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861.
Arkian F Salahinejad M Bidokhti AA Meshkatee A 《Environmental monitoring and assessment》2008,140(1-3):325-330
Measurement of gross α, gross β activities and cosmogenic beryllium-7 (7Be) concentrations were made both daily and weekly during the years 2001–2004 from samples of atmospheric aerosols filtered
from the air at Tehran Nuclear Research Center (35 41′ N) and Zahedan (28 29′ N). Weekly aerosol samples collected with the
high-volume air samplers on cellulose filters were used to determine the 7Be contents of samples, using a semiconductor gamma spectrometer. Airborne dust samples were collected daily on fiber glass
filters and used to determine the gross β and gross α activities with automatic beta analyzer and a ZnS(Ag) counter, respectively.
In this work, the concentration and meteorological data were used to determine models for gross α, gross β and 7Be. The air concentrations of gross β and gross α activities and 7Be concentrations displayed lognormal distributions during the study period. Both β and 7Be have maximum activity concentrations during warm mid-year months. 相似文献
862.
太湖铜锈环棱螺对氮磷的降解作用 总被引:18,自引:0,他引:18
太湖的五湖里湾是一个富营养湖,水质亟待改善。铜锈环棱螺是太湖的常见种群,通过在五里湖的一些室内外实验,研究了螺对水体透明度,总磷、氨氮、溶解氧的作用,发现它能交水体透明度从0.5m左右提高到1.3m,使室内水体浊度迅速降低,降解总磷的幅度能达到50%,分析为铜锈环棱螺的絮凝作用所致;并且,在其水域氨氮深度大幅度降低,使实验点高达5mg/L以上的氨氮浓度降至2mg/L以下,从感观和水质指标两方面有效 相似文献
863.
Ti/Sb-SnO_2 anodes were prepared by thermal decomposition to examine the influence',of the amount of Sb dopant on the structure and electrocatalytic capability of the electrodes in the oxidation of 4-chlorophenol.The physicochemical properties of the Sb-SnO_2 coating were markedly influenced by different amounts of Sb dopant.The electrodes,which contained 5% Sb dopant in the coating, presented a much more homogenous surface and much smaller mud-cracks,compared with Ti/Sb-SnO_2 electrodes containing 10% or 15% Sb dopant,which exibited larger mud cracks and pores on the surface.However,the main microstructure remained unchanged with the addition of the Sb dopant.No new crystal phase was observed by X-ray diffraction(XRD).The electrochemical oxidation of 4-chlorophenol on the Ti/SnO_2 electrode with 5% Sb dopant was inclined to electrochemical combustion;while for those containing more Sb dopant,intermediate species were accumulated.The electrodes with 5% Sb dopant showed the highest efficiency in the bulk electrolysis of 4-chlorophenol at a current density of 20 mA/cm~2 for 180 min;and the removal rates of 4-chlorophenol and COD were 51.0% and 48.9%,respectively. 相似文献
864.
S. Reth W. Graf O. Gefke R. Schilling H. K. Seidlitz J. C. Munch 《Water, Air, & Soil Pollution: Focus》2008,8(2):129-137
Despite many studies of the N2O emission, there is a lack of knowledge on the role of subsoil for N2O emission, particularly in sandy soils. To obtain insight into the entrapment, diffusion, convection and ebullition of N2O in the soil, the N2O concentration in the soil atmosphere was measured over a period of 1 year in 4 lysimeters (agricultural soil monoliths of
1 m2 × 2 m) at 30, 50, 80, 155, and 190 cm depth with altogether 86 gas probes. Additionally the N2O emission into the atmosphere was measured in 20 closed chambers at the soil surface. Concurrently the soil temperature and
soil water content were recorded in order to quantify their effects on the fate of N2O in the soil. Results of the continuous measurements between January and December 2006 were: N2O concentrations were highest in the deeper soil; maximum concentration was found at a depth of 80 cm, where the water content
was high and the gas transport reduced. The highest N2O concentration was recorded after ‘special events’ like snowmelt, heavy rain, fertilization, and grubbing. The combination
of fertilization and heavy rain led to an increase of up to 2,700 ppb in the subsoil. 相似文献
865.
The wetlands play an important role in carbon storage, especially at high latitudes, at which they store nearly one-third of global soil carbons. However, few studies have investigated the emissions of CO(2), CH(4) and N(2)O in the long-term, especially effects of freeze-thaw cycles on these gases emissions in freshwater marsh ecosystems. In this paper, we collected greenhouse gas emission data from a freshwater marsh area in China for 4 years, evaluated their release variables and speculated on their potential atmospheric impact. For this paper, we report on the CO(2), CH(4) and N(2)O emission rates recorded from June 2002 to November 2005 in the Sanjiang Plain of northeast China. We measured their interannual variations and fluctuations, as well as factors affecting their emissions, and estimated their regulation and freeze-thaw cycle impacts. Our results revealed obvious CO(2) and CH(4) emission fluctuations during the winter months, and during the freeze-thaw cycle, and a strong interannual variation during the growing season. Overall, we documented a close relationship between the CO(2) and CH(4) emissions, implicating some regulatory commonality. We determined that the marsh was a N(2)O sink during the winter, but a significant source of N(2)O during the freeze-thaw cycle as the temperature increased, especially in early summer. During the thaw-freeze period, the N(2)O levels were positively correlated with the water depth. Additionally, water depth greatly governed the interannual variation of the N(2)O emissions from the marshes during the thaw-freeze period. 相似文献
866.
