Energy futures and green chemistry: competing for carbon

Global energy demand is expected to increase from the current 400 ExaJ per year to as much as 700–1,000 ExaJ per year by the middle of this century. If fossil carbon resources continue to make up the bulk of the energy supply, not only will atmospheric carbon dioxide increase to levels not seen for the past 30–35 million years, but depleting fossil carbon resources will become increasingly less available for other purposes, particularly the production of chemicals on which society now depends. The chemical process industries are heavily dependent on the availability of low-price petroleum as a feedstock. Recent life-cycle analyses suggest that pursuing both strategies of renewable energy sources and renewable feedstocks (i.e. biomass) will be required to meet these competing demands. Reducing the global use of both energy and manufactured chemicals will be a challenge for sustainable development. Education of the next generation of chemists and chemical engineers will have to change significantly from its current emphasis on petrochemical-based manufacturing to include a much greater emphasis on renewable resources and bio-based processes.Brief accounts of this work were presented at the 7th International Symposium on Green Chemistry in China (Zhuhai, People’s Republic of China, May 2005) and at the Joint US–China Green Chemistry Workshop (Beijing, People’s Republic of China, May 2005; this workshop was supported by US National Science Foundation grant CHE-0522369).     

Thermal neutron fluence from ultra low-level γ-ray spectrometry of spoons activated during the JCO criticality accident at Tokai-mura in 1999

During the JCO-accident in Tokai-mura in 1999, the surrounding village was irradiated by an uncontrolled neutron flux. At some locations in that village, the thermal neutron flux was determined retrospectively by measurement of the very low activity of ⁵¹Cr and ⁶⁰Co in stainless-steel spoons using γ-ray spectrometry in underground laboratories. Activities determined in the HADES underground facility are presented here, together with calibrations performed using a well-defined thermal neutron flux to directly estimate the fluence of thermal neutrons independent of most assumptions. The results show measurable ⁵¹Cr in three samples and ⁶⁰Co in four samples taken from locations at distances of up to 430 m from the accident location despite the elapse of 4 half-lives of ⁵¹Cr before measurement. Effects of air transport of the samples were considered and shown to be negligible.     

水泥行业节能减排与清洁生产——以鞍山某水泥有限责任公司清洁生产为例

以典型的水泥行业清洁生产审核为例,阐述传统的水泥行业,通过实施清洁生产是实现企业节能减排的重要手段之一,从而实现企业环境效益、经济效益双赢,为水泥行业的可持续发展奠定基础。     

浅议污水处理厂的节能

系统地介绍并分析了污水处理厂流程中各个处理构筑的能耗情况,并针对各个构筑物提出有效的节能途径。指出了常用的污水好氧处理能耗过高的突出问题,建议改用能耗低造价低的好氧过滤等处理方法。污水再生利用也是解决污水处理能耗高的途径之一。     

Thermal effects of a sonic jet fire impingement on a pipe

Although the effects of jet fires are often limited to rather short distances, if their flames impinge on a pipe or a vessel collapse can occur in very short times. In such cases, the heat flux on the affected equipment is very high and wall temperature can increase very rapidly. This can happen in parallel pipelines, if a release occurs and impinges on another one. Nevertheless, jet fire impingement has been scarcely studied. In this communication the results obtained from an experimental set-up are presented. Sonic jet fires impinged on a pipe containing stagnant air or water. The temperatures of the flames impinging on it were measured for the worst case (flame front-bright zone), as well as the evolution with time of the pipe wall temperature at different locations. Initial temperature increases up to around twenty °C/s were registered for the air inside, with maximum values of up to 600 °C reached in 2.5 min, and 800 °C in approximately 9 min. In the case of pipe containing water, in the zone of the wall in contact with the liquid the heating rates were much lower, the maximum temperature reached being up to approximately 150 °C. From the temperatures of the jet flames and of the pipe, the heat fluxes reaching the pipe and the corresponding heat transfer coefficients were obtained. The results obtained emphasized that safe distances are essential in pipelines, together with fire proofing and other safety measures.     

