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91.
介质阻挡放电降解SF6的研究   总被引:1,自引:1,他引:0  
沈燕  黄丽  张仁熙  侯惠奇 《环境化学》2007,26(3):275-279
采用GC-TCD考察介质阻挡放电技术(DBD)处理SF6的效果,并采用红外吸收光谱进行产物分析.结果表明,电源电压的增加、放电时间的延长、气体介质分压的降低,以及少量其它气体(Ar,N2,O2,H2O,空气)的加入能够提高转化效果.另外,SF6的降解率随着空气湿度的增加而增加,28.2 kPa相对湿度为51%的空气与2.0 kPa SF6的混合气体放电后SF6降解率达92%.放电产物包括SiF4,SF4,SOF2,SOF4,SO2F2.  相似文献   
92.
Permeable reactive barriers (PRBs) are now an established approach for groundwater remediation. However, one concern is the deterioration of barrier material performance due to pore clogging. This study sought to quantify the effect of pore clogging on the alteration of the physical porous architecture of two novel potential PRB materials (clinoptilolite and calcified seaweed) using image analysis of SEM-derived images. Results after a water treatment contaminated with heavy metals over periods of up to 10 months identified a decrease in porosity from c. 22% to c. 15% for calcified seaweed and from c. 22% to c. 18% for clinoptilolite. Porosity was reduced by as much as 37% in a calcified seaweed column that clogged. The mean pore size (2D) of both materials slightly decreased after water treatment with c. 11% reduction in calcified seaweed and c. 7% reduction in clinoptilolite. An increase in the proportion of crack-shaped pores was observed in both materials after the contaminated water treatment, most noticeably in the bottom of columns where contaminated water first reacted with the material. The distribution of pores (within a given image) derived from the distance transform indicated the largest morphological differences in materials was recorded in calcified seaweed columns, which is likely to impact significantly on their performance as barrier materials. The magnitude of porosity reduction over a short time period in relation to predicted barrier longevity suggest these and similar materials may be unsuited for barrier installation in their present form.  相似文献   
93.
Jan Hayes 《Safety Science》2012,50(3):424-432
Operational personnel in complex hazardous industries are regularly called upon to make decisions that balance the production and safety objectives of their organisation. Regulations and industry standards focus on defining and complying with operating limits of various kinds as the primary method of achieving the right balance. Such limits remove the need in many cases for in-the-moment judgements about safety and production priorities.Focussing solely on the compliance with a pre-defined envelope underestimates the direct contribution to safety from operational managers based on their professional judgement. Research in a chemical plant, a nuclear power station and an air navigation service provider has identified a “line in the sand” approach taken by experienced operating personnel when abnormal situations arise. In developing these situation-specific self-imposed limits, operational managers focus on the status of safety barriers, rather than considering risk from first principles. This approach could form the basis of a new procedure, which lays out the process to be followed in determining how best to proceed (similar to job safety analysis or permit to work). This would acknowledge that such decisions are necessary, assist operational personnel in making better choices and open such decisions to appropriate audit and scrutiny.  相似文献   
94.
We apply a fixed-effects model to examine the impact of trade and environmental policies on air quality at ports along the U.S.-Mexico border. We control for other factors influencing air quality, such as air quality of cities near the border, volume of traffic flows and congestion. Results show the air quality improved after 2004, when the diesel engine policy was applied. We see mixed results for the trade policy, whose implementation time varies across ports along the international border. Controlling for air quality in cities near the border is essential for assessing the policy contributions to air quality.  相似文献   
95.
美国排污权交易制度的实践是成功的,也为多个国家和地区所借鉴。本文通过清洁空气跨州法则(CAIR)的实施成效及环境效益两个方面论述美国排污权交易制度的最新实践,并结合实施情况在政策持续性、数据质量保证、信息公开、政策准备研究等方面提出几点启示,以供我国各区域开展排污权交易政策借鉴和参考。  相似文献   
96.
绿色贸易壁垒的成因   总被引:7,自引:0,他引:7  
环境问题的全球化、政治化、社会化、累加化和用经济手段解决环境问题,使形成绿色贸易壁垒成为可能,关贸总协定中达成一些与生态环境保护有关的协定为绿色贸易壁垒的设置提供了法律依据,而“环境标志”制度则是实施绿色贸易壁垒的重要的通常的手段。  相似文献   
97.
陈天蛋 《环境工程》2012,(Z1):228-232
为了提高居民居住和工作环境质量,降低噪声对人们的干扰,创造社会一片安宁和谐的氛围,志绿隔声产品将复合高性能新材料形成阻尼约束结构放置在两块板中间,将透过墙板的噪音能量降低85%以上。本文结合项目工程案例,来展现志绿隔声产品的高性能,解决噪声对人们的危害。  相似文献   
98.
In a stylized model of international trade, firms in the North indirectly export second-hand products to a representative firm in the South to be reused as intermediate goods, with potential trade gains. The level of reusability of waste products – or green design – is a crucial choice variable in the North. This is because, in the presence of imperfect international monitoring, non-reusable waste can be illegally mixed with reusable waste. I explore the driving forces for illegal waste movement, with a particular focus on local waste regulations such as the EU׳s Directive on Waste Electrical and Electronic Equipment. Under mild conditions, it is shown that increasingly stringent regulations in the North can induce Northern firms to reduce product reusability. Consequently, the flow of non-reusable waste to the South increases, magnifying the pollution haven effect.  相似文献   
99.
Local government is attributed a vital role in climate-change adaptation. Previous studies contend that conflicting priorities, insufficient institutional incentives and knowledge of risks, and inadequate resources all impede local climate adaptation. Though the importance of local political support in enabling climate adaptation is widely acknowledged, the views of local politicians have rarely been analysed. Drawing on semi-structured interviews with local politicians in Sweden, we explore what affects their engagement in climate adaptation. The study claims that climate adaptation contrary to mitigation is not viewed as political beyond directing attention and sanctioning guidelines set by officials. A limited number of interviewees claim a more strategic political role in adaptation. The combined effect of institutional incentives (e.g. fragmented national guidelines, unappealing goals, and lack of funding), relative weight in local politics, and ability to exercise political leadership (e.g. campaign value, public and media pressure, and lack of ideology) is perceived as too insignificant to trigger strong political engagement. In less-populous municipalities, adaptive measures were highly valued for demonstrating political action.  相似文献   
100.
随着中国加入WTO进程的加快和西部大开发战略的实施,依法治国无疑是改善投资环境、促进西部开发的最有效手段之一。本文根据WTO基本原则与法制经济的相互关系和影响深入浅出地论述了WTO对西部开发的风险及机遇,并提出了针对性的策略和措施。  相似文献   
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