挥发性有机物污染土壤样品采样方法比较

以苯系物污染土壤样品的采集为例,比较了4种不同采样方法导致样品检测结果的差异。其中,方法 1将样品装填至广口瓶内并压实密封,方法2采用非扰动采样器采集10 g样品后转移至加有10 mL甲醇保护剂的Vial瓶中密封,方法 3用非扰动采样器采集10 g样品后直接将其密封于采样器内,方法 4用Encore采样器采样后将其密封于采样器内。结果表明,方法 2采集样品的检出率最高,其余3种方法的差异不明显,方法 2采集样品的检出结果 71%以上都大于其余3种方法。而且,对于挥发性较强的苯与甲苯,以方法 2采集的样品91%以上都大于其余3种方法,最大及平均检出浓度高出2~3个数量级。5种不同土质样品检测结果表明,对于有机质含量较低的细砂,方法2的最高及平均检出浓度均高于其余3种方法 1~3个数量级,差异随土壤有机质含量的升高而降低。可见,对于苯系物及挥发性强于苯系物的其他挥发性有机物污染土壤样品的采集,方法 2效果最优,可指定为VOCs污染场地土壤样品的采样方法。     

Point‐Nonpoint Trading – Can It Work?1

Ribaudo, Marc O. and Jessica Gottlieb, 2011. Point‐Nonpoint Trading – Can It Work? Journal of the American Water Resources Association (JAWRA) 47(1):5‐14. DOI: 10.1111/j.1752‐1688.2010.00454.x Abstract: Water quality trading between point and nonpoint sources is of great interest as an alternative to strict command and control regulations on point sources for achieving water quality goals. The expectation is that trading will reduce the costs of water quality protection, and may speed compliance. The United States Environmental Protection Agency has issued guidance to the States on developing point‐nonpoint trading programs, and United States Department of Agriculture is encouraging farmer participation. However, existing point‐nonpoint trading programs have resulted in very few trades. Supply side and demand side impediments seem to be preventing trades from occurring in most trading programs. These include uncertainty over the number of discharge allowances different management practices can produce, high transactions costs of identifying trading partners, baseline requirements that eliminate low‐cost credits, the reluctance of point sources to trade with unfamiliar agents, and the perception of some farmers that entering contracts with regulated point sources leads to greater scrutiny and potential future regulation. Many of these problems can be addressed through research and program design.     

Numerical simulation of water curtain application for ammonia release dispersion

Using water curtain system to forced mitigate ammonia vapor cloud has been proven to be an effective measure. Currently, no engineering guidelines for designing an effective water curtain system are available, due to lack of understanding of complex interactions between ammonia vapor cloud and water droplets, especially the understanding of ammonia absorption into water droplets. This paper presents numerical calculations to reproduce the continuous ammonia release dispersion with and without the mitigating influence of a downwind water curtain using computational fluid dynamic (CFD) software ANSYS Fluent 14.0. The turbulence models k–ɛ and RNG were used to simulate the ammonia cloud dispersion without downwind water curtain. The simulated results were compared with literature using the statistical performance indicators. The RNG model represents better agreement with the experimental data and the k–ɛ model generates a slightly lesser result. The RNG model coupled with Lagrangian discrete phase model (DPM) was used to simulate the dilution effectiveness of the water curtain system. The ammonia absorption was taken into account by means of user-defined functions (UDF). The simulated effectiveness of water curtains has good agreements with the experimental results. The effectiveness of water mitigation system with and without the ammonia absorption was compared. The results display that the effectiveness mainly depends on the strong air entrainment enhanced by water droplets movement and the ammonia absorption also enhances the effectiveness of water curtain mitigation system. The study indicates that the CFD code can be satisfactorily applied in design criteria for an effective mitigation system.     

Preparation and performance of arsenate (V) adsorbents derived from concrete wastes

Solid adsorbent materials, prepared from waste cement powder and concrete sludge were assessed for removal of arsenic in the form of arsenic (As(V)) from water. All the materials exhibited arsenic removal capacity when added to distilled water containing 10–700 mg/L arsenic. The arsenic removal isotherms were expressed by the Langmuir type equations, and the highest removal capacity was observed for the adsorbent prepared from concrete sludge with heat treatment at 105 °C, the maximum removal capacity being 175 mg-As(V)/g. Based on changes in arsenic and calcium ion concentrations, and solution pH, the removal mechanism for arsenic was considered to involve the precipitation of calcium arsenate, Ca₃(AsO₄)₂. The enhanced removal of arsenic for the adsorbent prepared from concrete sludge with heat treatment was thought to reflect ion exchange by ettringite. The prepared adsorbents, derived from waste cement and concrete using simple procedures, may offer a cost effective approach for arsenic removal and clean-up of contaminated waters, especially in developing countries.     

