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711.
Degradation of azo dyes in water by Electro-Fenton process 总被引:19,自引:0,他引:19
Elodie?Guivarch Stephane?Trevin Claude?Lahitte Mehmet?A.?OturanEmail author 《Environmental Chemistry Letters》2003,1(1):38-44
The degradation of the azo dyes azobenzene, p-methyl red and methyl orange in aqueous solution at room temperature has been studied by an advanced electrochemical oxidation
process (AEOPs) under potential-controlled electrolysis conditions, using a Pt anode and a carbon felt cathode. The electrochemical
production of Fenton's reagent (H2O2, Fe2+) allows a controlled in situ generation of hydroxyl radicals (·OH) by simultaneous reduction of dioxygen and ferrous ions on the carbon felt electrode. In turn, hydroxyl radicals react
with azo dyes, thus leading to their mineralization into CO2 and H2O. The chemical composition of the azo dyes and their degradation products during electrolysis were monitored by high performance
liquid chromatography (HPLC). The following degradation products were identified: hydroquinone, 1,4-benzoquinone, pyrocatechol,
4-nitrocatechol, 1,3,5-trihydroxynitrobenzene and p-nitrophenol. Degradation of the initial azo dyes was assessed by the measurement of the chemical oxygen demand (COD). Kinetic
analysis of these data showed a pseudo-first order degradation reaction for all azo dyes. A pathway of degradation of azo
dyes is proposed. Specifically, the degradation of dyes and intermediates proceeds by oxidation of azo bonds and aromatic
ring by hydroxyl radicals. The results display the efficiency of the Electro-Fenton process to degrade organic matter.
Electronic Publication 相似文献
712.
K. Srogi 《Environmental Chemistry Letters》2007,5(4):169-195
Polycyclic aromatic hydrocarbons (PAHs) are a large group of organic compounds with two or more fused aromatic rings. They
have a relatively low solubility in water, but are highly lipophilic. Most of the PAHs with low vapour pressure in the air
are adsorbed on particles. When dissolved in water or adsorbed on particulate matter, PAHs can undergo photodecomposition
when exposed to ultraviolet light from solar radiation. In the atmosphere, PAHs can react with pollutants such as ozone, nitrogen
oxides and sulfur dioxide, yielding diones, nitro- and dinitro-PAHs, and sulfonic acids, respectively. PAHs may also be degraded
by some microorganisms in the soil. PAHs are widespread environmental contaminants resulting from incomplete combustion of
organic materials. The occurrence is largely a result of anthropogenic emissions such as fossil fuel-burning, motor vehicle,
waste incinerator, oil refining, coke and asphalt production, and aluminum production, etc. PAHs have received increased attention
in recent years in air pollution studies because some of these compounds are highly carcinogenic or mutagenic. Eight PAHs
(Car-PAHs) typically considered as possible carcinogens are: benzo(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene,
benzo(a)pyrene (B(a)P), dibenzo(a,h)anthracene, indeno(1,2,3-cd)pyrene and benzo(g,h,i)perylene. In particular, benzo(a)pyrene
has been identified as being highly carcinogenic. The US Environmental Protection Agency (EPA) has promulgated 16 unsubstituted
PAHs (EPA-PAH) as priority pollutants. Thus, exposure assessments of PAHs in the developing world are important. The scope
of this review will be to give an overview of PAH concentrations in various environmental samples and to discuss the advantages
and limitations of applying these parameters in the assessment of environmental risks in ecosystems and human health. As it
well known, there is an increasing trend to use the behavior of pollutants (i.e. bioaccumulation) as well as pollution-induced
biological and biochemical effects on human organisms to evaluate or predict the impact of chemicals on ecosystems. Emphasis
in this review will, therefore, be placed on the use of bioaccumulation and biomarker responses in air, soil, water and food,
as monitoring tools for the assessment of the risks and hazards of PAH concentrations for the ecosystem, as well as on its
limitations. 相似文献
713.
