再生水回灌地下水风险管理建议

随着经济发展、城市化速度的加快,缺水问题日益严重。再生水人工地下回灌作为水资源回用的一种新方式,已成为解决区域水资源短缺的一种有效措施。通过对再生水回灌地下水风险分析和对国内外再生水回灌地下水应用与管理现状进行梳理,为我国的再生水回灌地下水风险管理提出对策和建议。     

Determination of Commonly Used Herbicides in Surface Water Using Solid-Phase Extraction and Dual-Column HPLC-DAD

The present study describes the application of different solid-phase extraction techniques for the extraction, separation, and quantitative determination of 10 commonly used herbicides with different chemical structures (chlorsulfuron, diuron, bentazone, linuron, chlorpropham, fenoxoprop-ethyl, MCPA, diclofop-methyl, fluazifop-butyl, trifluraline) in water. Octadecyl (C₁₈) Empore extraction disks, octadecyl (C₁₈), and stryene divinylbenzene (SDB) Bond Elut Env cartridges were compared for solid-phase extraction efficiency. Herbicides were separated and quantified by reversed-phase high performance liquid chromatography with diode-array detection (HPLC-DAD) with simultaneous separation on two columns of differing polarity (C₁₈ and CN) to confirm identification. Analytical separation was performed simultaneously on C₁₈ and CN columns. Reanalysis of the sample extracts on a (cyano) CN column were used to confirm the identity of these compounds. Method optimization and validation parameters were presented in this work. Recoveries varied from 76.0% to 99.0% for C₁₈ disks, from 75.1% to 100.0% for C₁₈ cartridges, and from 54.0% to 98.0% for SDB cartridges over concentrations at 0.025–0.4 μg L^?1. The limits of detection were 0.012–0.035 μg L^?1.     

Do plants’ emissions respond to ambient environmental quality? Evidence from the clean water act

In this paper we show that plants respond to downstream ambient water quality after controlling for permitted levels of pollution. We find if past water quality declines by one percent, plants reduce current pollution by 0.35 percent. The magnitude of this coefficient is comparable to the coefficient on permitted discharge levels i.e. regulatory stringency itself. Results are consistent with two mechanisms. First, a decline in water quality may lead to more stringent permits that would raise the cost of abatement of a plant significantly. Second, the plant is likely to be subject to increased public pressure in response to poor water quality. Indeed, as expected, the impact of water quality becomes stronger in locations with higher median household income, higher percent carpooling to work, or lower percent of manufacturing employment but surprisingly with lower median age of residents, lower percent with bachelor׳s degree or higher percent of families with children.     

Integrating empirical and heuristic knowledge in a KBS to approach stream eutrophication

The nutrient enrichment of rivers and its consequences are among the most severe water quality problems in Europe, causing eutrophication and other problems. The decision-making processes involved in the management of these problems require extensive human expertise from people who deal directly with day-to-day stream problems, as well as empirical knowledge based on scientific research. This means that eutrophication is a complex problem, the optimal management of which requires an integrated and multidisciplinary approach. This approach can be taken using a Knowledge-Based System (KBS) built upon the concepts and methods of human reasoning. Accordingly, a KBS was developed within the STREAMES project. In this KBS most of the knowledge needed for managing eutrophication problems was organised and structured in the form of a decision tree (DT). The methodology specially developed to build this KBS, as well as the internal structure of the eutrophication decision tree, is presented here. The good DT obtained led to consider the KBS a suitable tool to support the management of eutrophication.     

铋和石墨烯改性金属有机框架对碘离子的吸附性能

采用一步法制备石墨烯(GO)和铋[Bi(Ⅲ)]改性沸石咪唑酯骨架结构(ZIF-8),得到GZIF和Bi@GZIF吸附剂,并用X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)及扫描电镜(SEM)对制备的吸附剂进行表征。结果显示,改性后ZIF-8晶体结构没有被破坏,表面形态及表面基团发生了变化,对碘离子的吸附能力增强,吸附速度加快,尤其是Bi@GZIF在5 min内完成吸附88.3%,最大吸附容量达197.2 mg/g。     

Mass balance modeling to elucidate historical and continuing sources of dioxin into an urban estuary

Polychlorinated dibenzo-p-dioxins and dibenzofurans (dioxins) are typically found in sediment, water and tissue as in the case of the Houston Ship Channel and Upper Galveston Bay (HSC–UGB) in Texas studied in this research. While hydrodynamic and fate and transport models are important to understand dioxin distribution in the various media, it is difficult to assimilate modeling results into a decision framework without appropriate tools that can aid in the interpretation of the simulated data. This paper presents the development of a mass-balance modeling tool linked to RMA2 and WASP models of the HSC–UGB system for 2002–2005. The mass-balance tool was used to aggregate modeling results spatially and temporally and estimate the relative contribution of sediments to dioxin loading into the Channel in comparison to runoff, deposition, and permitted effluent discharges. The total sediment associated-dioxin load into the system calculated using the mass balance model was 2.34 × 10⁷ ng d⁻¹ (almost 86% of the toxic equivalent load), and the re-deposited load to the sediment from the water column was 1.48 × 10⁷ ng-TEQ d⁻¹, such that 8.6 × 10⁶ ng-TEQ d⁻¹ or approximately 69% of the average daily dioxin flux is transported between model segments as sediment. The external loads to the system contribute approximately 3.83 × 10⁶ ng-TEQ d⁻¹, a value that is an order of magnitude smaller when compared to the contribution from sediment. These findings point to the need for sediment remediation strategies that take into account the spatial locations within the system that serve as sediment sources to dioxin in the water column.     

