重庆市大气污染对锌材料腐蚀的经济损失分析

简要介绍了材料大气腐蚀经济损失的估算方法,并以2002年为基准年,选择了重庆市主城中心的6个功能区作为代表性区域,运用腐蚀破坏剂量响应函数和使用寿命计算公式对锌材料的腐蚀经济损失进行了定量估算.结果表明,由大气污染腐蚀破坏锌材料造成的年直接经济损失约为4061.7万元,约为同期GDP的0.1%.其中,干沉降对经济损失总量的贡献率在71%～99%之间,均值为92%.     

云母钛珠光颜料的应用研究

介绍了一种不使用有机溶剂获得云母钛珠光颜料、水性金属效果云母钛珠光浆、珠光涂料的环保型制备工艺和性能.采用液相沉积法获得了不同厚度的纳米TiO2薄膜包覆层而显示银白、金、红、紫、蓝、绿等各种色彩的系列珠光云母颜料;应用珠光云母颜料与分散剂等水性助剂混合,获得了水性金属效果云母钛珠光浆的制备工艺;应用云母钛珠光浆与乳液配合,获得了云母钛珠光涂料的制备工艺.制备的云母钛珠光涂料系列多彩,白度高、反射率大、珠光效果好,硬度、附着力、耐候性等指标优异.     

吴淞工业区大气降尘变化规律及趋势

吴淞工业区是重工业聚集区,烟(粉)尘的排放量非常大,造成该地区空气污染严重.为了解降尘的污染特征、变化规律及趋势,以近10 a监测数据为依据,运用方差分析等数理统计方法对工业区降尘量进行分析,检验不同季节降尘的差异并简要分析原因,使用秩相关系数法对其进行趋势分析.结果表明,工业区降尘量较混合区与清洁区明显不同; 工业区与混合区的降尘受本地源的影响较大,4季的降尘量没有明显差异,相反清洁区的4季降尘呈显著差异.10 a来工业区及其周边地区的降尘量下降了56%,说明环境综合整治取得了显著效果,使区域环境空气质量得到改善.     

南方土壤酸沉降敏感性研究Ⅷ.盐基离子淋溶的多因素分析

在模拟酸雨条件下土壤盐基离子淋溶特性研究的基础上,采用生成分分析及多元回归分析方法研究了土壤盐基淋溶的影响因子．结果表明,通过主成分分析方法可将选取的15个原始变量综合成为2个主成分,为进一步分析盐基释放量与土壤理化性质之间的关系提供了方便．影响盐基释放量的主要因子有土壤原始pH值、可交换性盐基含量、蒙脱石含量、活性氧化物、1.4nm矿物等,它们表现出效应,而高岭石和可交换性铝含量表现出负效应．利用主成分分析的结果进行多元回归分析,可得到土壤累积盐基释放量与2个主成分之间的回归方程．     

Wet weather impact on trihalomethane formation potential in tributaries to drinking water reservoirs

During rain storm events, land surface runoff and resuspension of bottom sediments cause an increase in Trihalomethane (THM) precursors in rivers. These precursors, when chlorinated at water treatment facilities will lead to the formation of THMs and hence impact drinking water resources. In order to evaluate the wet weather impact on the potential formation of THMs, river samples were collected before, during and after three rain storms ranging from 15.2 to 24.9 mm precipitation. The samples were tested for THM formation potential and other indicators including UV254 absorbance, turbidity and volatile suspended solid (VSS). Average levels of THMs increased from 61 μg/l during dry weather to 131 μg/l during wet weather, and then went back to 81 μg/l after rain ended. Wet weather values of THM are well above the maximum contaminant level (MCL) 80 μg/l, set by EPA for drinking water. THM indicators also exhibited similar trends. Average levels increased from 0.6 to 1.8 abs; 2.6 to 6 ntu; and 7.5 to 15 mg/l respectively for UV254, turbidity and VSS. A positive correlation was observed between THM formation and THM indicators. The t-test of significance (p-value) was less than 0.05 for all indicators, and R values ranged from 0.85 to 0.92 between THMs and the indicators, and 0.72 to 0.9 among indicators themselves.     

