Nafion修饰汞膜电极微分脉冲阳极溶出伏安法测定蔬菜中的铅

采用Nafion修饰汞膜电极微分脉冲阳极溶出伏安法测定蔬菜中的铅,选择0.1 mol/L NH4NO3作为支持电解质,富集时间420 s,搅拌速度300 r/min,Nafion修饰体积10 μL,考察了共存离子的干扰.方法在0.01 μg/L～ 14.0 μg/L范围内线性良好,检出限为0.2 μg/L,铅酸电池厂附近蔬菜样品的测定结果与石墨炉原子吸收光谱法相吻合,加标回收率为89.5％～106％.     

广西北部湾蔬菜种植基地土壤中代森锌类农药残留调查

采用顶空-气相色谱-质谱法,对南宁、北海、钦州和防城港等4个北部湾区域城市蔬菜种植基地60份土壤样品中的代森锌类农药残留进行检测。结果表明,南宁市的15份土壤样品均未检出代森锌类农药残留;北海市有5份土壤样品检出代森锌类农药残留,检出率为33.3%,其质量比范围为0.005 2 mg/kg~0.034 6 mg/kg;钦州和防城港2市30份土壤样品均检出代森锌类农药残留,检出率为100%,其质量比范围为0.004 9 mg/kg~0.674 mg/kg。     

再生水—土壤—蔬菜体系中Zn的迁移

2011~2013年通过小区试验种植小白菜和萝卜,以再生水灌溉和污泥施肥,采用修正的BCR法测定了再生水、污泥、土壤、蔬菜中Zn的5种形态含量,分析Zn在再生水(污泥)-土壤-蔬菜体系中的迁移和累积特征。结果表明:2011~2013年水样中Zn含量均未超出国家《农田灌溉水质标准(GB5084—2005)》中Zn的标准。水样中水溶态B0比例较大。污泥中B0含量极少,残渣态B4含量较高。土壤中Zn的本底含量较少,经过3年的蔬菜种植和灌溉,土壤中Zn含量有增高的趋势。蔬菜中5种形态均有分布,地上部分中水溶态B0和可氧化态B3含量较高,地下部分中残渣态B4含量也较高。小白菜中Zn的含量高于萝卜。灌溉水中B0的含量对Zn在土壤和蔬菜中的迁移产生了较大影响。适当的再生水灌溉和污泥施肥可以改善土壤的缺Zn状况。     

Ammonia volatilization from a Chinese cabbage field under different nitrogen treatments in the Taihu Lake Basin, China

Ammonia(NH_3) volatilization is a major pathway of nitrogen(N) loss from soil-crop systems.As vegetable cultivation is one of the most important agricultural land uses worldwide,a deeper understanding of NH_3 volatilization is necessary in vegetable production systems.We therefore conducted a 3-year(2010–2012) field experiment to characterize NH_3 volatilization and evaluate the effect of different N fertilizer treatments on this process during the growth period of Chinese cabbage.Ammonia volatilization rate,rainfall,soil water content,p H,and soil NH_4~+were measured during the growth period.The results showed that NH_3 volatilization was significantly and positively correlated to topsoil p H and NH4+concentration.Climate factors and fertilization method also significantly affected NH_3 volatilization.Specifically,organic fertilizer(OF) increased NH_3 volatilization by 11.77%–18.46%,compared to conventional fertilizer(CF,urea),while organic–inorganic compound fertilizer(OIF) reduced NH_3 volatilization by 8.82%–12.67% compared to CF.Furthermore,slow-release fertilizers had significantly positive effects on controlling NH_3 volatilization,with a 60.73%–68.80% reduction for sulfur-coated urea(SCU),a 71.85%–78.97% reduction for biological Carbon Power~#174; urea(BCU),and a 77.66%–83.12% reduction for bulk-blend controlled-release fertilizer(BBCRF)relative to CF.This study provides much needed baseline information,which will help in fertilizer choice and management practices to reduce NH_3 volatilization and encourage the development of new strategies for vegetable planting.     

Vegetable Oil Spills - Pollution Or Over-Cautiousness?

