Life cycle assessment of spray dried soluble coffee and comparison with alternatives (drip filter and capsule espresso)

This paper aims to evaluate the environmental burdens associated with spray dried soluble coffee over its entire life cycle and compare it with drip filter coffee and capsule espresso coffee. It particularly aims to identify critical environmental issues and responsibilities along the whole life cycle chain of spray dried coffee. This life cycle assessment (LCA) specifically uses foreground data obtained directly from coffee manufacturers and suppliers. Aside from energy consumption and greenhouse gases emissions, water footprint is also studied in detail, including regionalization of water impacts based on the ecological scarcity method 2006. Other impact categories are screened using the IMPACT 2002+ impact assessment method.The overall LCA results for a 1 dl cup of spray dried soluble coffee amounts approximately to 1 MJ of primary non-renewable energy consumption, to emissions of 0.07 kg of CO_2-eq, and between 3 and 10 l of non-turbined water use, depending on whether or not the coffee cultivation is irrigated and wet treated. When considering turbined water, use can be up to 400 l of water per cup. Pouch – and to a lesser extent metal can packaging alternatives – show lower environmental burdens than glass or sticks.On average, about one half of the environmental footprint occurs at a life cycle stage under the control of the coffee producer or its suppliers (i.e., during cultivation, treatment, processing, packaging up to distribution, along with advertising) and the other half at a stage controlled by the user (shopping, appliances manufacturing, use and waste disposal). Key environmental parameters of spray dried soluble coffee are the amount of extra water boiled and the efficiency of cup cleaning during use phase, whether the coffee is irrigated or not, as well as the type and amount of fertilizer used in the coffee field. The packaging contributes to 10% of the overall life cycle impacts.Compared to other coffee alternatives, spray dried soluble coffee uses less energy and has a lower environmental footprint than capsule espresso coffee or drip filter coffee, the latter having the highest environmental impacts on a per cup basis. This study shows that a broad LCA approach is needed to help industry to minimize the environmental burdens directly related to their products. Including all processes of the entire system is necessary i) to get a comprehensive environmental footprint of the product system with respect to sustainable production and consumption, ii) to share stakeholders responsibility along the entire product life cycle, and iii) to avoid problem shifting between different life cycle stages.     

Best linear unbiased estimators for the simple linear regression model using ranked set sampling

When sample observations are expensive or difficult to obtain, ranked set sampling is known to be an efficient method for estimating the population mean, and in particular to improve on the sample mean estimator. Using best linear unbiased estimators, this paper considers the simple linear regression model with replicated observations. Use of a form of ranked set sampling is shown to be markedly more efficient for normal data when compared with the traditional simple linear regression estimators.     

Development of a new hydrocarbon index for oil-in-water

A new robust method for determination of hydrocarbons in water without use of Freon^™ or other halogenated solvents has been validated and subjected to an interlaboratory exercise. The method is based on extraction with a light hydrocarbon (boiling point in the 39–69°C range), followed by cleanup for removal of polar components and detection by gas chromatography (GC) with flame ionisation (FID) detection. The performance characteristics of the method are comparable with that of the previous Freon-IR method with recoveries in the 60–80% range and reproducibility (between laboratory variations) of about 30%.

A screening method for hydrocarbons in the range 5 ppm and above based on infrared spectroscopy (IR), and a promising method for detection of low levels based on solid phase extraction (SPE) has been tested and validated.     

PCDDs and PCDFs in food samples from Catalonia, Spain. An assessment of dietary intake

Food samples from local markets and supermarkets of Tarragona (Catalonia, Spain) were analyzed for PCDD/F concentrations. On lipid basis, PCDD/F levels in meat, fish, eggs, and fats and oils were similar or lower than those found in other countries. By contrast, in general terms PCDD/F levels in milk, vegetables, and cereals showed higher levels than those previously reported. The total dietary PCDD/F intake by the population of Tarragona was estimated to be 210 pg I-TEQ/day. This value is higher than the dietary intake of PCDD/Fs found in a number of surveys from other countries. However, when total dietary intake of PCDD/Fs was calculated including only fish and seafood, meat, milk and dairy products, eggs, and fats and oils, a dietary intake of PCDD/Fs of 117 pg I-TEQ/day was obtained. This intake is in the same range than that reported for different regions and countries. The results of the present study show that food groups such as vegetables, fruits, and cereals should not be excluded to estimate the total dietary intake of PCDD/Fs by general populations, especially in those countries and/or regions in which their consumptions are notable.     