Izaskun Zorita Joana Larreta Natalia Montero José Germán Rodríguez Javier Franco Ángel Borja 《Chemistry and Ecology》2013,29(5):432-445
Bioaccumulation and biological effects of pollution were assessed in mussels (Mytilus galloprovincialis) caged for one month at three sites in the Oiartzun estuary (south-eastern Bay of Biscay, Spain) with the aim of evaluating their usefulness within the investigative monitoring defined in the European Union Water Framework Directive (WFD). The highest concentrations of organic contaminants determined in mussels' tissue were detected towards the inner part of the estuary but no gradient pattern was found for metal bioaccumulation. Population fitness responses measured as condition index, stress on stress and gonad index were similar in all caged mussels and did not follow the organic pollution gradient. However, biomarkers determined at tissue, cell and protein level (histopathology, micronuclei frequency, malondialdehyde levels and vitellogenin-like protein levels) revealed a higher stress syndrome at the inner part of the estuary showing signs of genotoxicity, oxidative stress and endocrine disruption. Overall, the integrated chemical–biological approach in connection with mussel caging technique proved to be a useful tool to assess environmental pollution, allowing a better understanding of the cause–effect relationship within the investigative monitoring defined in the WFD. 相似文献
714.
Xuemin Hao Guanlong Wang Shuo Chen Hongtao Yu Xie Quan 《Frontiers of Environmental Science & Engineering》2019,13(5):77
715.
716.
An overview of the methods used in the characterisation of natural organic matter (NOM) in relation to drinking water treatment 总被引:9,自引:0,他引:9
Matilainen A Gjessing ET Lahtinen T Hed L Bhatnagar A Sillanpää M 《Chemosphere》2011,83(11):1431-1442
Natural organic matter (NOM) is found in all surface, ground and soil waters. During recent decades, reports worldwide show a continuing increase in the color and NOM of the surface water, which has an adverse affect on drinking water purification. For several practical and hygienic reasons, the presence of NOM is undesirable in drinking water. Various technologies have been proposed for NOM removal with varying degrees of success. The properties and amount of NOM, however, can significantly affect the process efficiency. In order to improve and optimise these processes, the characterisation and quantification of NOM at different purification and treatment processes stages is important. It is also important to be able to understand and predict the reactivity of NOM or its fractions in different steps of the treatment. Methods used in the characterisation of NOM include resin adsorption, size exclusion chromatography (SEC), nuclear magnetic resonance (NMR) spectroscopy, and fluorescence spectroscopy. The amount of NOM in water has been predicted with parameters including UV-Vis, total organic carbon (TOC), and specific UV-absorbance (SUVA). Recently, methods by which NOM structures can be more precisely determined have been developed; pyrolysis gas chromatography-mass spectrometry (Py-GC-MS), multidimensional NMR techniques, and Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS). The present review focuses on the methods used for characterisation and quantification of NOM in relation to drinking water treatment. 相似文献
717.
718.
城市河流水质常规评价技术研究 总被引:11,自引:0,他引:11
运用综合水质标识指数法,对我国河流水质评价面临的关键技术问题,包括水质评价方法、水质评价项目,水质级别评价,水环境功能区达标评价、水质定性评价、河流及水系整体水质比较、水质随时间和空间变化等作了明确界定,并介绍了在上海河流水质评价中的应用。 相似文献
719.
Adsorption of pesticides ametryn, aldicarb, dinoseb and diuron from aqueous solution onto high specific area activated carbon-cloth was studied. Kinetics of adsorption was followed by in situ UV-spectroscopy and the data were treated according to various rate models. The extent of adsorption was determined at the end of 125 min adsorption period. Rate constants and the extent of adsorption for the four pesticides were found to follow the order: dinoseb > ametryn > diuron > aldicarb. Adsorption isotherms were derived at 25 °C on the basis of batch analysis. Isotherm data were treated according to Langmuir and Freundlich models. The fits of experimental data to these equations were examined. The types of interactions between the surface and pesticide molecules were discussed. 相似文献
720.
玄武湖蓝藻水华成因探讨 总被引:15,自引:3,他引:15
为了解南京玄武湖蓝藻水华的成因,对玄武湖长期监测资料进行了分析和现场调查。结果表明,玄武湖鲢鳙急剧减少中断了正常的食物链,使浮游植物的牧食压力降低,在东南湖回水的诱因作用下,发生了以微囊藻为优势种群的蓝藻水华。指出,玄武湖蓝藻水华的发生进程表明,东南湖回水可能是蓝藻水华发生的诱因,生态失衡是蓝藻水华发生的主要原因,蓝藻水华的暴发与富营养化程度无显著相关性,其暴发加重了玄武湖富营养化程度。 相似文献