Laser cleaning of historical limestone buildings in Bordeaux appraisal using cathodoluminescence and electron paramagnetic resonance

BACKGROUND: Most historical buildings in Bordeaux city are made of limestone. This yellowish-white rock is rather porous and highly sensitive to pollution. As a consequence of local weathering conditions, these buildings present a dark appearance due to the development of a superficial dark grey to black crust. METHODS: For the last decade, a campaign has been underway to clean these buildings. Eleven techniques of surface treatment have been used, including laser beam technology. As a contribution to the study of laser beam effects on stone buildings, two analytical methods have been used on clean versus unclean surfaces: Cathodoluminescence (CL) and Electron Paramagnetic Resonance (EPR), in addition to SEM-EDX and XRD. RESULTS: The black crust is composed of different types of particles: carbon porous micro-particles of industrial origin, atmospheric dust due to the erosion of soils and rocks, alumino-silicate particles from urban pollution; all these particles being cemented by gypsum. DISCUSSION: As far as heritage conservation is concerned, the laser surface treatment not only preserves the original patina of the stone, but also leaves surface smoothness unaltered. CONCLUSIONS AND PERSPECTIVES: CL and EPR data confirm that lasers--with highly controlled parameters--only get rid of the black crust and, thus, reveal the underneath layer, the so-called patina. This patina shows no luminescence, whereas the limestone on which it has grown shows a bright orange emission of CL. This indicates CL to be a fast and easy way to provide a high quality control for the restoration of polluted ancient stones.     

Financing energy transformation: The role of renewable energy equity indices

The support of financial markets for the transformation of the energy system to a low carbon society seems critical for its success. But will they support this transformation on the basis of market incentives alone? This study analyses how equity indices that try to capture renewable energy investments perform compared to conventional benchmark indices. Especially financial market investors—such as pension funds, insurance companies, and mutual funds—use these to assess and guide their renewable energy investments. As such, we take the perspective of financial market participants, which mainly only indirectly invest in renewable energy. We also analyze whether renewable energy indices are to be regarded as an example of market environmentalism. We find that the renewable energy indices’ risk-adjusted return is very poor and suggests renewables is not a financially attractive portfolio investment yet. We also argue that renewable energy equity indices can be regarded as an example of market environmentalism, especially with respect to commodification and frame-shifting.     

The adoption of green energy technologies: The role of policies in Austria,Germany, and Switzerland

We contribute to the existing research about policy-induced technology adoption in several ways. First, we suggest a new survey design to measure the energy-related policy environment. Second, we simultaneously estimate the policy effects for the adoption propensity and the adoption intensity simultaneously and, third, we compare the policy effects in the three countries, Austria, Germany, and Switzerland. Based on a representative sample of firms for all three countries we find that policies essentially promote the adoption of technologies and they are practically ineffective for the intensity, which poses a great challenge to future policy designs. Voluntary agreements or demand-related factors are among the most important drivers for the adoption propensity of green energy technologies. Given the current institutional framework in the surveyed countries, subsidies are more effective in Austria, taxes are more effective in Germany, and demand-related factors are relatively more effective in Switzerland.     

Energy-efficient HVAC system through chillers’ capacity sizing for a library building

Heating, ventilating, and air-conditioning (HVAC) systems in commercial buildings consume the largest amount of energy. Recent surge in energy cost necessitates constant re-evaluation of HVAC system for most of the buildings. The objective of this study is to present the strategic approach on energy saving analysis of the HVAC system and chiller sizing optimization for a library building. Energy modeling code (eQUEST) for buildings simulation has been applied to verify and predict the long-term energy consumption of HVAC systems. To improve the accuracy of simulation results, the actual performance curves of the chillers and pumps were the inputs of curve fitting data from on-site field measurements data. Energy consumption data acquisition from the building energy management system (BEMS) for one year has been conducted comprehensively to calibrate energy modeling and to quantify energy saving results. The results revealed good agreement between energy modeling and BEMS data with the error of less than 10%. Besides, energy savings through the chillers’ sizing based on cooling load profile could be achieved satisfactorily by utilizing energy modeling by using the actual chiller performance curve. The energy saving for HVAC system can be obtained satisfactorily at the saving of 110,362 kWh per year. It is expected that the study will stimulate a more robust investigation of energy-efficient and cost-effective HVAC system specific for library buildings.     