Criteria for equitable allocations: the heart of international water conflict

At the heart of most international water conflicts is the question of 'equitable' allocations, criteria for which are vague and often contradictory. However, application of an equitable water-sharing agreement along the volatile waterways of the globe is a prerequisite to hydropolitical stability. This article explores the question of equity measures for water-sharing agreements in the context of global hydropolitics and is divided into three parts. The Introduction provides a brief summary of the general principles of equitable allocations. The second part of the paper describes the practice of water resources allocations as exemplified in the Transboundary Freshwater Dispute Database - a computerized database of 149 treaties relating to international water resources compiled at Oregon State University; 49 of these treaties delineate specific water allocations. The third and fourth parts of the article contrast the principles and practice of water equity. It is noticeable how rarely the general principles are explicitly invoked, particularly the extreme principles of absolute sovereignty or absolute riverain integrity. Most treaties favor existing uses, and/or guarantees to downstream riparians. It is interesting that, while many international water negotiations begin with differing legal interpretations of rights, they often shift to a needs-based criteria for water allocations. Mostly, one is struck by the creativity of the negotiators in addressing specific language to each very specific local setting and concerns.     

Electroconductive RGO-MXene membranes with wettability-regulated channels: improved water permeability and electro-enhanced rejection performance

● Electroconductive RGO-MXene membranes were fabricated. ● Wettable membrane channels were established between RGO and MXene nanosheets. ● Hydrophilic MXene reduces the resistance of water entering the membrane channels. ● Water permeance of RGO-MXene membrane is 16.8 times higher than that of RGO membrane. ● Electro-assistance can enhance the dye rejection performance of RGO-MXene membrane. Reduced graphene oxide (RGO) membranes are theoretically more conducive to the rapid transport of water molecules in their channels compared with graphene oxide (GO) membranes, as they have fewer oxygen-containing functional groups and more non-oxidized regions. However, the weak hydrophilicity of RGO membranes inhibits water entry into their channels, resulting in their low water permeability. In this work, we constructed wettable RGO-MXene channels by intercalating hydrophilic MXene nanosheets into the RGO membrane for improving the water permeance. The RGO-MXene composite membrane exhibits high pure water permeance of 62.1 L/(m²·h·bar), approximately 16.8 times that of the RGO membrane (3.7 L/(m²·h·bar)). Wettability test results and molecular dynamics simulations suggest that the improved water permeance results from the enhanced wettability of RGO-MXene membrane and increased rate of water molecules entering the RGO-MXene channels. Benefiting from good conductivity, the RGO-MXene membrane with electro-assistance exhibits significantly increased rejection rates for negatively charged dyes (from 56.0% at 0 V to 91.4% at 2.0 V for Orange G) without decreasing the permeate flux, which could be attributed to enhanced electrostatic repulsion under electro-assistance.     

黄土窑洞构造防水技术的工程试验研究

介绍了利用土壤水动力学中止水势在层状土中的阻水原理，以防止黄土窑洞在50a一遇的降雨过程中，产生渗漏雨导致坍窑成灾的工程试验。讨论了双层或三层结构在3a的实验观测中防水减渗过程方面的有效性和适用性。     

近年来淮河干流区水质变化及原因分析

频繁的水旱灾害和严重的水污染是治理淮河的两大难题,入洪泽湖口以上的淮河干流区尤其突出。本文主要分析了近年来淮河干流区的水质情况。首先简要介绍了淮河流域的自然和水环境背景,然后分析了干流区水质的时空变化趋势及其原因。最后对淮河治理存在的问题进行了总结。从总体上看,淮河流域的水污染仍十分严重,防污治污工作任重而道远。     

A system dynamics model to facilitate public understanding of water management options in Las Vegas,Nevada

Water managers increasingly are faced with the challenge of building public or stakeholder support for resource management strategies. Building support requires raising stakeholder awareness of resource problems and understanding about the consequences of different policy options. One approach that can help managers communicate with stakeholders is system dynamics modeling. Used interactively in a public forum, a system dynamics model can be used to explain the resource system and illustrate the effects of strategies proposed by managers or suggested by forum participants. This article illustrates the process of building a strategic-level system dynamics model using the case of water management in Las Vegas, Nevada. The purpose of the model was to increase public understanding of the value of water conservation in Las Vegas. The effects of policies on water supply and demand in the system are not straightforward because of the structure of the system. Multiple feedback relationships lead to the somewhat counterintuitive result that reducing residential outdoor water use has a much greater effect on water demand than reducing indoor water use by the same amount. The model output shows this effect clearly. This paper describes the use of the model in research workshops and discusses the potential of this kind of interactive model to stimulate stakeholder interest in the structure of the system, engage participant interest more deeply, and build stakeholder understanding of the basis for management decisions.     

西北地区水资源承载力弹性区间综合分析

阐述了水资源承载力的内涵,通过分析弹簧的弹性形变引出了水资源承栽力的弹性区间,并根据西北地区的实际情况得出生态水的用量决定水资源承载力弹性区间的范围。定量分析了节水系数与污水处理率对生态用水量的影响,最后提出了增加西北地区水资源承栽力弹性区间的对策。