全文获取类型
收费全文 | 3923篇 |
免费 | 352篇 |
国内免费 | 1509篇 |
专业分类
安全科学 | 265篇 |
废物处理 | 167篇 |
环保管理 | 712篇 |
综合类 | 2621篇 |
基础理论 | 574篇 |
污染及防治 | 856篇 |
评价与监测 | 317篇 |
社会与环境 | 220篇 |
灾害及防治 | 52篇 |
出版年
2024年 | 7篇 |
2023年 | 53篇 |
2022年 | 118篇 |
2021年 | 130篇 |
2020年 | 120篇 |
2019年 | 148篇 |
2018年 | 153篇 |
2017年 | 184篇 |
2016年 | 243篇 |
2015年 | 222篇 |
2014年 | 280篇 |
2013年 | 355篇 |
2012年 | 371篇 |
2011年 | 401篇 |
2010年 | 307篇 |
2009年 | 409篇 |
2008年 | 233篇 |
2007年 | 282篇 |
2006年 | 276篇 |
2005年 | 257篇 |
2004年 | 171篇 |
2003年 | 165篇 |
2002年 | 147篇 |
2001年 | 116篇 |
2000年 | 105篇 |
1999年 | 95篇 |
1998年 | 71篇 |
1997年 | 61篇 |
1996年 | 63篇 |
1995年 | 68篇 |
1994年 | 39篇 |
1993年 | 28篇 |
1992年 | 30篇 |
1991年 | 13篇 |
1990年 | 14篇 |
1989年 | 4篇 |
1988年 | 8篇 |
1987年 | 6篇 |
1986年 | 4篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1981年 | 1篇 |
1980年 | 4篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有5784条查询结果,搜索用时 0 毫秒
101.
102.
103.
Polyvinylidene chloride (PVDC; polymer of 1,1-dichloroethylene) was combusted with paper in a well-controlled, small-scale incinerator at an average grate temperature of 700 °C, and then dioxins (PCDDs, PCDFs, and coplanar-PCBs) formed in the exhaust gases were analyzed by gas chromatography/mass spectrometry. PVDC lowered the combustion temperature due to its less flammable character. The amount of total dioxins (PCDDs + PCDFs + coplanar-PCBs) formed in the exhaust gas was 58.0 ng/g of a combustion sample and its toxicity equivalency quantity (TEQ) value was 0.64 ng-TEQ/g. The amount of PCDDs formed in the sample ranged from 2.33 ng/g (Cl8-isomer) to 0.048 ng/g (Cl1-isomer). The lower the number of chloride, the less production of PCDDs. On the other hand, there was no relation between the number of chloride and PCDF formation. The amount of PCDFs formed in the sample ranged from 8.02 ng/g (Cl2-isomer) to 4.46 ng/g (Cl8-isomer). A polyvinylchloride (PVC) sample produced 207 ng/g of total dioxins and a PVDC sample produced 57.4 ng/g of total dioxins when they were combusted under the same conditions. An approximately equal composition of dioxin isomers was formed from PVDC and PVC samples. Paper was found to contribute to PCDF formation when it was combusted with plastics. 相似文献
104.
New data on the vapour pressures and aqueous solubility of 1,8-dichlorooctane and 1,8-dibromooctane are reported as a function of temperature between 20 °C and 80 °C and 1 °C and 40 °C, respectively. For the vapour pressures, a static method was used during the measurements which have an estimated uncertainty between 3% and 5%. The aqueous solubilities were determined using a dynamic saturation column method and the values are accurate to within ±10%. 1,8-Dichlorooctane is more volatile than 1,8-dibromooctane in the temperature range covered (psat varies from 3 to 250 Pa and from 0.53 to 62 Pa, respectively) and is also approximately three times more soluble in water (mole fraction solubilities at 25 °C of 5.95 × 10−7 and 1.92 × 10−7, respectively). A combination of the two sets of data allowed the calculation of the Henry’s law constants and the air water partition coefficients. A simple group contribution concept was used to rationalize the data obtained. 相似文献
105.
Occurrences of pharmaceutical and personal care products as micropollutants in rivers from Romania 总被引:15,自引:0,他引:15
Moldovan Z 《Chemosphere》2006,64(11):1808-1817
The occurrence of pharmaceutical and personal care products (PPCPs) was investigated in the Somes River. The aim of this study was to obtain a first overview about the contamination of Somes River (Transylvania) with PPCPs. The samples were preconcentrated by Solid Phase Extraction (SPE) procedures and analysed by GC/MS. A number of 15 compounds including pharmaceutics, metabolites, intermediates and musk fragrances were detected in concentration ranging from 30 ng/l to 10 μg/l. The detected pharmaceuticals are included in following therapeutic groups: analgesics, antiepileptics, psychiatric, stimulants, anticoagulants, antineoplastic and disinfectants. 相似文献
106.
