A Perspective on Nonstationarity and Water Management1

Hirsch, Robert M., 2011. A Perspective on Nonstationarity and Water Management. Journal of the American Water Resources Association (JAWRA) 47(3):436‐446. DOI: 10.1111/j.1752‐1688.2011.00539.x Abstract: This essay offers some perspectives on climate‐related nonstationarity and water resources. Hydrologists must not lose sight of the many sources of nonstationarity, recognizing that many of them may be of much greater magnitude than those that may arise from climate change. It is paradoxical that statistical and deterministic approaches give us better insights about changes in mean conditions than about the tails of probability distributions, and yet the tails are very important to water management. Another paradox is that it is difficult to distinguish between long‐term hydrologic persistence and trend. Using very long hydrologic records is helpful in mitigating this problem, but does not guarantee success. Empirical approaches, using long‐term hydrologic records, should be an important part of the portfolio of research being applied to understand the hydrologic response to climate change. An example presented here shows very mixed results for trends in the size of the annual floods, with some strong clusters of positive trends and a strong cluster of negative trends. The potential for nonstationarity highlights the importance of the continuity of hydrologic records, the need for repeated analysis of the data as the time series grow, and the need for a well‐trained cadre of scientists and engineers, ready to interpret the data and use those analyses to help adjust the management of our water resources.     

Integrating soil carbon cycling with that of nitrogen and phosphorus in the watershed model SWAT: Theory and model testing

In this paper we describe and test a sub-model that integrates the cycling of carbon (C), nitrogen (N) and phosphorus (P) in the Soil Water Assessment Tool (SWAT) watershed model. The core of the sub-model is a multi-layer, one-pool soil organic carbon (S_C) algorithm, in which the decomposition rate of S_C and input rate to S_C (through decomposition and humification of residues) depend on the current size of S_C. The organic N and P fluxes are coupled to that of C and depend on the available mineral N and P, and the C:N and N:P ratios of the decomposing pools. Tillage explicitly affects the soil organic matter turnover rate through tool-specific coefficients. Unlike most models, the turnover of soil organic matter does not follow first order kinetics. Each soil layer has a specific maximum capacity to accumulate C or C saturation (S_x) that depends on texture and controls the turnover rate. It is shown in an analytical solution that S_x is a parameter with major influence in the model C dynamics. Testing with a 65-yr data set from the dryland wheat growing region in Oregon shows that the model adequately simulates the S_C dynamics in the topsoil (top 0.3 m) for three different treatments. Three key model parameters, the optimal decomposition and humification rates and a factor controlling the effect of soil moisture and temperature on the decomposition rate, showed low uncertainty as determined by generalized likelihood uncertainty estimation. Nonetheless, the parameter set that provided accurate simulations in the topsoil tended to overestimate S_C in the subsoil, suggesting that a mechanism that expresses at depth might not be represented in the current sub-model structure. The explicit integration of C, N, and P fluxes allows for a more cohesive simulation of nutrient cycling in the SWAT model. The sub-model has to be tested in forestland and rangeland in addition to agricultural land, and in diverse soils with extreme properties such high or low pH, an organic horizon, or volcanic soils.     

Local calibration of coliforms parameters of water quality problem at Igapó I Lake, Londrina, Paraná, Brazil

This article presents results concerning the local calibration of the transport parameters (longitudinal and transversal diffusions and decay coefficient) for a two-dimensional problem of water quality at Igapó I Lake, located in Londrina, Paraná, Brazil, using fecal coliforms as an indicator of water quality. The simulation of fecal coliforms concentrations all over the water body is conducted by means of a structured discretization of the geometry of Igapó I Lake, together with the finite difference and finite element methods. By using the velocity field, modeled by the Navier-Stokes and Poisson equations, the flow of fecal coliforms is described by means of a transport model, which considers advective and diffusive processes, as well as a process of fecal coliforms decay. In the checkpoint, the longitudinal and transversal diffusion coefficients and the coliforms decay coefficient that best fitted the value of the fecal coliforms concentration were D_x = D_y = 0.001 m²/h and k = 0.5 d⁻¹ = 0.02083 h⁻¹. A qualitative and quantitative analysis of the numerical simulations conducted in function of the diffusion coefficients and of the coliforms decay parameter provided a better understanding of the local water quality at Igapó I Lake.     

水和废水中阴离子表面活性剂测定干扰因素试验研究

对二氮杂菲萃取分光光度法测定水和废水中阴离子表面活性剂的主要干扰因素进行了试验研究.设计了温度过低、浑浊带色和混溶乳化3种干扰试验方案,探讨了各干扰因素在不同工况下的试验结果、影响程度及消除措施.提出温度过低须在测定前提高环境温度,以确保显色反应完全;浑浊带色须在测定中采用色(浊)度校正法消除干扰;混溶乳化可在测定中利...     