Synergisms between climate change mitigation and adaptation: an insurance perspective

As the world’s largest industry, the insurance sector is both an aggregator of the impacts of climate change and a market actor able to play a material role in decreasing the vulnerability of human and natural systems. This article reviews the implications of climate change for insurers and provides specific examples of insurance-relevant synergisms between adaptation and mitigation in the buildings and energy sectors, agriculture, forestry, and land use. Although insurance is far from a “silver bullet” in addressing climate change, it offers significant capacity and ability to understand, manage, and spread risks associated with weather-related events, more so today in industrialized countries but increasingly so in developing countries and economies in transition. Certain measures that integrate climate change mitigation and adaptation also bolster insurers’ solvency and profitability, thereby increasing their appeal. Promising strategies involve innovative products and systems for delivering insurance and the use of new technologies and practices that both reduce vulnerability to disaster-related losses and support sustainable development. However, climate change promises to erode the insurability of many risks, and insurance responses can be more reactive than proactive, resulting in compromised insurance affordability and/or availability. Public–private partnerships involving insurers and entities such as the international relief community offer considerable potential, but have not been adequately explored.

Improving the environmental performance of machine-tools: influence of technology and throughput on the electrical energy consumption of a press-brake

Machine-tools have been identified as one of the main energy-using products to be analyzed in an Ecodesign perspective, targeting the reduction of their environmental impact. Following this, machine-tool manufacturers are committed to anticipate eminent regulations and are looking for guidelines to improve their products on an effective and low-cost manner. This paper describes part of the energy consumption study followed in the frame of the Ecodesign of a commercial press-brake. All-hydraulic and all-electric commercially available systems, of different capacities and working in real production scenarios, have been included. From this study, a preliminary version of an LCI dataset for the bending process is proposed, structured in technology, machine capacity and usage mode categories, and using the bending cycle as the reference unit. The energy consumption per category was estimated based on a specific process energy model built as a function of the referred parameters. The contribution of the respective machine-tool structure to the environmental impact of the machining process is to be included, targeting the completion of such machining unit process dataset. The full LCA of an all-hydraulic system revealed the significant contribution of the machine-tool structure to the global life-cycle environmental impact of the machine (about 40%), while electricity during use phase contributes with about 46% to the total impact. This contradicts the general results published for other metal and non-metal forming processes, and is understood to be related with the discrete loading character of such forming processes here discussed.     

Public policy as a part of transforming energy systems: framing bioenergy in Finnish energy policy

Government interventions have been identified as important for energy systems change, because they can either facilitate or hinder transitions toward more sustainable energy systems. This article analyses how bioenergy options have been framed in Finnish policy strategies and how the framing has changed over time. The empirical material includes the content of 15 government programmes and nine national energy/climate strategies. On the basis of this assessment, both the link between bioenergy framings in strategies and the actual transformation of Finnish bioenergy systems are explored.On the basis of bioenergy framings, the development of energy policy can be divided into three phases: support for domestic energy sources in 1979-1991, support for wood- and industry-based bioenergy in 1992-1998, and diversified bioenergy in the context of climate change in 1999-2010. For two decades, primarily wood-based bioenergy was supported despite alternative technological developments occurring elsewhere. After the turn of the millennium, the importance of climate policy increased and alternative bioenergy sources were raised on the government policy agenda, also resulting in some new policy instruments. Rather than adopting a visionary outlook to guide system transformation, climate and energy policy has strengthened those technological options that have been selected elsewhere. If public policies are to enhance the shift toward low-carbon, sustainable energy systems, they would need to be more comprehensive, be more consistent over time, and emphasise energy use more.     

Path creation for sustainable consumption: promoting alternative heating systems in Finland

There are many cost-effective technologies to reduce resource use and carbon dioxide emissions in space heating, yet they are adopted very slowly, and inefficient heating systems persist. In this article, we examine path dependence and path creation in home heating systems. Path dependence refers to the self-sustaining characteristics of existing systems such as the dominant energy system. Path creation is a related concept that highlights entrepreneurship in ‘mindfully deviating’ from existing paths and creating new ones by engaging various stakeholders and generating momentum. Research on path creation in energy systems has focused on energy production systems, whereas end-use technologies have gained less attention. We explore the role of path creation in end-use technologies through four attempts to change heating systems for detached houses in Finland via the promotion of heat pump technologies. Within the path creation process, we focus on how the initiators of new paths try to counter the forces maintaining the dominant system. In particular, we pay attention to how small organizations make use of co-operation to challenge the existing path. The aim is to identify the conditions for successful path creation by entrepreneurs and energy end-users under adverse conditions.