首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   679篇
  免费   26篇
  国内免费   241篇
安全科学   15篇
废物处理   41篇
环保管理   65篇
综合类   457篇
基础理论   124篇
污染及防治   214篇
评价与监测   22篇
社会与环境   8篇
  2024年   4篇
  2023年   12篇
  2022年   14篇
  2021年   28篇
  2020年   18篇
  2019年   17篇
  2018年   31篇
  2017年   23篇
  2016年   21篇
  2015年   33篇
  2014年   31篇
  2013年   69篇
  2012年   39篇
  2011年   55篇
  2010年   27篇
  2009年   42篇
  2008年   49篇
  2007年   66篇
  2006年   55篇
  2005年   37篇
  2004年   38篇
  2003年   51篇
  2002年   31篇
  2001年   35篇
  2000年   26篇
  1999年   24篇
  1998年   20篇
  1997年   12篇
  1996年   3篇
  1995年   4篇
  1994年   6篇
  1993年   9篇
  1992年   6篇
  1991年   1篇
  1990年   3篇
  1987年   1篇
  1983年   1篇
  1981年   2篇
  1975年   1篇
  1968年   1篇
排序方式: 共有946条查询结果,搜索用时 62 毫秒
111.
Alcaligenes sp.YF11菌对杀灭菊酯的降解机理   总被引:6,自引:0,他引:6  
测定了降解菌Alcaligenessp.YF11对不同浓度杀灭菊酯的降解及其降解途径。在纯培养系统中,Alcaligenessp.YF11对100mg/L的杀灭菊酯的降解符合零级动力学特征,其降解速率为2.1mg/L·h;50mg/L的杀灭菊酯在24h的降解率为87.5%;10mg/L的杀灭菊酯10h的降解率为71.0%。Alcaligenesso.YF11对杀灭菊酯的降解为矿化作用。  相似文献   
112.
Biological treatment of dye wastewaters using an anaerobic-oxic system   总被引:5,自引:0,他引:5  
Three dye solutions, namely, C.I. Acid Yellow 17, C.I. Basic Blue 3, and C.I. Basic Red 2, were treated in an upflow anaerobic sludge blanket (UASB) reactor followed by a semi-continuous aerobic activated sludge tank. When hydraulic retention time was about 12 hours, no significant color removal was observed in the aerobic stage. In the anaerobic stage, Acid Yellow 17, Basic Blue 3, and Basic Red 2 were removed by 20%, 72%, and 78%, respectively. To treat wastewater from a dye manufacturing factory with COD concentration of 1200 mg/l and Color of 500 degree (dilution factor), an UASB reactor (4.5 liters) and an activated sludge tank (5 liters, adjustable), COD and color were removed by more than 83% and 90% at a COD loading rate of 5.3 kg COD/m3-day in the anaerobic stage, and at the hydraulic retention time of 6-10 hours for the anaerobic stage and 6.5 for the aerobic stage. The anaerobic stage of the A/O system removes both color and COD. In addition, it also improves biodegradability of dyes for further aerobic treatment.  相似文献   
113.
Clay loam soil from agricultural fields of alluvial (AL) soil (typic udifluvent) and coastal saline (CS) soil (typic endoaquept) were investigated for the degradation and effect of pencycuron application at field rate (FR), 2-times FR (2FR) and 10-times FR (10FR) with and without decomposed cow manure (DCM) on soil microbial variables under laboratory conditions. Pencycuron degraded faster in CS soil and in soil amended with DCM. Pencycuron spiking at FR and 2FR resulted in a short-lived (in case of 10FR slightly longer) and transitory toxic effect on soil microbial biomass-C (MBC), ergosterol content and fluorescein diacetate hydrolyzing activity (FDHA). Amendment of DCM did not seem to have any counteractive effect of the toxicity of pencycuron on the microbial variables. The ecophysiological status of the soil microbial communities as expressed by microbial metabolic quotient (qCO2) and microbial respiration quotient (Q(R)) changed, but for a short period, indicating pencycuron induced disturbance. The duration of this disturbance was slightly longer at 10FR. Pencycuron was more toxic to the metabolically activated soil microbial populations, specifically the fungi. It is concluded that side effects of pencycuron at 10FR on the microbial variables studied were only short-lived and probably of little ecological significance.  相似文献   
114.
研究了投加硝态氮NO3^--N对缺氧反硝化-好氧和缺氧水解-好氧串联系统处理印染PVA退浆废水的效果。结果表明,缺氧反硝化投加硝态氮NO3^--N比缺氧水解-好氧对CODCr的去除率在缺氧池、好氧池中均提高了30%,缺氧反硝化-好氧工艺二沉池出水经生物碳处理后,CODCr,的去除率达90%。C:N:P的比例合适与否是处理印染PVA退浆废水成功的关键。  相似文献   
115.
印染废水混凝脱色技术的分子结构基础   总被引:17,自引:2,他引:17  
印染废水的混凝脱色效果取决于染料分子的分子结构及其在水中的分子分散状态和染料的染色机制。大量研究结果表明,所选用的染料分子的分子结构决定了印染废水混凝脱色技术的混凝机制和混凝效果,合成絮凝剂与选择絮凝剂应充分考虑染料分子的分子结构与空间构型。  相似文献   
116.
白腐菌对芳香族化合物的降解途径   总被引:4,自引:0,他引:4  
白腐菌 (Whiterotfungi)是目前所发现的对芳香族化合物有很强降解能力的一类微生物。本文探讨了降解芳香族化合物的白腐菌种及其代谢化合物的主要类型 ,分析了对不同化合物的不同代谢途径 ,同时展望了其应用前景  相似文献   
117.
