绿色贸易转型政策框架及“十二五”重点政策探讨

绿色贸易转型政策框架,是指一切有利于促进我国对外贸易发展,同时缓解贸易资源环境代价和改善环境质量的贸易手段和措施构成的政策集合体系。本文基于环境保护部环境与贸易专家组(以下称专家组)多年研究探索基础上,依据贸易政策理论,构建促进绿色贸易转型的政策框架,梳理出主要绿色贸易手段的政策矩阵,并顺应"十二五"贸易政策取向和国家"十二五"环保规划目标,提出相应的重点政策建议:一是绿化海关进出口产品目录,进行产品环境分类管理;二是制定实行以征收出口环节的环境关税为主导的绿色贸易政策;三是对生态标志产品实施出口退税差别税率政策;四是推行鼓励进口替代政策,促进节能减排;五是及时修订外商投资产业指导目录,防范外商直接投资西部转移的环境风险;六是制定企业境外投资国别指导目录,把环境影响评价制度延伸至境外投资项目;七是健全进口废物贸易政策,有效防范废物贸易环境风险;八是适度提高人民币汇率,促进绿色贸易转型。     

Interaction and combined toxicity of microplastics and per- and polyfluoroalkyl substances in aquatic environment

● Adsorption of PFASs on MPs and its mechanisms are critically reviewed. ● MPs could alter the transport and transformation of PFASs in aquatic environments. ● Combined toxicity of MPs and PFASs at organismal and molecular levels is discussed. Microplastics (MPs) are recognized as vectors for the transport of organic contaminants in aquatic environments in addition to their own adverse effects on aquatic organisms. Per- and polyfluoroalkyl substances (PFASs) are widely present in aquatic environments due to their widespread applications, and thus coexist with MPs. Therefore, we focus on the interaction of MPs and PFASs and related combined toxicity in aquatic environments in this work. The adsorption of PFASs on MPs is critically reviewed, and new mechanisms such as halogen bonding, π-π interaction, cation-π interactions, and micelle formation are proposed. Moreover, the effect of MPs on the transport and transformation of PFASs in aquatic environments is discussed. Based on four typical aquatic organisms (shellfish, Daphnia, algae, and fish), the toxicity of MPs and/or PFASs at the organismal or molecular levels is also evaluated and summarized. Finally, challenges and research perspectives are proposed, and the roles of the shapes and aging process of MPs on PFAS biogeochemical processes and toxicity, especially on PFAS substitutes, are recommended for further investigation. This review provides a better understanding of the interactions and toxic effects of coexisting MPs and PFASs in aquatic environments.     

Oxidation of diclofenac by birnessite: Identification of products and proposed transformation pathway

Diclofenac (DCF), a widely used non-steroidal anti-inflammatory, reacted readily with birnessite under mild conditions, and the pseudo first order kinetic constants achieved 8.84 × 10^?2 hr^?1. Five products of DCF including an iminoquinone product (2,5-iminoquinone-diclofenac) and four dimer products were observed and identified by tandem mass spectrometry during the reaction. Meanwhile, 2,5-iminoquinone-diclofenac was identified to be the major product, accounting for 83.09% of the transformed DCF. According to the results of spectroscopic Mn(III) trapping experiments and X-ray Photoelectron Spectroscopy, Mn(IV) contained in birnessite solid was consumed and mainly converted into Mn(III) during reaction process, which proved that the removal of DCF by birnessite was through oxidation. Based on the identified products of DCF and the changes of Mn valence state in birnessite solid, a tentative transformation pathway of DCF was proposed.     

