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排序方式: 共有946条查询结果,搜索用时 31 毫秒
1.
Gabriela P. Mendes Vivian M.A. Magalhães Lélia C.R. Soares Rayanne M. Aranh Claudio A.O. Nascimento Marilda M.G.R. Viann Osvaldo Chiavone-Filho 《环境科学学报(英文版)》2020,32(4):67-77
Chemical oxidation was applied to an artificially contaminated soil with naphthalene (NAP). Evaluation of NAP distribution and mass reduction in soil, water and air phases was carried out through mass balance. Evaluation of NAP distribution and mass reduction in soil, water and air phases was carried out through mass balance. The importance of the air phase analysis was emphasized by demonstrating how NAP behaves in a sealed system over a 4 hr reaction period. Design of Experiments method was applied to the following variables: sodium persulfate concentration [SP], ferrous sulfate concentration [FeSO4], and pH. The system operated with a prefixed solid to liquid ratio of 1:2. The following conditions resulted in optimum NAP removal [SP] = 18.37 g/L, [FeSO4] = 4.25 g/L and pH = 3.00. At the end of the 4 hr reaction, 62% of NAP was degraded. In the soil phase, the chemical oxidation reduced the NAP concentration thus achieving levels which comply with Brazilian and USA environmental legislations. Besides the NAP partitioning view, the monitoring of each phase allowed the variabilities assessment over the process, refining the knowledge of mass reduction. Based on NAP distribution in the system, this study demonstrates the importance of evaluating the presence of semi-volatile and volatile organic compounds in the air phase during remediation, so that there is greater control of the system as to the distribution and presence of the contaminant in the environment. The results highlight the importance of treating the contaminant in all its phases at the contaminated site. 相似文献
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As a novel alternative to traditional perfluoroalkyl substances (PFASs), including perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS), hexafluoroproplyene oxide trimer acid (HFPO-TA) has been detected worldwide in surface water. Moreover, recent researches have demonstrated that HFPO-TA has stronger bioaccumulation potential and higher hepatotoxicity than PFOA. To treat these contaminants e.g. PFOA and PFOS, some photochemical techniques by adding exogenous substances had been reported. However, there is still no report for the behavior of HFPO-TA itself under direct UV irradiation. The current study investigated the photo-transformation of HFPO-TA under UV irradiation in aqueous solution. After 72 hr photoreaction, 75% degradation ratio and 25% defluorination ratio were achieved under ambient condition. Reducing active species, i.e., hydrated electrons and active hydrogen atoms, generated from water splitting played dominant roles in degradation of HFPO-TA, which was confirmed by different effects of reaction atmospheres and quenching experiments. A possible degradation pathway was proposed based on the products identification and theoretical calculations. In general, HFPO-TA would be transformed into shorter-chain PFASs, including hexafluoropropylene oxide dimer acid (HFPO-DA), perfluoropropionic acid (PFA) and trifluoroacetate (TFA). This research provides basic information for HFPO-TA photodegradation process and is essential to develop novel remediation techniques for HFPO-TA and other alternatives with similar structures. 相似文献
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分光光度法测定染色废水的色度 总被引:3,自引:0,他引:3
为消除测定染色废水色度的主观误差,采用分光光度法测定染色废水的色度,与稀释倍数法相比,具有精确,重现性好,适用范围广等特点,PH值对色度的测定有明显影响,控制PH值为7.60,测定色度具有可比性。 相似文献
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生活垃圾生物处理的研究与展望 总被引:2,自引:0,他引:2
综述了国内外生活垃圾生物处理的研究进展和目前生活垃圾微生物研究水平,以及生活垃圾处理发展趋势与新动向,在此基础上提出了生活垃圾处理的建议和展望。 相似文献
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研究不同浓度的Cd对铅锌矿区和非矿区重金属超累积植物——小花南芥真菌根际pH的影响,以便更有效地减轻重金属污染。 相似文献
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2,4,6—三硝基甲苯废水治理技术的研究进展 总被引:19,自引:0,他引:19
论述了2,4,6-三硝基甲苯废水中化学耗氧量和色度的研究进展情况,指出生化法中白腐菌综合治理2,4,6-三硝基甲苯废水的处理方法是目前极有前途的有效的技术。 相似文献
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