Broad range analysis of endocrine disruptors and pharmaceuticals using gas chromatography and liquid chromatography tandem mass spectrometry 总被引:3,自引:0,他引:3
Endocrine disrupting compounds (EDCs) and pharmaceuticals and personal care products (PPCPs) have been globally detected in impacted natural waters. The detection of trace quantities of EDCs and PPCPs in the environment is of great concern since some of these compounds have known physiological responses at low concentrations. EDCs can have a wide range of polarities, acidic and basic moieties, and exist in trace quantities, which often requires numerous complex extractions, large sample collection volumes, and multiple instrumental analyses. A comprehensive method has been developed allowing for the analysis of 58 potential EDCs in various water matrices using a single solid-phase extraction (SPE) of a 1 L sample with subsequent analyses using both gas chromatography and liquid chromatography, each coupled with tandem mass spectrometry (GC–MS/MS and LC–MS/MS). Instrument detection limits ranged between 0.12–7.5 pg with corresponding method reporting limits of 1–10 ng l−1 in water. Recoveries for most compounds were between 50% and 112% with good reproducibility (RSD 6–22%). 相似文献
107.
Vuyolwethu O. Ndabankulu Suresh Maddila 《Journal of environmental science and health. Part. B》2019,54(2):138-146
The ozone initiated oxidation of 1,3,7-trimethylxanthine (caffeine), commonly found in wastewaters as model compound is reported using cerium (Ce)/titanium dioxide (TiO2) as catalyst. The effect of pH and loading of ceria on titania were investigated. Effect of reaction conditions on degradation of caffeine based on their pseudo first-order rate constants were compared. The combination of catalyst Ce-TiO2 and ozone aeration significantly enhanced the degradation of caffeine compared to uncatalysed ozonation. The oxidation of caffeine ensued via the free radical mechanism, through enhanced ozone decomposition into OH radicals. Ce/TiO2(0.5?wt%) showed good activity in degradation of caffeine at pH 6, in both natural stream and river water samples showing about 60% total organic carbon removal in 2?h ozonation period. Using liquid chromatography-mass spectroscopy, degradation products were analysed. A reaction intermediate and one final product were positively identified. Nano-catalysts with different loadings of Ce on TiO2 synthesized by sol-gel route were characterized by scanning electron microscope, transmission electron microscopy, BET and powder X-ray diffraction spectrum techniques. The results showed that the material retained a highly ordered mesoporous structure and possessed large surface area. 相似文献
108.
城市污水再生处理工艺中发光细菌毒性变化的初步研究 总被引:7,自引:0,他引:7
保障再生水的生态安全是污水再生利用过程中非常关键的问题.本文采用发光细菌毒性测试方法测定了2个城市污水再生利用示范工程工艺流程中生物毒性的变化,尤其是可能生成有毒副产物的氯消毒过程中的毒性变化.结果表明,二级生物处理能显著降低污水的发光细菌毒性,但氯消毒显著提高了污水的毒性,并且脱氯后污水的毒性仍保持较高的水平,对生态安全造成了潜在威胁.同时,通过比较2种污水水质发现,DOC(溶解性有机碳含量)和UV254(254 nm处的紫外吸收值)较高的水样,消毒后的毒性较大,认为DOC和UV254可望作为预测污水消毒生态风险的水质指标,为污水消毒实践中确定安全合理的污水水质条件提供一定的依据. 相似文献
109.
采用机械共混法制备了EVA/CSM复合材料.系统地研究了EVA与CSM的混合比率、CSM交联及不同阻燃体系对复合材料阻燃性质的影响.结果表明,掺杂阻燃剂之后,复合材料都具有很好的阻燃性能,其中使用Sb2O3/氯乙醇混合阻燃体系,阻燃效果最好,且复合材料交联后,阻燃性能会进一步增强.同时研究了各种因素,如交联、混合比率和处理温度对复合材料收缩率的影响.当CSM含量较高或拉伸温度处于室温,收缩率都较好;而交联前,加入阻燃剂会使复合材料收缩性能降低;反之,交联后使之增加. 相似文献
110.
讨论了城市污水经过A/O工艺处理时活性污泥的二次污染问题。将原水、处理后的出水及活性污泥用甲苯萃取,萃取相经过真空浓缩后,采用GC/MS测定了样品中的有机化合物,结果表明,在A/O工艺处理城市污水过程中,活性污泥的吸附作用是主要的,降解作用是次要的;A/O工艺所排放的活性污泥仍然是一种危险的污染物。 相似文献