全文获取类型
收费全文 | 117篇 |
免费 | 2篇 |
国内免费 | 19篇 |
专业分类
安全科学 | 11篇 |
废物处理 | 2篇 |
环保管理 | 10篇 |
综合类 | 63篇 |
基础理论 | 15篇 |
污染及防治 | 34篇 |
社会与环境 | 3篇 |
出版年
2023年 | 1篇 |
2022年 | 2篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2018年 | 6篇 |
2017年 | 5篇 |
2016年 | 2篇 |
2015年 | 4篇 |
2014年 | 8篇 |
2013年 | 12篇 |
2012年 | 7篇 |
2011年 | 11篇 |
2010年 | 8篇 |
2009年 | 7篇 |
2008年 | 6篇 |
2007年 | 4篇 |
2006年 | 7篇 |
2005年 | 4篇 |
2004年 | 7篇 |
2003年 | 4篇 |
2002年 | 10篇 |
2001年 | 7篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 5篇 |
1997年 | 1篇 |
1991年 | 1篇 |
排序方式: 共有138条查询结果,搜索用时 15 毫秒
21.
22.
曝气生物滤池(BAF)是近年来国外发展起来的一项废水好氧生物处理的新工艺.根据该工程废水水质,采用曝气生物滤池工艺处理丰城废旧物收购加工区的废水,经过一段时间的运行,取得了良好的效果,系统出水达到<污水综合排放标准>(GB8978-1 996)一级排放标准,整个废水处理工程具有处理能力强、处理效果好、启动快、受气温影响小、耐冲击负荷、不需二沉池、工艺流程简单和菌群简单等优点,说明该工艺在我国具有广阔的应用前景. 相似文献
23.
24.
Elina?PortjanskajaEmail author Marina?Krichevskaya Sergei?Preis Juha?Kallas 《Environmental Chemistry Letters》2004,2(3):123-127
The photocatalytic oxidation of humic substances in aqueous solutions and natural waters with TiO2 attached to buoyant, hollow glass micro-spheres was studied. A maximum oxidation efficiency of 3.6 mg W–1 h–1 was achieved in neutral or alkaline media at a plane surface concentration of the catalyst attached to the micro-spheres of 25 g m–2. Proceeding by different mechanisms in acidic and alkaline media, the photocatalytic oxidation efficiency did not benefit from an excessive presence of hydroxyl radical promoters, hydrogen peroxide and alkali. 相似文献
25.
Frank von der Kammer 《Environmental pollution (Barking, Essex : 1987)》2010,158(12):3472-10052
Assessment of the behavior and fate of engineered nanoparticles (ENPs) in natural aquatic media is crucial for the identification of environmentally critical properties of the ENPs. Here we present a methodology for testing the dispersion stability, ζ-potential and particle size of engineered nanoparticles as a function of pH and water composition. The results obtained from already widely used titanium dioxide nanoparticles (Evonik P25 and Hombikat UV-100) serve as a proof-of-concept for the proposed testing scheme. In most cases the behavior of the particles in the tested settings follows the expectations derived from classical DLVO theory for metal oxide particles with variable charge and an isoelectric point at around pH 5, but deviations also occur. Regardless of a 5-fold difference in BET specific surface area particles composed of the same core material behave in an overall comparable manner. The presented methodology can act as a basis for the development of standardised methods for comparing the behavior of different nanoparticles within aquatic systems. 相似文献
26.
Combining the use of photocatalysts with cementitious materials is an important development in the field of photocatalytic air pollution mitigation. This paper presents the results of a systematic study on assessing the effectiveness of pollutant degradation by concrete surface layers that incorporate a photocatalytic material – Titanium Dioxide. The photocatalytic activity of the concrete samples was determined by photocatalytic oxidation of nitric oxide (NO) in the laboratory. Recycled glass cullets, derived from crushed waste beverage bottles, were used to replace sand in preparing the concrete surface layers. Factors, which may affect the pollutant removal performance of the concrete layers including glass color, aggregate size and curing age, were investigated. The results show a significant enhancement of the photocatalytic activity due to the use of glass cullets as aggregates in the concrete layers. The samples fabricated with clear glass cullets exhibited threefold NO removal efficiency compared to the samples fabricated with river sand. The light transmittance property of glass was postulated to account for the efficiency improvement, which was confirmed by a separate simulation study. But the influence of the size of glass cullets was not evident. In addition, the photocatalytic activity of concrete surface layers decreased with curing age, showing a loss of 20% photocatalytic activity after 56-day curing. 相似文献
27.