Chemical fluxes in time through forest ecosystems in the UK - Soil response to pollution recovery

Long term trend analysis of bulk precipitation, throughfall and soil solution elemental fluxes from 12 years monitoring at 10 ICP Level II forest sites in the UK reveal coherent national chemical trends indicating recovery from sulphur deposition and acidification. Soil solution pH increased and sulphate and aluminium decreased at most sites. Trends in nitrogen were variable and dependant on its form. Dissolved organic nitrogen increased in bulk precipitation, throughfall and soil solution at most sites. Nitrate in soil solution declined at sites receiving high nitrogen deposition. Increase in soil dissolved organic carbon was detected - a response to pollution recovery, changes in soil temperature and/or increased microbial activity. An increase of sodium and chloride was evident - a possible result of more frequent storm events at exposed sites. The intensive and integrated nature of monitoring enables the relationships between climate/pollutant exposure and chemical/biological response in forestry to be explored.     

CHEMISTRY RESPONSE OF TWO FORESTED WATERSHEDS TO ACID ATMOSPHERIC DEPOSITION1

ABSTRACT: The deposition and chemistry of precipitation were estimated for one year in two forest ecosystems in the South-Central United States. Precipitation, throughfall, litter leachate, and soil leachate were analyzed for a small catchment of pine-hardwoods in southeastern Oklahoma and for a catchment of loblolly pines (Pinus taeda L.) in northern Mississippi. In the pine-hardwood forest, 98 percent of the acid deposition was neutralized, 50 percent in the forest canopy, and 48 percent in the forest floor. In the pine forest, 75 percent of the acid deposition was neutralized, all in the forest floor. The pine-hardwood ecosystem accumulated sulfate, nitrate, and ammonia ions, and lost base cations. During seasons of deficient precipitation, dry deposition appeared to enrich the concentrations of hydrogen, nitrate, sulfate, and ammonia ions in throughfall samples at both locations.     

Evaluating the effectiveness of air quality management within the class I area of great smoky mountains national park

The Clean Air Act Amendments of 1977 designated national parks and wilderness areas larger than 1894 ha to be class I areas for air quality management, setting more restrictive criteria than the National Ambient Air Quality Standards. Class I areas are afforded the greatest degree of air quality protection under the Clear Air Act of 1970. In recent years, several studies have documented air pollution effects in the Great Smoky Mountains National Park (GSMNP), the second-largest class I area in the eastern United States. Air pollution problems of greatest concern in the GSMNP are effects of acid deposition, visibility impairment, and tropospheric ozone. Several recent events have increased concerns about air quality management in the class I area of the GSMNP. A forum, sponsored by the Southern Appalachian Man and the Biosphere Cooperative (SAMAB), was held in March 1992, which involved representative. parties-at-interest and began to address strategies for better management of air resources in the Southern Appalachians. This paper summarizes those discussions and recommendations and reports actions occurring as a result of the forum. Another objective of this paper is to present a conceptual framework for more effective management of the class I area of the GSMNP.     

CONTRIBUTION OF PRECIPITATION TO QUALITY OF URBAN STORM RUNOFF1

Precipitation and runoff samples were collected for 13 storms in a nonindustrial urban area in Central Pennsylvania between July 1980 and June 1981. Runoff was collected from tree surfaces, a residential roof and street, a shopping mall parking lot, a downtown business district alley, and a heavily traveled street. Analysis of the water samples showed 10 to 25 percent of the nitrogen, 25 percent of the sulfate, and less than 5 percent of the phosphorus, potassium, and calcium in water below a tree was deposited by the precipitation. The residential roof caused insignificant changes in water chemistry. The results for the four paved areas showed that all the nitrogen, and from 16 to 40 percent of the sulfate and 13, 4, and 2 percent of the phosphorus, potassium, and calcium, respectively, in runoff was deposited by the precipitation. Precipitation can also be an important source of sulfate and phosphorus in runoff. All of the surfaces raised the pH of the runoff, with the largest increases, from a pH of 4 to about 7, occurring in runoff from the paved areas. Precipitation and runoff chemistry was not related to antecedent conditions such as the length of the preceding dry period.     

COMPARATIVE WATER CHEMISTRY OF FOUR LAKES IN ROCKY MOUNTAIN NATIONAL PARK1

ABSTRACT: The inorganic chemistry of two pairs of lakes in Rocky Mountain National Park was studied to determine reasons for their similarities and differences. The pairs were located on differing geologic units. It was expected that weathering from the different types of parent material would cause differing cation concentrations between the pairs. This was verified by dissimilar concentrations of those cations which are products of primary weathering. Unexpected was a significant difference in anion concentrations between members of one pair having the same bedrock geology. This difference has been attributed to the presence of a wet sedge meadow above one of the lakes which serves as a biological filter for anions, particularly nitrate and sulfate. It is shown that small scale drainage characteristics which can alter regional atmospheric contributions are important contributors to lake chemistry.