石墨炉原子吸收法测定水中铅的质量控制指标研究

通过对全国9个省份82家实验室监测数据的分析,研究确定了石墨炉原子吸收法测定水中铅的质量控制指标。建议控制值为：标准样品室内相对标准偏差（RSD）≤5.0%,实际样品相对偏差（RD）≤30.0%,标准样品室间相对标准偏差（RSD’）≤10%,标准样品相对误差（RE）≤±8.0%,加标回收率范围为90%～115%,同时还对方法的重复性和再现性指标进行了验证性研究。     

Visible light photocatalytic bismuth oxide coatings are effective at suppressing aquatic cyanobacteria and degrading free-floating genomic DNA

Access to safe drinking water free from microbial pollution is an issue of global concern. The use of photocatalytic thin films in water treatment has focused on titanium dioxide, which requires UV-activation, proving a potential barrier to upscaling and implementation in the real world. Visible-light-activated photocatalytic thin films, such as bismuth oxide, have recently been shown to have antimicrobial properties. However, more understanding of the photocatalytic effect on the microbial population in water is required. Glass beads coated with bismuth oxide were incubated with either Microcystis aeruginosa, Anabaena sp. or free-floating genomic DNA. The presence of bismuth oxide-coated glass beads was able to rapidly stop a population of cyanobacteria from increasing. The coated beads were also able to degrade genomic DNA. Leachate from the beads showed no increase in toxicity against human liver cells. This data demonstrates the efficacy of bismuth oxide-coated glass beads for controlling potentially dangerous cyanobacterial populations, whilst potentially reducing the amount of free-floating genomic DNA (an essential issue in the face of antimicrobial resistance) – all of which should be essential considerations in emerging water treatment technologies.     

Electrochemical reduction of Cr(VI) in the presence of sodium alginate and its application in water purification

Chromium (Cr) is used in many manufacturing processes, and its release into natural waters is a major environmental problem today. Low concentrations of Cr(VI) are toxic to human health and living organisms due to the carcinogenic and mutagenic nature of this mineral. This work examined the conversion of Cr(VI) to Cr(III) via electrochemical reduction using gold electrode in an acidic sodium alginate (SA) solution and subsequent removal of the produced Cr(III)-SA by the polymer-enhanced ultrafiltration (PEUF) technique. A solution of SA in nitric acid was used both as an electrolytic medium during the voltammetric measurements and bulk electrolysis and as an extracting agent during the PEUF technique. The electroanalysis of Cr(VI) was performed by linear sweep voltammetry in the presence of acidic SA solution to study its voltammetric behavior as a function of the Cr(VI) concentration, pH, presence of Cr(III), SA concentration and scan rate. In addition, the quantitative reduction of Cr(VI) to Cr(III) was studied through the bulk electrolysis technique.The results showed efficient reduction with well-defined peaks at approximately 0.3 V vs. Ag/AgCl, using a gold working electrode. As the pH increased, the reduction signal strongly decreased until its disappearance. The optimum SA concentration was 10 mmol/L, and it was observed that the presence of Cr(III) did not interfere in the Cr(VI) electroanalysis. Through the quantitative reduction by bulk electrolysis in the presence of acidic SA solution, it was possible to reduce all Cr(VI) to Cr(III) followed by its removal via PEUF.     

A provider-based water planning and management model--WaterSim 4.0--for the Phoenix Metropolitan Area

Uncertainty in future water supplies for the Phoenix Metropolitan Area (Phoenix) are exacerbated by the near certainty of increased, future water demands; water demand may increase eightfold or more by 2030 for some communities. We developed a provider-based water management and planning model for Phoenix termed WaterSim 4.0. The model combines a FORTRAN library with Microsoft C# to simulate the spatial and temporal dynamics of current and projected future water supply and demand as influenced by population demographics, climatic uncertainty, and groundwater availability. This paper describes model development and rationale. Water providers receive surface water, groundwater, or both depending on their portfolio. Runoff from two riverine systems supplies surface water to Phoenix while three alluvial layers that underlie the area provide groundwater. Water demand was estimated using two approaches. One approach used residential density, population projections, water duties, and acreage. A second approach used per capita water consumption and separate population growth estimates. Simulated estimates of initial groundwater for each provider were obtained as outputs from the Arizona Department of Water Resources (ADWR) Salt River Valley groundwater flow model (GFM). We compared simulated estimates of water storage with empirical estimates for modeled reservoirs as a test of model performance. In simulations we modified runoff by 80%-110% of the historical estimates, in 5% intervals, to examine provider-specific responses to altered surface water availability for 33 large water providers over a 25-year period (2010-2035). Two metrics were used to differentiate their response: (1) we examined groundwater reliance (GWR; that proportion of a providers' portfolio dependent upon groundwater) from the runoff sensitivity analysis, and (2) we used 100% of the historical runoff simulations to examine the cumulative groundwater withdrawals for each provider. Four groups of water providers were identified, and discussed. Water portfolios most reliant on Colorado River water may be most sensitive to potential reductions in surface water supplies. Groundwater depletions were greatest for communities who were either 100% dependent upon groundwater (urban periphery), or nearly so, coupled with high water demand projections. On-going model development includes linking WaterSim 4.0 to the GFM in order to more precisely model provider-specific estimates of groundwater, and provider-based policy options that will enable "what-if" scenarios to examine policy trade-offs and long-term sustainability of water portfolios.     

废水中氨氮的去除与利用

化学沉淀剂可去除废水中的氨氮，并得到有用复合肥ＭｇＮＨ４ＰＯ４。探讨了诸反应对氨氮去除率的影响。     

本溪市水环境承载力及指标体系

水环境承载力是近年提出的一个新概念，它是用以定量描述水资源和水污染及其有关参数的一个综合指标，其含义为：在一定的自然环境条件和特定的社会经济发展模式下，区域水环境（包括水资源和水污染）对其社会经济发展的支撑能力．水环境承载力是由水环境系统结构决定的，它体现了水环境与人类社会经济活动之间的联系．对一个城市而言，不同的社会经济发展速度规模及不同的水环境治理对策，其水环境承载力各不相同，水环境承载力是区域自然条件、区域经济发展模式（发展的方向和发展的速度）及相应的水资源与水污染防治对策的函数．水环境承载力具有客观性、变动性和可控性三个基本特点，利用水环境承载力可以评判城市水环境对其社会经济发展承载大小．为区域社会经济与水环境协调发展提供决策依据．