity constant Ks and maximum degradation rate Rmax were 98.3 mg·L^-1 and 19.7mg·mg^-1VSS·d^-1 for free B111, as well as 87.2mg·L^-1 and 21.1mg·mg^-1VSS·d^-1 for immobilized B 111, respectively. 16S rDNA gene sequence analyses confirmed that the dominant genera were Pseudomonas and Brevundimonas for BPA biodegradation in microorganisms B 111. 相似文献
460.