Crosslinkable poly(4-methyl-2-pentyne) (PMP) membranes were cast from carbon tetrachloride solutions containing PMP and either 4,4′-diazidobenzophenone or 4,4′-(hexafluoroisopropylidene)diphenyl azide. The composite membranes were transparent and homogeneous and were crosslinked by UV irradiation at room temperature or thermal treatment at 180 °C. Low levels of the bis(aryl azide) (1–4.5 wt%) were effective in rendering the membranes insoluble in cyclohexane and carbon tetrachloride, both are good solvents for PMP, thus PMP can easily be converted to mechanically stable membranes with permeabilities and selectivities comparable or higher than those of the well-known poly(dimethylsiloxane) (PDMS). The permeabilities of O2, N2, H2, CH4 and CO2 were measured. Compared to pure PMP, the crosslinked membranes containing bis(aryl azide) had lower permeabilities and higher selectivities, consistent with a reduction in free volume. 相似文献
867.
氧化亚氮形成的微生物学分子机制研究进展 总被引:1,自引:0,他引:1
1 氧化亚氮 (N2 O)的形成N2 O是继CO2 、CH4之后的第三大温室气体 ,它能破坏大气中的臭氧层 .在过去的 2 0~ 30年间 ,N2 O以每年 0 .2 %~ 0 .3%的速率增长 ,并且有进一步增长的趋势[1 ] .地球上人类和其他生物的活动是N2 O产生的主要来源 ,而微生物是其中最重要的生物源 .微生物产生N2 O的机理主要是通过硝化作用和反硝化作用过程进行的 ,如图 1所示 .反硝化过程中N2 O的形成 :硝化过程中N2 O的形成 :图 1 N2 O的形成Fig.1 FormationofN2 O 催化反硝化过程的酶有 4种 :硝酸还原酶 (Nar)、亚… 相似文献
868.
土壤中的反硝化作用由于直接影响到肥料氮的利用率和环境问题,仍然是氮素研究领域的热点和难点之一,而反硝化作用研究的进展在很大程度上依赖与土壤反硝化的田间测定方法的建立。文章就目前反硝化研究领域常用的15N平衡差值法、15N示踪气体通量法、乙炔抑制气室法、乙炔抑制土柱法的原理、气体样的采集、测定和计算作了综述,以期为土壤反硝化的研究提供依据。 相似文献
869.
Alam JB Hossain A Khan SK Banik BK Islam MR Muyen Z Rahman MH 《Environmental monitoring and assessment》2007,134(1-3):233-242
Surma River is polluted day by day by human activities, poor structured sewerage and drainage system, discharging industrial
and household wastes. The charas (natural channels) are responsible for surface runoff conveyance from its urban catchments
to the receiving Surma River. Water samples have been collected from a part of Surma River along different points and analyzed
for various water quality parameters during dry and monsoon periods. Effects of industrial wastes, municipal sewage, and agricultural
runoff on river water quality have been investigated. The study was conducted within the Chattak to Sunamganj portion of Surma
River, which is significant due to the presence of two major industries – a paper mill and a cement factory. The other significant
feature is the conveyors that travel from India to Chattak. The river was found to be highly turbid in the monsoon season.
But BOD and fecal coliform concentration was found higher in the dry season. The water was found slightly acidic. The mean
values of parameters were Conductivity 84–805 μs; DO: dry-5.52 mg/l, monsoon-5.72 mg/l; BOD: dry-1mg/l, monsoon-0.878 mg/l;
Total Solid: dry-149.4 mg/l, monsoon-145.7 mg/l. In this study, an effort has been taken to investigate the status of concentration
of phosphate (PO−4) and ammonia–nitrogen (NH4–N) at four entrance points of Malnichara to the city, Guali chara, Gaviar khal and Bolramer khal. Data has been collected
from March–April and September–October of 2004. Concentrations have been measured using UV Spectrophotometer. Although the
phosphate concentration has been found within the limit set by DOE for fishing, irrigation and recreational purposes, however
ammonia–nitrogen has been found to exceed the limit. 相似文献
870.
This study compared three forecasting models based on the mean absolute percentage errors (MAPE) of their accuracy in forecasting
air pollution in a traffic tunnel: the Grey model (GM), the combination model used four sample point and five sample point
prediction with GM (1,1)(GM(1,1)4 + 5), and the modified grey model (MGM). An MGM was combined using the four points of the original sequence using the original
grey prediction GM (1,1) for short-term forecasting. The proposed method cannot only enhance the prediction accuracy of the
original grey model, but can also solve the jump data forecasting problem something for which the original grey model is inappropriate.
The MAPE was applied to the models, and the MGM found the proposed method to be simple and efficient. The MAPE of MGM, calculated
over 3 h of forecasts, were as follows: 10.12 (Upwind), 10.07 (Middle) and 7.68 (Downwind) for CO; 10.79 (Upwind), 6.05 (Middle)
and 5.98 (Downwind) for NO
x
, and 11.67 (Upwind), 7.32 (Middle) and 4.56 (Downwind) for NMHC. The MGM model results reveal that the combined forecasts
can significantly decrease the overall forecasting error. Results of this demonstrate that MGM can accurately forecast air
pollution in the Kaohsiung Chung–Cheng Tunnel. 相似文献