A device for sampling the mud‐water interface in eutrophic lakes and bogs for residue analysis

Abstract

A tubular device has been developed making it possible to obtain layered samples of loosely aggregated, flocculent material from bogs or eutrophic lakes. The samples are up to 50 cm long and 15 cm in diameter. The sampler is free from protuberances and intact, layered samples can be taken. The tubular part of the sampler is about 85 em long, the walls of the lower 25‐cm portion harbouring a pneumatic closing mechanism which is controlled from above the water surface. An extendible handle for manipulating the sampler and for guiding it into place, is fastened to the upper end of the sampling tube. The performance and the operation of the sampler in the field are described.     

Critical review of Integrated Water Resources Management: Moving beyond polarised discourse

Integrated Water Resource Management (IWRM) emerged as a popular concept in the water sector in the 20th century. From a highly techno-centric approach in the past, it has taken a new turn embracing Habermasian communicative rationality as a place-based nexus for multiple actors to consensually and communicatively integrate decisions in a hydrological unit. The 'how to integrate' approach had remarkable appeal worldwide in promoting authentic participation of all stakeholders. However, critics argue that the domain of water resource management is a political process of contestation and negotiation; the emphasis is on complexities, contextuality, power dynamics and the importance of analysing real world situations. They demonstrate 'how integration cannot be achieved' given the power dynamics in social interactions. These apparently contradictory discourses draw on different theoretical paradigms and polarise the discourse on IWRM, without offering constructive alternatives. To this end, this paper offers an option to complement this polarised discourse by examining 'how integration actually does take place' in a strategic context thereby facilitating consensual decisions to integrate water management for a sustainable future.     

Modeling the impacts of calcite precipitation on the epilimnion of an ultraoligotrophic, hard-water lake

A mass-balance model of calcite precipitation was developed to investigate the interactions of the varied processes governing the generation and fate of calcite in lakes. The model was used in conjunction with data to assess the evolution and impact of calcite precipitation for calcareous, ultraoligotrophic Torch Lake, Michigan (USA). This lake is an ideal setting for implementation of a baseline modeling study of calcite precipitation where the physical drivers could be evaluated without being dominated, as in many systems, by biological processes. The model provides a representation of calcite precipitation with particulate surface area changing over time, and demonstrates that it is possible for the change in water clarity to be explained by calcite precipitation employing standard optical models. Using the mass balance model to quantify the roles of the various chemical, biological and physical processes interacting in the lake's epilimnion, it was shown that the seasonal temperature rise and air-water CO₂ exchange drive calcite precipitation much more than primary production for this ultraoligotrophic system.     

Integration of long-term fish kill data with ambient water quality monitoring data and application to water quality management

Almost half (354) of all fish kills (805) in South Carolina, USA, between 1978 and 1988 occurred in the coastal zone. These kills were analyzed for causative, spatial, and temporal associations as a distinct data set and as one integrated with ambient water quality monitoring data. Estuarine kills as a result of natural causes accounted for 42.8% followed by man-induced (35.1%) and undetermined causes (22.1%). Although general pesticide usage was responsible for 53.9% of man-induced kills, weed control activities around resorts and municipal areas accounted for slightly more kills (20.9%) than did agricultural (19.8%) or vector control (13.2%) uses. A dramatic decline in agricultural-related kills has been observed since 1986 as the integrated pest management approach was adopted by many farmers. When taken with the few kills (12.0%) resulting from wastewaters, this suggests that these two land-use activities have been successfully managed via existing programs (IPM and NPDES, respectively) to minimize their contributions to estuarine fish kills. Ambient trend monitoring data demonstrated no coastal-wide dispersion of pesticide pollution. These data confirmed the nature of fish kills to be site-specific, near-field events most closely associated with the contiguous land-use practices and intensities. Typically, fish kill data are considered as event-specific data limited to the bounds of that event only. Our analysis has shown, however, that a long-term data set, when integrated with ambient water quality data, can assist in regulatory and resource management decisions for both short- and long-term planning and protection applications.