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41.
Arsenic, cadmium, chromium, and copper concentrations of the Pacific oyster,Crassostrea gigas, purchased from four different markets were determined in this project. In general, gill tissue had the highest proportion
of metal contents (34%–67%) when compared with other tissue parts (mantle, viscera, and adductor muscle), except for arsenic,
which showed the highest level in adductor muscle (44%). Smaller oysters (longitudinal length of soft body part less than
6 cm) had higher metal levels than larger ones (longitudinal length of soft body part more than 6 cm), except copper. None
of the four metals examined showed an obvious seasonal trend, although cadmium levels seemed to be higher in autumn and winter
months. Arsenic, cadmium, and copper levels in oysters purchased from different markets and different months obtained in the
present study were higher when compared with past reports. Cadmium levels, as high as 10.98 mg/kg (dry weight basis) have
been obtained. This approaches the safety limit that may be hazardous to human health. Continual monitoring of cadmium and
other trace metals of toxicological significance to man in Hong Kong seafood is recommended. 相似文献
42.
Seven sediment samples from mangrove sediments of the Red Sea were taken in order to evaluate the possible contamination of the sediments by trace metals (iron (Fe), manganese (Mn), zinc (Zn), copper (Cu), lead (Pb) and cadmium (Cd)). Sequential extraction techniques were performed to study the different geochemical forms of these metals. X-ray diffraction analysis has been performed to correlate the mineralogical composition with the geochemical forms of the studied elements. The results of Fe and Mn contents indicate that they are in large part from lithogenous origin. The elevated concentrations are associated with the residual form ranged from 70 to 93% for Fe and 46 to 70% for Mn. The percentage of Zn, Cu, Cd and Pb in the non-residual form was much greater than that of the residual fractions. This reflects the high mobility and bioavailability of these metals in mangrove sediments of the Red Sea. X-ray diffraction analysis revealed the presence of silicate components including quartz, feldspars and clay minerals in some locality. Non-silicate components recorded in the study area as calcite as well as, Mg-calcite. Quantitatively both components i.e. silicate and carbonate varied according to their source material. 相似文献
43.
The zinc, cadmium, copper and lead release from the uncontaminated and contaminated coastal sediments with aerated sea water was studied. the metals transfer to the dissolved forms was monitored during one-two months by differential pulse anodic voltammetry (DPASV). the sediments with different initial degree of contamination were sampled in the Peter the Great Bay, Sea of Japan around Vladivostok-the biggest city in Russian Far East. Sediment contamination by metals led to increased release to solution of zinc due to sulphide oxidation and cadmium on account of organic matter decomposition. the copper behaviour was complicated by strong binding with organic matter and enhancements of copper release can only be seen in sediment with a low organic matter content. Significant lead transfer to dissolved forms was not observed regardless of sediment contamination. the temperature affected the release of cadmium and copper through enhanced organic matter destruction. the dissolved metal fluxes from the sediment transformation are compared with metal fluxes towards bottom. Such comparisons show that second contamination by dissolved metals of the studied coastal environment may be important for cadmium only. 相似文献
44.
45.
Characterization of Santa Catarina (Brazil) coal with respect to human health and environmental concerns 总被引:1,自引:0,他引:1
Silva LF Oliveira ML da Boit KM Finkelman RB 《Environmental geochemistry and health》2009,31(4):475-485
The current paper presents the concentration, distribution, and modes of occurrence of trace elements of 13 coals from south
Brazil. The samples were collected in the state of Santa Catarina. Chemical analyses and the high ash yields indicate that
all studied coals are rich in mineral matter, with SiO2 and Al2O3 dominating as determined by inductively coupled plasma-atomic emission spectrometry (ICP-AES). Quartz is the main mineral
species and is associated with minor levels of feldspars, kaolinite, hematite, and iron-rich carbonates. The contents of trace
elements, including As, Pb, Cd, Ni, Cr, Mn, Be, V, U, Zn, Li, Cu, Tl, and Ni, in coals were determined. A comparison of ranges
and means of elemental concentrations in Santa Catarina, Brazil, and world coals shows that the ranges of most elements in
Santa Catarina coal are very close to the usual worldwide concentration ranges in coal. 相似文献
46.
Inter-seasonal studies on the trace metal load of surface water, sediment and Tympanotonus fuscatus var. radula of Iko River were conducted between 2003 and 2004. The impact of anthropogenic activities especially industrial effluent,
petroleum related wastes, gas flare and episodic oil spills on the ecosystem are remarkable. Trace metals analyzed included
cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), lead (Pb), manganese (Mn), nickel (Ni), vanadium (V) and zinc (Zn). Sediment
particle size analysis revealed that they were characteristically psammitic and were predominantly of medium to fine grained
sand (>73%), less of silt (<15%) and clay (<10%). These results correlated with low levels of trace elements such as Pb (0.03 ± 0.02 mg kg−1), Cr (0.22 ± 0.12 mg kg−1), Cd (0.05 ± 0.03 mg kg−1), Cu (0.04 ± 0.02 mg kg−1) and Mn (0.23 ± 0.22 mg kg−1) in the sediment samples. This observation is consistent with the scarcity of clayey materials known to be good scavengers
for metallic and organic contaminants. Sediments indicated enhanced concentration of Fe, Ni and V, while other metal levels
were relatively low. The concentrations of all the metals except Pb in surface water were within the permissible levels, suggesting
that the petroleum contaminants had minimal effect on the state of pollution by trace metals in Iko River. Notably, the pollutant
concentrations in the sediments were markedly higher than the corresponding concentrations in surface water and T. fuscatus tissues, and decreased with distance from point sources of pollution. 相似文献
47.