Determination of Cd,Cr, Cu,Pb and Zn from various water samples with use of FAAS techniques after the solid phase extraction on rice bran

A facile and novel method has been developed for the determination of cadmium, chromium, copper, lead, and zinc from various water samples using FAAS. In the present investigation, a syringe was loaded with sorbent (rice bran) for the separation and enrichment of cadmium, chromium, copper, lead, and zinc, prior to their analysis by flame atomic absorption spectrometry which was described to substitute the batch and column techniques. The syringe was loaded with 2.0 g of sorbent in order to retain the analyte elements. Six milliliter of sample solution (pH 8.0 ± 0.2) was drawn into the syringe in 15 s and discharged over a period of 15 s. Then, 2.0 M HCl eluent was drawn into the syringe and ejected back to desorb the analyte elements. At the optimum conditions, the percentage recoveries of Cd, Cr, Cu, Pb, and Zn was in the range of 95.5–99.4% with SD of 0.10%. The elements could be concentrated by drawing and discharging several portions of sample successively. The detailed study of various interferences made the confirmation of the method highly selective. The risk of contamination is less than that with the column technique. The method was successfully applied for the determination of Cd, Cr, Cu, Pb, and Zn in spiked and natural water samples. The results obtained are in good agreement with the reported methods at the 95% confidence level.     

Water policy implementation in the state of São Paulo,Brazil: Key challenges and opportunities

Challenges in implementing water planning and management are common, and the effective implementation of integrated water policies is yet to occur. In Brazil, the state of São Paulo enacted a Water Act in 1991 to ensure water availability for current and future generations based on the principles of decentralization, participation and integration. This research addresses water policy implementation issues by conducting an exploratory case study in the state of São Paulo. Factors affecting the water policy implementation process were analyzed, together with some water resources management practices. The findings indicate four dimensions of key challenges: institutional and governance, political, financial and technical. The stakeholders believe the political and the institutional and governance challenges are more important than the technical and financial ones. Additionally, the results show different levels of involvement in the areas of water policy strategy, the planning and decision-making process, and implementation by the different stakeholders groups. Stakeholders external to the water sector and from local government were considered to be less involved in water-related issues, when compared with stakeholders from the water sector. The study recommends a change in current institutional and governance arrangements in order to influence decisions and investments in different levels and sectors.     

Mainstreaming investments in watershed services to enhance water security: Barriers and opportunities

Watersheds are under increasing pressure worldwide, as expanding human activities coupled with global climate change threaten the water security of people downstream. In response, some communities have initiated investments in watershed services (IWS), a general term for policy-finance mechanisms that mitigate diverse watershed threats and promote ecosystem-based adaptation. Here, we explore the potential for increasing the uptake and impact of IWS, evaluating what limits its application and how institutional, financial, and informational barriers can be overcome. Our analysis complements the growing literature on individual programs by identifying levers at regional and global scales. We conclude that mainstreaming IWS as a cost-effective strategy alongside engineered approaches will require advances that (i) lower institutional barriers to implementation and participation in IWS; (ii) introduce structural market changes and standards of practice that account for the value of watersheds’ natural capital; (iii) develop practical tools and metrics of IWS costs and benefits; and (iv) share success stories of replicable institutional and financial models applied in varied contexts.     

Institutional networks and adaptive water governance in the Klamath River Basin,USA

Polycentric networks of formal organizations and informal stakeholder groups, as opposed to centralized institutional hierarchies, can be critically important for strengthening the capacity of governance systems to adapt to unexpected social and biophysical change. Adaptive governance is one type of environmental governance characterized by the emergence of networks that stimulate adaptive capacity through increases in social-learning, communication, trust, public participation and adaptive management. However, detecting and analyzing adaptive governance networks remains elusive, especially given contexts of highly contested resource governance such as large-scale negotiations over water use. Research methods such as social network analysis (SNA) are often infeasible as they necessitate collecting in-depth and politically sensitive personal data from a near-complete set of actors or organizations in a network. Here we present a method for resolving this problem by describing the results of an institutional SNA aimed at characterizing the changing governance network in the Klamath River Basin, USA during a period of contested negotiations over water. Through this research, we forward a method of institutional SNA useful when an individual or egocentric approach to SNA is problematic for political, logistical or financial reasons. We focus our analysis on publically available data signaling changes in formal relationships (statutory, regulatory, contractual) between organizations and stakeholder groups. We find that employing this type of SNA is useful for describing potential and actual transitions in governance that yield increases in adaptive capacity to respond to social and biophysical surprises such as increasing water scarcity and changes in water distribution.