Vegetable oil spills are relatively uncommon compared to those of mineral oil in the marine environment. Evidence from the spillages that have occurred indicate that they can cause the death of animals in the vicinity through suffocation, inhibition of feeding and other non-specific toxic effects. Smothering of the intertidal area may lead to the development of anoxic conditions with associated changes in species diversity. Polymerisation appears to be a key process in determining the persistence of these oils in the intertidal region. Experiments have indicated that indigenous bacteria are capable of degrading the oil until it polymerises and work is being directed towards determining mechanisms to aid in the degradation process. in conclusion, vegetable oils are pollutants although the risk to the marine environment is small but that does not mean we should not be prepared for such events.     

Co-processing of DVDs and CDs with vegetable cooking oil by thermal degradation

Waste DVDs and CDs were thermally degraded at 450°C by a semibatch process. In total, 40–50 wt% was converted into liquid product that consisted of phenol derivatives (∼75 wt%), bisphenol (∼10 wt%) and its derivatives, and small amounts of aromatic hydrocarbons such as benzene, toluene, ethylbenzene, dimethylbenzene, methylethylbenzene, diethylbenzene, and methylisopropyl benzene. Degradation of the polycarbonate support from DVDs and CDs was enhanced by coprocessing with vegetable cooking oil, the degradation of which gave a homologue series of hydrocarbons and organic acids with up to 25 and 18 atoms of carbon, respectively. Silver from the reflective coating on DVDs and CDs remained in the solid residue, its concentration increasing about 2.5 times compared to that of the original disks.     

沈阳市农业污染现状的初步调查

区域化、规模化和集约化的生产方式促进了沈阳市蔬菜生产和畜牧业的快速发展 ,但是也带来了一些污染问题。调查表明 ,蔬菜的硝酸盐污染状况非常严重 ,多数叶菜类蔬菜的硝酸盐含量超标 ,其中 ,茼蒿菜的硝酸盐含量高达6687.9/ mg·kg- 1 ,超标近 9倍 ;由畜牧业生产各个环节引起的环境污染问题也日趋严峻。畜牧业生产专业村镇的空气和地下水污染严重 ,已对沈阳市及其周边地区小城镇的生态环境建设构成严重影响。     

银川地区菜田土壤和蔬菜中有害元素含量及污染程度评价

对银川地区菜地土壤和蔬菜中有害元素进行调查并作出初步评价.表明该地区菜田土壤中氟、铅、汞有一定程度污染,镉污染也已露头;一定比例的蔬菜中,受到轻污染的元素有:铜、锌、铅、镉、砷和氟;汞在28.3％～53.2％的大白菜和青萝卜中受到中度及重度污染.     

The fate of exogenous iodine in pot soil cultivated with vegetables

A pot experiment was conducted to explore a more effective approach to enhancing vegetable uptake of soil iodine, with the ultimate goal of using agricultural fortification as a measure to prevent iodine deficiency disorders in local communities. Two types of iodine fertilizers were added separately to pot soil samples at various dosages. The fortified soil in each of the flower pots was seeded with one of four test crops (pakchoi, celery, pepper, and radish) in an effort to examine the effect of vegetable cultivation. The fate and residual levels of the exogenous iodine in the fortified soil samples were then monitored and quantified. The data showed that the soil iodine contents decreased with time (and hence with plant growth as well). At the second cutting, iodine from the inorganic form (KI) as the exogenous source was reduced to approximately 50% (41.6–61.0%) of the applied dose, whereas that in soil fortified with the seaweed fertilizer was down to approximately 60% (53.9–71.5%). The abilities of the edible portion of the four vegetables in accumulating the soil iodine were as follows: pakchoi > celery > radish > pepper. On the whole, iodine residues were found less in soil cultivated with vegetables. Vegetable cultivation appeared to have enhanced the soil content of the water-soluble form of iodine somewhat, especially in soil fortified with the inorganic forms. There also appeared to be a significant negative correlation between the residual iodine and its dissolution rate in soil. Overall, the results of the present study pointed toward the direction that the seaweed fertilizer tends to be a (more) preferred source of agricultural fortification in promoting human iodine nutrition.     

重庆市蔬菜基地土壤环境质量状况及对策措施

依据我国《食用农产品产地环境质量评价标准》(HJ332-2006),采用单项质量指数和综合质量指数法,以白市驿蔬菜基地为例,结合全市33个蔬菜基地监测结果,对重庆市蔬菜基地土壤环境质量进行了评价和分析,表明蔬菜基地土壤环境质量总体较好,但土壤中汞和镉等重金属出现不同程度的超标。本文分析了蔬菜基地土壤受污染的原因,提出了改善土壤环境质量的对策措施。