Effects of investment on energy intensity: evidence from China

This article explores the effects of investment upon energy intensity by applying a unique panel data of China’s 27 provinces between 2004 and 2013. In addition, it also particularly studies other factors, such as energy price, economic structure, and urbanization. The results, based on four econometric regression model results, suggest that in general, the indigenous investment on research and development is a more powerful tool to decrease China’s energy intensity regardless of region disparity. The foreign direct investment (FDI) has a prominent but not persistent effect on energy intensity. However, the outward direct investment has not shown its significant impact on energy intensity. At the level of an aggregate economy and China’s eastern region, the results demonstrate that FDI improves energy efficiency significantly. For the central and western provinces, FDI does not support the similar conclusion. Based on these analyses, we present the corresponding regional policies for policymakers.     

The SEAP in the city of Girona,a crossroads between boldness and pragmatism

The Covenant of Mayors has secured the commitments of over 5400 European Cities (as of December 2013) to achieving the European Union 20-20-20 climate change mitigation targets by 2020 through action at the local level. Due to the youth of the initiative, few experiences have been reported in the academic literature. We study the development of the Sustainable Energy Action Plan (SEAP) in the city of Girona (Catalonia, Spain) to analyse the opportunities and challenges this process may present in a small- to medium-sized, compact Mediterranean city. This knowledge can provide information to local authorities in similar municipalities, technical teams and decision-makers at the European level interested in enhancing the performance of such plans in the future. In this article, we explain how the SEAP was developed in Girona, the main results and proposed actions, and discuss the main setbacks. We conclude that an overarching European oversight organism is advisable to coordinate and aid local efforts.     

Toward a CO2 zero emissions energy system in the Middle East region

Climate change and energy security are global challenges requiring concerted attention and action by all of the world’s countries. Under these conditions, energy supplier and exporter countries in the Middle East region are experiencing further challenges, such as increasing domestic energy demand while energy exports have to concurrently be kept at high levels. Middle East countries process the largest proven oil and gas reserves in the world and contribute a large fraction of the world’s CO₂ emissions from the use of these as fuels both domestically and internationally. This paper addresses different policies that could dramatically change the future course of the Middle East region toward a zero CO₂ emission energy system. To this aim, an integrated energy supply–demand model has been developed to analyze required commitments including renewable energy and energy efficiency targets and the potential of nuclear power, all of which should need to be considered in order to reduce CO₂ emissions by 2100. The results indicate that nearly 43% of the global energy of the Middle East region can be supplied from non-fossil fuel resources in 2100.     

Characterization of human manure-derived biochar and energy-balance analysis of slow pyrolysis process

Biochars have received increasing attention in recent years because of their soil improvement potential, contaminant immobilization properties, and ability to function as carbon sinks. This study adopted a pyrolytic process to prepare a series of biochars from dried human manure at varying temperatures. The thermal analysis of human manure and physicochemical properties of the resulting biochars illustrated that human manure can be a favorable feedstock for biochar production. In particular, the porous texture and nutrient-rich properties of biochars produced from human manure and may significantly enhance soil fertility when used as used soil additives. A temperature range of 500–600 °C was optimal for human manure biochar production. Significantly, when the moisture content of the feedstock is lower than 57%, the system could not only harvest manure-derived biochar but also have a net energy output, which can be provide heat source for nearby users.     

Salem Revisited: Updating the MTBE Controversy

I am wronged. It is a shameful thing that you should mind these folks that are out of their wits.* *Statement of Martha Carrier (excerpt), hanged as a witch on 19 August, 1692 in Salem, Massachusetts. In all, 20 innocent persons were executed in 1692 as a result of the hysteria attending the Salem witch trials. After the executions, the court was prohibited from "reliance on spectral and intangible evidence". No prosecutions were successful thereafter. See generally, The Salem Witch Trials 1692: A Chronology of Events , at www.salemweb.com/memorial This article provides background information regarding the emerging controversies involving methyl tert -butyl ether (MTBE) and litigation involving leaking underground storage tanks (USTs) in general. It examines (1) the administrative, legislative and litigation history of MTBE in the context of the Clear Air Act and state environmental statues; (2) the importance of applicable RCRA (Resource Conservation and Recovery Act) deadlines regarding UST compliance in these cases; (3) the question of MTBE toxicity for personal injury claims; and (4) the scope of damages available in cases filed by plaintiffs who are not physically impacted by contamination. The authors conclude that the MTBE controversy does not appear to be a legitimate public health or environmental crisis, but rather is yet another speculative product of the American legal industry.