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181.
《Journal of environmental science and health. Part. B》2013,48(1):159-165
Abstract The region of Ribeirão Preto City, located in Southeast of Brazil, São Paulo State, is an important sugarcane, soybean, and corn producing area with a high level of pesticides utilization. This region is also an important recharge area for groundwater supply of the Guarany aquifer. Since the past ten years atrazine, simazine, ametryn, tebuthiuron, diuron, 2,4-D, picloram, and hexazinone are the main herbicides used in this area. In order to study a possible leaching of some of these herbicides into the aquifer, surface, and groundwater samples were collected in a watershed during the years of 1996 to 2003, from different locations. To detect and quantify the herbicides a GC-MS (gas chromatograph/mass spectrometry) method was used. The response of the herbicides analyzed was linear over the concentration range of 0.02 to 2.0 μg/L. Analysis of groundwater revealed that the herbicides tebuthiuron, diuron, atrazine, simazine, and ametryn were not present in the samples. In the surface water collected in 1997, ametryn was present in two out of nine locations with concentrations ranging from 0.17 and 0.23 μg/L, which is above the allowable 0.1 μg/L according to the European safety level. The leaching potential of tebuthiuron, diuron, atrazine, simazine, 2,4-D, picloram, and hexazinone has been evaluated using CMLS-94, “Chemical Movement in Layered Soil,” as simulation model. No leaching into the depth of the water table at 40 m was found. 相似文献
182.
M. Noble P. C. Oloffs R. So J. Yee F. Yuen 《Journal of environmental science and health. Part. B》2013,48(5):359-373
Abstract A tubular device has been developed making it possible to obtain layered samples of loosely aggregated, flocculent material from bogs or eutrophic lakes. The samples are up to 50 cm long and 15 cm in diameter. The sampler is free from protuberances and intact, layered samples can be taken. The tubular part of the sampler is about 85 em long, the walls of the lower 25‐cm portion harbouring a pneumatic closing mechanism which is controlled from above the water surface. An extendible handle for manipulating the sampler and for guiding it into place, is fastened to the upper end of the sampling tube. The performance and the operation of the sampler in the field are described. 相似文献
183.
Abstract This paper describes the development of apparatus suitable for direct supercritical fluid extraction of organics from water. Results are presented for the extraction of pentachlorophenol present in water at concentrations of the order of 0.1 ppm. The effect of changes in apparatus design and supercritical fluid flow rate on recovery are discussed. 相似文献
184.
《Chemosphere》2013,92(3):233-246
Organochlorine pesticides (OCPs) can cause environmental damage and human health risks since they are lipophilic compounds with high resistance to degradation and long half-lives in humans. As most persistent OCPs have been banned years ago, it is expected to find these compounds at trace levels in environment. Therefore, increasingly sensitive and reliable analytical techniques are required to ensure effective monitoring of these compounds. The aim of this review is to discuss extraction and clean-up methods used to monitor OCP residues in milk, reported in the last 20 years. To carry out this review, an exhaustive bibliographic review was conducted. Despite the disadvantages of conventional extraction and clean-up methods, such as liquid–liquid, solid-phase or Soxhlet extractions, these procedures are still used due to their reliability. New extraction methods, like solid-phase microextraction, matrix solid-phase dispersion or QuEChERS, have not been thoroughly evaluated for OCP determination in milk. Almost all the methodologies analyzed in this review presented good performance characteristics according to the performance acceptability criteria set in SANCO’s procedure. Comparison between limits of quantification (LOQ) and detection (LOD), for the reported methodologies, is not always possible due to the heterogeneity of the units. Thus, researchers should take into account an homogenization of LOD and LOQ units, according to the international regulations and MRLs established. Finally, more research is necessary to obtain the ideal methodology for OCPs determination in milk, which comprises the environmentally friendly characteristics of the new techniques and the reliability of the traditional methodologies. 相似文献
185.
固城湖春季水环境因子空间变异及其原因探讨 总被引:3,自引:1,他引:3
在现场采样数据的基础上,运用Arc GIS的地统计学组件分析了固城湖春季水环境因子空间变异规律,并从污粢源分布、水生植物密度差异方面探讨了水环境因子空间变异产生的原因.结果表明:(1)变异函教选择球状模型和高斯模型拟合水环境因子的变差曲线,从预测误差判断,拟合效果很好,因此,固城湖水环境因子的空同分布图比较真实地反映了固城湖水环境现状;(2)固城湖TN、NH4+-N基本上呈现从南到北逐渐升高的趋势,TN、NH4+-N、SD的空间变异主要是由人类活动引起,水革对TN、NH4+-N的吸收作用、SD的改善作用不明显;(3)太湖区TP基本上呈现从中西部向东逐渐升高的趋势,与大湖区水草密度的变化趋势相反;水革密度越大(大湖中南部)pH越高,而水草密度越小(航道、湖东部)pH越小;(4)中南部湖区围罔的全部拆除、港口河上游生活污水减少,都使得中南部湖区水质得到改善. 相似文献
186.
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188.
A Global Model Tracking Water, Nitrogen, and Land Inputs and Virtual Transfers from Industrialized Meat Production and Trade 总被引:1,自引:0,他引:1
Marshall Burke Kirsten Oleson Ellen McCullough Joanne Gaskell 《Environmental Modeling and Assessment》2009,14(2):179-193
Rising populations and incomes throughout the world have boosted meat demand by over 75% in the last 20years, intensifying
pressures on production systems and the natural resources to which they are linked. As a growing proportion of global meat
production is traded, the environmental impacts of production become increasingly separated from where the meat is consumed.
In this paper, we quantify the use of three important resources associated with industrial livestock production and trade—water,
land, and nitrogen—using a country-specific model that combines trade, agronomic, biogeochemical, and hydrological data. Our
model focuses on pigs and chickens, as these animals are raised predominantly in intensive systems using concentrated, compound
feeds. The results describe the geographical patterns of environmental resource use due to meat production, trade, and consumption.
We show that US feed, animal, and meat destined for export require almost as much nitrogen and land, and 20% more water, than
products destined for domestic consumption. Model results also demonstrate that among various production factors, improvements
in crop yields and animal feed conversion efficiencies result in the most significant reductions in environmental harm. By
explicitly tracking the externalities of meat production, we hope to bolster suppliers’ accountability and provide better
information to meat consumers.
相似文献
Kirsten OlesonEmail: |
189.
北京公园水体中邻苯二甲酸酯类物质的测定及其分布特征 总被引:2,自引:2,他引:2
为了正确评估北京市公园水体受PAEs污染的程度,采集了北京11个公园湖水的水样,采用固相萃取-气相色谱联用技术检测了其中六种邻苯二甲酸酯类物质(PAEs)的含量,该方法加标回收率在73%~89.3%,RSD为5.9%~18.1%,检出限在0.40~4.58mg/L。实验结果为北京公园水体中总PAEs浓度在6.4~138.1μg/L,平均值为27.9μg/L,证明北京公园水体受到不同程度的PAEs污染,主要的污染物为邻苯二甲酸二丁酯(DBP)和邻苯二甲酸双(2-乙基己基)酯(DEHP),其中东南部以及西北部的公园污染较严重。分析了PAEs在公园湖水底泥中和水体中的分布特征,结果显示,PAEs在湖水底泥中的含量明显大于在水体中的含量。 相似文献
190.