大气汞在土壤中转化及其与土壤汞富集的相关性

通过现场调查与模拟试验相结合的方法，研究了大气汞对土壤汞富集的影响及其进入土壤后的形态转化。     

产业关联水平对碳排放演化的影响机理及效应研究——基于欧盟27国投入产出数据的实证分析

碳排放逐步升高是以工业化为特征的区域经济崛起的必然结果。论文的理论研究说明,产业关联水平反映了区域发展过程中产业多样化和分工细化的程度,相较于产业结构,产业关联水平对区域经济发展水平的指示意义更深刻。那么,产业关联水平对碳排放的影响特征及其趋势将更接近于碳排放在经济发展驱动下的演进规律。因此,论文采用欧盟27国投入产出数据,在测算不同类型制造业和服务业的产业关联水平的基础上,确定不同类型制造业所对应的特征服务业类型,进而应用经济计量学工具对制造业与服务业产业关联度对碳排放的影响进行实证分析,结果显示：第一,作为发达经济体,欧盟的制造业与服务业整体间产业关联度对碳排放具有显著负效应;第二,低端、中端和高端制造业与各自对应特征服务业类型间产业关联度对碳排放的影响均较为显著,其强度呈现随制造业水平升级而先上升、后下降的趋势;第三,高端制造业与生产性、分配性服务业间产业关联度的提高是实现区域碳排放达到峰值并逐步下降的重要动力,而中端制造业与其对应特征服务业关联度提升对碳排放的正向效应将高于低端制造业主导时期。因此,结合发达经济体的发展经验可以发现,碳排放的演化具有规律性特征,而以产业关联度入手的分析能够提供操作性更强的参考。目前,中国应在推动产业结构升级结构的过程中,大力提升生产性服务业的发展水平及其与制造业的关联水平,并采取积极措施降低交通运输业等分配性服务业的能耗强度。     

中亚五国气溶胶光学厚度时空分布特征研究

气溶胶时空变化是影响气溶胶气候效应不确定性的主要因素之一.在生态环境脆弱的中亚五国(哈萨克斯坦、乌兹别克斯坦、土库曼斯坦、吉尔吉斯斯坦和塔吉克斯坦)研究气溶胶光学厚度(Aerosol Optical Depth,AOD)的时空变化对中亚地区及全球生态环境和气候变化具有重要意义.基于2002-2019年MODIS 04_...     

Mercury removal from flue gas using nitrate as an electron acceptor in a membrane biofilm reactor

Membrane bioreactor achieved mercury removal using nitrate as an electron acceptor. The biological mercury oxidation increased with the increase of oxygen concentration. Ferrous sulfide could make both Hg²⁺ and MeHg transform into HgS-like substances. Nitrate drives mercury oxidation through katE, katG, nar, nir, nor, and nos. Mercury (Hg⁰) is a hazardous air pollutant for its toxicity, and bioaccumulation. This study reported that membrane biofilm reactor achieved mercury removal from flue gas using nitrate as the electron acceptor. Hg⁰ removal efficiency was up to 88.7% in 280 days of operation. Oxygen content in flue gas affected mercury redox reactions, mercury biooxidation and microbial methylation. The biological mercury oxidation increased with the increase of oxygen concentration (2%‒17%), methylation of mercury reduced with the increase of oxygen concentration. The dominant bacteria at oxygen concentration of 2%, 6%, 17%, 21% were Halomonas, Anaerobacillus, Halomonas and Pseudomonas, respectively. The addition of ferrous sulfide could immobilize Hg²⁺ effectively, and make both Hg²⁺ and MeHg transform into HgS-like substances, which could achieve the inhibition effect of methylation, and promote conversion of mercury. The dominant bacteria changed from Halomonas to Planctopirus after FeS addition. Nitrate drives mercury oxidation through katE, katG, nar, nir, nor, and nos for Hg⁰ removal in flue gas.     

主要发达国家碳达峰碳中和的实践经验及对中国的启示

气候变化问题是人类社会共同面临的重大挑战，关系到人类生存和各国利益。推进碳达峰碳中和是中国的一项重大战略决策，是负责任大国对国际社会的庄严承诺，也是推动高质量发展的内在要求。本文归纳分析欧盟、美国、日本、韩国、德国、英国等主要发达经济体碳达峰的经济社会特征、碳中和的路径共识，系统梳理推动实现碳达峰碳中和的经验举措，对比分析中国国内进展和差距，并提出重点借鉴的国际经验与启示。研究发现，中国已经逐步具备实现碳达峰国家的基本特征，但相比发达国家，在降碳效果核算评估、低碳安全高效能源系统构建、碳价格传导机制设计、低碳技术创新和新业态模式打造、法规制度系统化构建等方面仍有差距，仍需加强政策驱动和重点国际经验借鉴，进一步优化“双碳”目标评估指标体系，将构建清洁、低碳、安全、高效能源系统作为能源生产和消费革命的主要目标，有序推进碳排放权交易市场建设和能源资源市场化价格调控，强化绿色低碳技术的研发创新，加快构建形成系统性推动“双碳”目标的法规体系。