Y. Xu   《Chemosphere》2001,43(8):1281
The degradation of a common textile dye, Reactive-brilliant red X-3B, by several advanced oxidation technologies was studied in an air-saturated aqueous solution. The dye was resistant to the UV illumination (wavelength λ  320 nm), but was decolorized when one of Fe3+, H2O2 and TiO2 components was present. The decolorization rate was observed to be quite different for each system, and the relative order evaluated under comparable conditions followed the order of Fe2+–H2O2–UV  Fe2+–H2O2 > Fe3+–H2O2–UV > Fe3+–H2O2 > Fe3+–TiO2–UV > TiO2–UV > Fe3+–UV > TiO2–visible light (λ  450 nm) > H2O2–UV > Fe2+–UV. The mechanism for each process is discussed, and linked together for understanding the observed differences in reactivity.  相似文献   
118.
堆肥中纤维素和木质素的生物降解研究现状   总被引:5,自引:0,他引:5  
堆肥是垃圾处理的主要方法之一 ,厨房垃圾、园林垃圾、农村秸秆和日常生活中的废弃纤维产品均可作为堆肥原料 ,这些原料中含有一定量的纤维素和木质素 ,而纤维素和木质素在堆肥过程中较难生物降解。因此 ,国内外学者致力于研究能加速纤维素和木质素降解的高效微生物。研究发现 ,对纤维素和木质素有降解能力的微生物主要是高温放线菌和高温真菌 ,其中有独特降解机制的白腐菌在木质素降解中起着重要作用  相似文献   
119.
Investigation of a groundwater plume containing up to 24 g l(-1) phenolic compounds suggested that over a period of nearly 50 years, little degradation had occurred despite the presence of a microbial community and electron acceptors within the core of the plume. In order to study the effect of contaminant concentration on degradation behaviour, laboratory microcosm experiments were performed under aerobic and anaerobic conditions at four different concentrations obtained by diluting contaminated with uncontaminated groundwater. The microcosms contained groundwater with total phenols at ca. 200, 250, 660 and 5000 mg l(-1), and aquifer sediment that had been acclimatised within the plume for several months. The microcosms were operated for a period of 390-400 days along with sterile controls to ascertain whether degradation was microbially mediated or abiotic. Under aerobic conditions, degradation only occurred at concentrations up to 660 mg l(-1) total phenols. At phenol concentrations below 250 mg l(-1) a benzoquinone intermediate, thought to originate from the degradation of 2,5-dimethylphenol, was isolated and identified. This suggested an unusual degradative pathway for this compound; its aerobic degradation more commonly proceeding via catecholic intermediates. Under anaerobic conditions, degradation only occurred in the most dilute microcosm (total phenols 195 mg l(-1)) with a loss of p-cresol accompanied by a nonstoichiometric decrease in nitrate and sulphate. By inference, iron(III) from the sediment may also have been used as a terminal electron acceptor, in which case the amount of biologically available iron released was calculated as 1.07 mg Fe(III)/g of sediment. The study shows that natural attenuation is likely to be stimulated by dilution of the plume.  相似文献   
120.
宁南山区人工林草对土壤真菌群落的影响   总被引:4,自引:0,他引:4  
以宁南山区天然草地(长芒草(Stipa bungeana Trin))为参照,选取2种典型人工恢复植被:人工草地(苜蓿(Medicago sativa))和人工林地(柠条(Caragana korshinskii Kom))的表层土壤(0-20cm)为研究对象,利用Miseq高通量测序技术分析土壤真菌的多样性、物种组成及其相对丰度变化特征,并采用冗余分析(RDA)的方法研究环境因子对不同植被土壤真菌群落的影响.结果表明:3种植被样地土壤样品共测得真菌27个门,44个纲,70个目,91个科.其中,优势菌门有子囊菌门(Ascomycota)和担子菌门(Basidiomycota),丰度分别为71.8%和15.2%;优势菌纲主要有:粪壳菌纲(Sordariomycetes)、座囊菌纲(Dothideomycetes)、伞菌纲(Agaricomycetes)和盘菌纲(Pezizomycetes);优势菌属有:赤霉菌属(Gibberella)、肾形虫属(Colpoda)、水球壳属(Hydropisphaera)、叶生壳属(Floricola)、管柄囊霉属(Funneliformis)和Marcelleina.土壤真菌丰富度和多样性在苜蓿地最大,柠条地最小.球囊菌门(Glomeromycota)在天然草地的丰度最高,为4.8%;子囊菌门丰度在苜蓿地里最大,达82.6%,在柠条地最低,为56.8%;担子菌门和分类不明确门(Unclassified)在柠条土壤中丰度最大,分别为:25.3%和7.9%,在苜蓿地中最低,分别为:7.1%和0.8%.盘菌纲在天然草地中的丰度最高,为17.8%,且显著高于柠条地.伞菌纲在(Agaricomycetes)柠条地中的丰度明显高于苜蓿地.Heatmap热图分析表明,尽管苜蓿地中土壤真菌群落与天然草地的相似度更高,但是天然草地中AM真菌(Arbuscular mycorrhizal Fungi)的相对丰度最大,种植苜蓿使土壤致病菌属的相对丰度增加,柠条地的肾形虫属相对丰度最高.人工林草对土壤真菌的群落组成和多样性有较明显的影响.土壤水分(SW)、有机碳(TOC)和全氮(TN)是影响宁南山区林草地土壤真菌群落的主要理化因子.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号