Petro-chemical wastewater treatment by biological process

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PLC控制系统在钢渣热焖工艺中的应用

利用PLC控制系统,实现在钢渣热焖工艺中的恒压供水和钢渣热焖定时定量喷水的自动控制要求,具有国际先进水平,取得了良好的经济效益、社会效益和环境效益.     

Application of CGP-cross route process for microstructure refinement and mechanical properties improvement in steel sheets

A modified method of severe plastic deformation (SPD) entitled constrained groove pressing-cross route (CGP-CR) was introduced for imposing a high magnitude of equivalent strain of about 2.32 per pass on the sheet form samples. The major benefit of this improved route compared to previous common route was the more homogeneity of strain in the rolling (RD) and transverse (TD) directions of sheets. In this study, low carbon steel samples were used for examination of evolutions in microstructure and mechanical properties during SPD via CGP-CR process. Mechanical properties improvement were measured by tensile and macro hardness tests. The results indicate that CGP-CR process can effectively improve tensile strength; and also, yield stress and hardness of as-received low carbon steel samples were improved up to about 100% after two deformation passes. Also, high magnitude of inhomogeneity can be observed in hardness distribution through first pass of the process which diminishes in the subsequent passes. Microstructural evolutions during process were monitored by optical microscopy observations and X-ray diffraction analysis. The results demonstrate that initial ferritic microstructure with grain size of about 30 μm was refined to a 225 nm cell structure after two passes of CGP-CR process.     

火灾下钢框架结构热-力耦合模拟与性能分析

基于"自然火灾安全概念"(NFSC)的基本思想,提出了火灾下钢结构热-力耦合模拟方法。利用ANSYS的参数化设计语言,建立了ANSYS软件与OZone火灾分析软件的数据接口,实现了火灾分析软件与大型有限元软件的耦合运用。基于火灾模拟软件OZone的分析结果,利用APDL语言,对钢框架结构进行了真实火灾场景下的热-力耦合模拟。研究表明:钢框架结构在真实火灾场景下,受非均匀变热流影响,结构内部将产生热应力梯度和应力牵移现象;同时钢框架中钢梁固接时,火灾初期变形较小,当达到某个关键时间点后将开始大的变形破坏,其主要原因是钢框架内部产生塑性铰,即钢梁由固接变为铰接,释放了对钢梁的约束。     

Effect of oxide-based fluxes on mechanical and metallurgical properties of Dissimilar Activating Flux Assisted-Tungsten Inert Gas Welds

Present investigation is to study the “Effect of Activating Fluxes on Mechanical and Metallurgical Properties of Dissimilar Activated Flux-Tungsten Inert Gas Welds”. Effect of current, welding speed, joint gap and electrode diameter on weld bead dimensions on 6 mm thick dissimilar weld between carbon steel to stainless steel, was studied under Activated Flux-Tungsten Inert Gas Welding process. During this investigation three different types of oxide powders were used-TiO₂, ZnO and MnO₂. After welding samples were subject to mechanical testing, in addition to characterization via micro hardness and microstructures of Normal Tungsten Inert Gas Welds and Activated Flux-Tungsten Inert Gas Welds. Activating fluxes TiO₂ and ZnO are effective fluxes for Activated Flux-Tungsten Inert Gas Welding of dissimilar weld between CS to SS. Highest depth/width (D/W) ratio reported under TiO₂ and ZnO fluxes compare to Normal-Tungsten Inert Gas Welds. Lowest angular distortion was observed under TiO₂ flux compare to Normal-Tungsten Inert Gas Welds. Mechanical properties, Joint Efficiency of Activated Flux-Tungsten Inert Gas Welds are higher than normal-Normal Tungsten Inert Gas Welds. Tensile Test specimens of both the processes failed from the parent metal (carbon steel side). Carbon migration from CS to SS, had occurred which led to failure of weld joints from CS side.     

