X射线荧光快速分析土壤中锑铊等重金属含量

本文建立了一种快速、准确、简便、高效和非破坏性分析土壤中锑和铊等8种主要关注的重金属含量的X射线荧光法,可在很短的时间(约1h)内完成1个样品中的重金属含量测定。采用该方法分析了ESS系列4个标准样品和8个实际样品,与电感耦合等离子体质谱法测定结果接近,表明该方法可信度高。     

Characterization and reactivity of biogenic manganese oxides for ciprofloxacin oxidation

Biogenic manganese oxides （BioMnOx） were synthesized by the oxidation of Mn（II） with Mn- oxidizing bacteria Pseudomonas sp. G7 under different initial pH values and Mn（II） dosages, and were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, and UV-Vis absorption spectroscopy. The crystal structure and Mn oxidation states of BioMnOx depended on the initial pH and Mn（lI） dosages of the medium. The superoxide radical （O2） was observed in Mn-containing （III/IV） BioMnOx suspensions by electron spin resonance measurements. BioMnOx（0.4）-7, with mixed valence of Mn（II/III/IV） and the strongest O~- signals, was prepared in the initial pH 7 and Mn（II） dosage of 0.4 mmol/L condition, and exhibited the highest activity for ciproftoxacin degradation and no Mn（II） release. During the degradation of ciprofloxacin, the oxidation of the Mn（II） formed came from biotic and abiotic reactions in BioMnOx suspensions on the basis of the Mn（II） release and O2- formation from different BioMnOx. The degradation process of ciprofloxacin was shown to involve the cleavage of the hexatomic ring having a secondary amine and carbon-carbon double bond connected to a carboxyl group, producing several compounds containing amine groups as well as small organic acids.     

新生态MnO2对活性艳红染料废水的处理研究

该研究以高锰酸钾和硫酸锰溶液作为原料,在pH=10．0条件下,采用两种物质混合反应制备新生态二氧化锰。以新生态MnO2作为吸附剂,以活性艳红X-3B为目标物,采用静态吸附实验研究,考察改变pH值、吸附剂投加量、反应时间、反应温度、离子强度等因素对新生态MnO2吸附活性艳红X-3B染料废水性能的影响。该吸附剂作为一种高效、经济的吸附材料对染料废水的脱色处理具有较好的作用。     

浅谈医用X射线CT机房辐射环境监测

本文从监测仪器、监测方法、监测布点等方面,简要说明了医用X射线CT机房辐射环境监测要点,对做好医用X射线CT机房辐射环境监测具有一定现实意义。     

高能X射线包裹图像边沿特征识别方法

针对包裹在进行X射线安检过程中,普遍存在包裹边沿区域自身结构特征如金属制加固筋、扣环以及提手等对违禁品自动探测产生的干扰问题,研究了一种包裹图像边沿特征区域识别方法:根据高能X射线材料特征,结合图像分割、图像模式识别技术,利用图像的形态学分析,定位出包裹边沿区域;然后通过一种阈值选取与连通区测量方式,实现对边沿特征区的识别过程。该试验结果表明,方法能够有效地识别出包裹图像边沿的金属制加固筋、扣环以及提手等特征区,对提高X射线安检设备违禁品自动探测的精度有一定的帮助作用。     

中捷炼油厂液化石油气球形贮罐射线探伤通用工艺

1适用范围 本工艺适用于中捷炼油厂球形液化石油气贮罐的射线探伤工艺,可供借鉴参考。     

球罐面积型缺陷的分析与检测

分析了冶金企业储气球罐焊缝内部裂纹和未熔合等面积型缺陷的产生原因,提出了面积型缺陷的检测方法和控制手段,指出超声波检测比射线检测更适宜检测球罐面积型缺陷,针对07MnCrMoVR低合金高强钢制造的球形储罐安装制造阶段应在对接焊缝100％射线检测的基础上,增加100％超声波检测,投入使用后的首次定期检验应进行100％超声波检测,对于超声波检测严重超标而射线检测没有发现缺陷部位要做返修处理。     

Effect of pretreatment on Pd/Al2O3 catalyst for catalytic oxidation of o-xylene at low temperature

The effect of pretreatment on Pd/Al₂O₃ catalysts for the catalytic oxidation of o-xylene at low temperature was studied by changing the pretreatment and testing conditions. The fresh and pretreated Pd/Al₂O₃ catalysts were characterized by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). The results showed that the pretreatment dramatically changed the Pd/PdO ratio and then significantly affected the Pd/Al₂O₃ activity; while the pretreatment had not much influence on Pd particle size. The Pd/Al₂O₃ pre-reduced at 300℃/400℃, which has fully reduced Pd species, showed the highest activity; while the fresh Pd/Al₂O₃, which has fully oxidized Pd species, presented the worst performance, indicating the Pd chemical state plays an important role in the catalytic activity for the o-xylene oxidation. It is concluded that metallic Pd is the active species on the Pd/Al₂O₃ catalyst for the catalytic oxidation of o-xylene at low temperature.     

多效应残差法(MERA)表征二甲亚砜-农药二元混合物毒性相互作用

采用直接均分射线设计(EquRay)构建二甲亚砜(DMSO)分别与3种常用农药乐果(DIM)、敌敌畏(DIC)和甲霜灵(MET)的二元混合物,应用微板毒性分析(MTA)测试单个物质及混合物对青海弧菌Q67(Vibrio qinghaiensis sp.-Q67)的发光抑制毒性.以浓度加和(concentration addition,CA)模型检测混合物的毒性相互作用,提出并应用多效应残差法(multi-effectresidual analysis,MERA)定量表征DMSO-农药二元混合物实验观测毒性相对于CA模型预测结果的偏离程度,即毒性相互作用强度.表征结果显示3组DMSO-农药二元混合物的毒性相互作用以拮抗作用为主,最强拮抗作用在-23%～-15%之间,发生拮抗作用的浓度范围及拮抗作用强度受混合物组成、组分浓度比和效应水平等因素的影响.综合分析比较MERA与传统等效线图及扩展毒性单位和对3组二元混合物的表征结果发现,MERA从生物效应角度表征毒性相互作用强度,受到混合物组成和效应水平的限制较少,适用于分析具有复杂相互作用的二元混合物.     

中国安全防范产品行业协会关于增补副理事长单位及代表人、常务理事单位、理事单位的决定

根据《中国安全防范产品行业协会章程》第二十条规定，经本次常务理事会审议、投票通过，决定增补成都亚光电子股份有限公司及杨和声同志为协会副理事长单位及代表人；