Leaf accumulation of trace elements and polycyclic aromatic hydrocarbons (PAHs) in Quercus ilex L 总被引:1,自引:0,他引:1
De Nicola F Maisto G Prati MV Alfani A 《Environmental pollution (Barking, Essex : 1987)》2008,153(2):376-383
Quercus ilex L. leaves were collected four times in one year at six urban sites and one remote area in order to determine trace element and PAH accumulation through concomitant analyses of unwashed and water-washed leaves. Both unwashed and washed leaves showed the highest amounts of trace elements and PAHs in the urban area. Unwashed leaves showed greater differences between urban and remote areas and among the urban sites than washed leaves for trace element and PAH concentrations. Water-washing resulted in a significant (P<0.001) decrease in leaf concentrations of Cr, Cu, Fe, Pb, V and Zn. By contrast, Cd and total PAH concentrations showed no differences between unwashed and washed leaves. 相似文献
48.
Singh S Sharma DK Dhar S Kumar A Kumar A 《Environmental monitoring and assessment》2007,130(1-3):301-309
Two measurement campaigns were conducted in two sampling sites, An Thinh and Duy Minh, in northern Vietnam during the months
of November–December 2000 and November 2001–February 2002 in order to investigate the extend of the particulate air pollution
from the Pha Lai coal fired power plant. Fine particle samples were analyzed by Energy Dispersive X-Ray Fluorescence spectrometry
and soot samples were analyzed by reflectometer. The result showed that high concentration of soot and elements mostly coincided
with the air masses originating from the power plant. Sea spray aerosol was found to be the major source of chlorine at both
sites. Ratios of specific elements and principal component analysis (PCA) revealed that coal combustion was the main contributor
to the air pollution at both sites. PCA also indicated that there were other sources responsible for the elements emission,
probably the influence of long distance transport and Asian Brown Cloud. 相似文献
49.
Castello M 《Environmental monitoring and assessment》2007,133(1-3):267-276
Transplants of the mosses Hypnum cupressiforme and Pseudoscleropodium purum used as active biomonitors of airborne trace elements were compared in a survey carried out at Trieste (NE Italy). Twelve
elements were considered: Al, As, Cd, Cr, Cu, Fe, Hg, Mn, Pb, Ti, V, Zn. Water-washed materials of H. cupressiforme and P. purum, collected in a remote area to prepare transplants, showed comparable content of all elements, excluding Pb. Transplants
of P. purum showed a significantly higher accumulation of Al, Fe, Pb and Ti; higher levels of Cu and V were accumulated in H. cupressiforme. Losses of some elements occurred in some samples of both species; the most consistent losses regarded Cr and Mn. Accumulation
data of Al, As, Cd, Hg, Zn found in the two transplanted sets were not correlated. Differences in element uptake in the two
mosses are likely to depend mainly on morphology, and probably on the different forms of emission and deposition types of
the elements. The two mosses showed an overall accordance in discriminating sites highly and scarcely affected by trace element
depositions, although they accumulated some elements, in particular Hg and Zn, in different ways. P. purum proved to be a better accumulator than H. cupressiforme, showing similar or higher accumulation and lower loss of almost all elements, especially those related to particulate, dry
depositions; H. cupressiforme could be effective in detecting large-scale patterns, related to wet depositions. These results indicate that these mosses
cannot be used interchangeably for monitoring particular elements, and are able to provide complementary information on different,
local and long-range deposition patterns. 相似文献
50.
Asante KA Agusa T Mochizuki H Ramu K Inoue S Kubodera T Takahashi S Subramanian A Tanabe S 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):862-873
Trace elements (22) and stable isotope ratios (δ15N and δ13C) were analyzed in marine organisms from shallow (SW) and deep-water (DW) of the East China Sea to understand biomagnification and prey source of trace elements. In the benthic marine organisms from DW, δ15N values were negatively correlated with Ba, Cu, Ag, Mo, Sr, As, and Co concentrations. This may be due to the specific accumulation in lower trophic animals and/or the biodilution through the food web in DW. Relationships between δ15N and concentrations of Co, Cr, Bi, and Tl in fish and Ag, Bi, V, Hg, and Tl in crustaceans showed positive correlations, suggesting that trophic position was affecting the concentrations of those elements in phyla, with higher trophic animals retaining higher concentrations than the lower trophic animals. Positive correlations between δ13C and Rb were observed in marine organisms. Therefore, Rb may be a possible substitute of δ13C as tracer of prey source in the East China Sea although further investigation is required. 相似文献