Karin Wiench Wendel Wohlleben Volker Hisgen Kristin Radke Edward Salinas Sabine Zok Robert Landsiedel 《Chemosphere》2009,76(10):1356-1365
Among the emerging literature addressing the biological effects of nanoparticles, very little information exists, particularly on aquatic organisms, that evaluates nanoparticles in comparison to non-nanocounterparts. Therefore, the potential effects of nano-scale and non-nano-scale TiO2 and ZnO on the water flea, Daphnia magna, were examined in 48-h acute toxicity tests using three different test media, several pigment formulations – including coated nanoparticles – and a variety of preparation steps. In addition, a 21-d chronic Daphnia reproduction study was performed using coated TiO2 nanoparticles. Analytical ultracentrifugation analyses provided evidence that the nanoparticles were present in a wide range of differently sized aggregates in the tested dispersions. While no pronounced effects on D. magna were observed for nano-scale and non-nano-scale TiO2 pigments in 19 of 25 acute (48-h) toxicity tests (EC50 > 100 mg L−1), six acute tests with both nano- and non-nano-scale TiO2 pigments showed slight effects (EC10, 0.5–91.2 mg L−1). For the nano-scale and non-nano-scale ZnO pigments, the acute 48-h EC50 values were close to the 1 mg L−1 level, which is within the reported range of zinc toxicity to Daphnia. In general, the toxicity in the acute tests was independent of particle size (non-nano-scale or nano-scale), coating of particles, aggregation of particles, the type of medium or the applied pre-treatment of the test dispersions. The chronic Daphnia test with coated TiO2 nanoparticles demonstrated that reproduction was a more sensitive endpoint than adult mortality. After 21 d, the NOEC for adult mortality was 30 mg L−1 and the NOEC for offspring production was 3 mg L−1. The 21-d EC10 and EC50 values for reproductive effects were 5 and 26.6 mg L−1, respectively. This study demonstrates the utility of evaluating nanoparticle effects relative to non-nano-scale counterparts and presents the first report of chronic exposure to TiO2 nanoparticles in D. magna. 相似文献
28.
Jie Tang Yun Wang Qiang Xue Fei Liu Kenneth C. Carroll Xiaohua Lu Taogeng Zhou Dengjun Wang 《环境科学学报(英文版)》2022,34(8):46-56
The adsorption behaviors of ciprofloxacin (CIP), a fluoroquinolone antibiotic, onto goethite (Gt) in the presence of silver and titanium dioxide nanoparticles (AgNPs and TiO2NPs) were investigated. Results showed that CIP adsorption kinetics in Gt with or without NPs both followed the pseudo-second-order kinetic model. The presence of AgNPs or TiO2NPs inhibited the adsorption of CIP by Gt. The amount of inhibition of CIP sorption due to AgNPs was decreased with an increase of solution pH from 5.0 to 9.0. In contrast, in the presence of TiO2NPs, CIP adsorption by Gt was almost unchanged at pHs of 5.0∼6.5 but was decreased with an increase of pH from 6.5 to 9.0. The mechanisms of AgNPs and TiO2NPs in inhibiting CIP adsorption by Gt were different, which was attributed to citrate coating of AgNPs resulting in competition with CIP for adsorption sites on Gt, while TiO2NPs could compete with Gt for CIP adsorption. Additionally, CIP was adsorbed by Gt or TiO2NPs through a tridentate complex involving the bidentate inner-sphere coordination of the deprotonated carboxylic group and hydrogen bonding through the adjacent carbonyl group on the quinoline ring. These findings advance our understanding of the environmental behavior and fate of fluoroquinolone antibiotics in the presence of NPs. 相似文献
29.
利用海藻胶渣吸附法处理高浓度含Zn^2+废水,试验考察了海藻胶渣用量、反应pH、震荡时间和温度对吸附效果的影响,探讨了吸附作用机理。试验结果表明,海藻胶渣对Zn^2+有良好的吸附性能,反应的pH、温度和海藻胶渣用量是影响吸附效果的主要因素,在pH7-9,温度30~40℃,用量4%~5%条件下,5~10min内吸附率可达99%以上。 相似文献
30.
光催化技术及其在室内空气净化方面研究现状 总被引:3,自引:0,他引:3
阐述了光催化技术的基本原理、二氧化钛光催化剂的特性,以及光催化技术在环境保护领域的广阔应用。介绍了中国室内空气污染的现状和甲醛、苯系物等主要污染物的性质与来源。简单讨论了物理法,化学法等主要的室内空气污染处理技术,突出表述了光催化技术的优势。从降解机理、降解效果、反应器应用等3个方面介绍了光催化技术在室内空气净化方面的研究现状。指出了单一技术的不足和联合协同作用的必要性。强调了将研究结果投入实际运用的迫切性,希望真正有效的室内空气净化器尽早普及。 相似文献