Microstructure of 2205 duplex stainless steel joint in submerged arc welding by post weld heat treatment

The 2205 duplex stainless steel (DSS) is of both good properties austenitic steel and ferritic steel, which applies to the shipbuilding industry usually. In this paper, the OM, XRD and microhardness test methods are used to analyze the variation of submerged arc welded (SAW) joints with and without post weld heat treatment (PWHT). The research results show that the σ phase disappear in the fusion edge zone near heat affect zone (HAZ) and an increase in the welded center zone during the follow-up PWHT, while the amount of γ phase is decreased in the welded center zone with PWHT. A segregation distribution of some second phases is also found in the welded center zone after PWHT. There have two pick values of microhardness arise in the fusion edge zone and the welded center zone separately without PWHT. However, a maximum value of microhardness at the fusion edge zone near HAZ is disappeared and the other is still held at the welded center zone during PWHT. It can be attributed to the changes of second phases, element diffusions and particle segregation during PWHT. A developing mechanism is issued to demonstrate the second phases transferring of the 2205 DSS SAW joints by PWHT.     

45~#钢在西双版纳大气环境下的腐蚀研究

目的研究西双版纳热带雨林地区大气环境下材料的初期腐蚀行为。方法使用45#碳钢在西双版纳大气环境下进行1年的大气暴露腐蚀试验,并利用质量损失分析、SEM、XRD和FTIR等技术,分析45#碳钢在西双版纳大气环境下暴露1年的腐蚀行为。结果 45#碳钢的腐蚀产物以γ-FeOOH,Fe(OH)3和Fe3O4为主,并有少量的α-FeOOH。结论西双版纳大气环境腐蚀性为C2级。在暴露1年的时间内,锈层化学稳定性随试验时间的延长逐渐增强,对基体的保护性逐渐加大。     

不同构造措施的钢管混凝土边框钢板剪力墙抗震性能试验研究

钢管混凝土边框钢板剪力墙是一种新型抗震剪力墙,为了比较不同构造措施对该新型剪力墙抗震性能的影响,进行了3个剪跨比为1.5的钢管混凝土边框钢板剪力墙低周反复荷载试验.其中,试验模型1为墙体钢板与边框柱钢管焊接,试验模型2为墙体钢板与边框柱钢管螺栓连接,试验模型3为墙体钢板开孔并与边框柱钢管焊接.通过试验研究,比较了各剪力...     

钢渣吸附-微波降解法处理碱性品红废水

研究了钢渣对碱性品红染料的吸附性能、影响因素以及微波对吸附在钢渣-焦炭上的染料的降解作用。实验表明,在中性条件下,钢渣对碱性品红具有优良的吸附性能,饱和吸附量可达到42．4mg／g。以钢渣处理质量浓度为100mg/L的碱性品红溶液,当固液质量比为1：50、振荡吸附1h后,染料溶液脱色率达97％。实验还表明,焦炭可吸收微波产生高温,用钢渣-焦炭混合物（质量比1：1）吸附染料后,以微波辐照可使物料达到665℃的高温,吸附的染料降解。吸附剂再生后重复使用4次,脱色率都达到95％以上。     

钢渣预处理含铬废水及其废渣与铬渣的固化

用钢渣对含铬废水进行预处理,探讨了钢渣粒度、用量、废水pH值和添加硫酸亚铁还原剂的影响.结果表明,经硫酸亚铁还原处理后再用钢渣处理比单纯用钢渣处理的效果明显提高,采用钢渣/总铬质量比为40的100目钢渣处理经硫酸亚铁还原后的含铬废水,总铬和Cr6 去除率分别达79%和84%,采用钢渣柱进行的两级淋滤实验进一步表明该方法可作为工业上含铬废水处理的预处理段.处理后的废钢渣同工业铬渣一起进行水泥固化,标准养护20 d后固化体表面Cr6 浸出率、破碎至5 mm粒径以下和酸雨淋溶下的浸出液Cr6 浓度均符合安全标准,可作为普通建材或进行填埋处置.