Mercury in Precipitation at an Urbanized Coastal Zone of the Baltic Sea (Poland)

Wet deposition is an important source of metals to the sea. The temporal variability of Hg concentrations in precipitation, and the impact of air masses of different origins over the Polish coastal zone were assessed. Samples of precipitation were collected (August 2008–May 2009) at an urbanized coastal station in Poland. Hg analyses were conducted using CVAFS. These were the first measurements of Hg concentration in precipitation obtained in the Polish coastal zone. Since Poland was identified as the biggest emitter of Hg to the Baltic, these data are very important. In the heating and non-heating season, Hg concentrations in precipitation were similar. Hg wet deposition flux dominated in summer, when the production of biomass in the aquatic system was able to actively adsorb Hg. Input of metal to the sea was attributed to regional and distant sources. Maritime air masses, through transformation of Hg(0), were an essential vector of mercury in precipitation.     

莱钢1~# 1880m~3高炉出铁场除尘系统改造

对1 880 m3高炉出铁场除尘系统存在问题进行分析,查找制约原有系统除尘效果的原因,并利用技术改造,提高系统风量和除尘效果,有效地降低了岗位粉尘浓度,改善了现场周围环境,取得了较好的社会效益和环保效益.     

硅锰合金电炉烟气干法净化煤气回收的设计与分析

结合9000kVA硅锰合金电炉烟气净化,对干法烟气净化、煤气回收工艺中烟气参数的选取和控制、安全保证等问题进行了分析,并对其进行了技术经济性评价。     

Removal of H2S using molten carbonate at high temperature

Gasification is considered to be an effective process for energy conversion from various sources such as coal, biomass, and waste. Cleanup of the hot syngas produced by such a process may improve the thermal efficiency of the overall gasification system. Therefore, the cleanup of hot syngas from biomass gasification using molten carbonate is investigated in bench-scale tests. Molten carbonate acts as an absorbent during desulfurization and dechlorination and as a thermal catalyst for tar cracking. In this study, the performance of molten carbonate for removing H₂S was evaluated. The temperature of the molten carbonate was set within the range from 800 to 1000 °C. It is found that the removal of H₂S is significantly affected by the concentration of CO₂ in the syngas. When only a small percentage of CO₂ is present, desulfurization using molten carbonate is inadequate. However, when carbon elements, such as char and tar, are continuously supplied, H₂S removal can be maintained at a high level.To confirm the performance of the molten carbonate gas-cleaning system, purified biogas was used as a fuel in power generation tests with a molten carbonate fuel cell (MCFC). The fuel cell is a high-performance sensor for detecting gaseous impurities. When purified gas from a gas-cleaning reactor was continuously supplied to the fuel cell, the cell voltage remained stable. Thus, the molten carbonate gas-cleaning reactor was found to afford good gas-cleaning performance.     

Helping small businesses implement toxics use reduction techniques: dry cleaners, auto shops, and floor finishers assisted in creating safer and healthier work places

The Toxics Use Reduction Institute (TURI), Boston Public Health Commission (BPHC), and Vietnamese American Initiative for Development (Viet-AID) have worked with small business sectors to reduce their use of toxic chemicals. Three cases, described here, in dry cleaning, auto shops and floor finishing share common approaches for creating successful models of effective dissemination of toxics use reduction in small businesses. These include direct business support, peer-to-peer training and promotion of alternatives, and collaborations with stakeholders to achieve greener businesses. These results were achieved despite predictable barriers of lack of resources, suspicion of safer alternatives, and language and cultural barriers.     

文南油田注水管线防污染清洗技术研究

针对文南油田注水管线内壁结垢对油田注水的危害,以及管线常规清洗中存在的环境污染和硫化氢中毒问题,进行了注水管线防污染清洗技术的研究。通过分析消除硫化氢的反应机理,配制了三种常规清洗剂和两组硫化氢抑制剂,并将清洗剂与抑制剂复配后进行脱垢实验,从而优选出最佳复配剂(MF-1-B),经过现场试验,排酸口空气中硫化氢浓度为3～5mg/m3。防污染清洗技术的开发应用使文南油田注水管网得到了及时、全面的清洗,水质达标率由清洗前的30%上升到100%。     

煤矿瓦斯爆炸主要原因的试验研究

利用长径比为7,横截面积为1m~2,一端开口的7m~3的爆炸试验装置,停放成下斜、水平和上倾状态,模拟一段煤巷道的走向。用和瓦斯气具有相同比重的天然气作为试验的可燃气体,在上述试验装置内进行了一系列爆炸试验。试验结果证明了:煤矿向下倾斜的巷道对瓦斯气的自洁作用可保证不集存大量瓦斯气,是安全的;水平走向的巷道在有合适的通风情况下也是安全的;向上倾斜的巷道有集存瓦斯气的自恶化作用,会造成较强的爆炸。     

安钢推行清洁生产的几点措施

在指出转变观念的基础上,介绍了安钢“九五”以来发展过程中推行清洁生产的主要举措;并通过“九五”末和2002年能耗与环保指标对比,说明清洁生产的经济性、科学性。进而提出大力推行清洁生产是企业生存发展的必然选择。     

DTC型采出水净化剂研究进展概述

二硫代胺基甲酸盐（DTC）是一种高效、多功能采出水净化剂，它由二硫化碳与伯胺或仲胺反应生成二硫代胺基甲酸，然后再与碱反应而制备。其作用机理是与采出水中的铁或其它溶解金属反应形成絮体，絮体迅速聚结形成网状而包裹油，从而使油去除。DTC具有净化作用快，除油功效高，适用于分离、重力沉降和浮选等水处理过程。目前，国外DTC型冷水剂已发展到第三代。