全文获取类型
收费全文 | 267篇 |
免费 | 35篇 |
国内免费 | 83篇 |
专业分类
安全科学 | 62篇 |
废物处理 | 10篇 |
环保管理 | 31篇 |
综合类 | 175篇 |
基础理论 | 56篇 |
污染及防治 | 28篇 |
评价与监测 | 9篇 |
社会与环境 | 8篇 |
灾害及防治 | 6篇 |
出版年
2023年 | 3篇 |
2022年 | 6篇 |
2021年 | 12篇 |
2020年 | 14篇 |
2019年 | 9篇 |
2018年 | 12篇 |
2017年 | 12篇 |
2016年 | 18篇 |
2015年 | 15篇 |
2014年 | 13篇 |
2013年 | 33篇 |
2012年 | 35篇 |
2011年 | 23篇 |
2010年 | 29篇 |
2009年 | 21篇 |
2008年 | 18篇 |
2007年 | 20篇 |
2006年 | 18篇 |
2005年 | 13篇 |
2004年 | 5篇 |
2003年 | 8篇 |
2002年 | 6篇 |
2001年 | 8篇 |
2000年 | 8篇 |
1999年 | 4篇 |
1998年 | 7篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1994年 | 3篇 |
1992年 | 2篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1983年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有385条查询结果,搜索用时 218 毫秒
161.
Three types of macromolecular organic matters (MOMs), i.e. humic acid (HA), kerogen+black carbon (KB), and black carbon (BC) were extracted from marine sediments of Xiamen Gulf, southeast of China. The chemical composition, morphological property and source of the three extractions were characterized by elemental analyzer/isotope ratio mass spectrometry (EA/IRMS) and scanning electron microscope (SEM). The results showed that KB was the predominant fraction in MOMs, which accounted for 61.79%-89.15% of the total organic content (TOC), while HA consisted less than 5%. The relative high contents of kerogen and BC, and low contents of HA in the samples indicated that anthropogenic input might be the major source of organic matter in marine sediments near the industrial regions. The characterization of SEM, not only revealed morphological properties of the three fractions, but also allowed a better understanding of the source of MOMs. The δ 13 C values of the three fractions suggested that materials from terrestrial C 3 plants were predominant. Furthermore, the anthropogenic activities, such as the discharge of sewage, coal and biomass combustion from industry nearby and agricultural practices within drainage basin of the Jiulong River, were remarkably contributed to the variations in δ 13 C values of MOMs in the offshore marine sediments. 相似文献
162.
Zhi-Wu Wang Seung-Hwan Lee James G. Elkins Yongchao Li Scott Hamilton-Brehm Jennifer L. Morrell-Falvey 《环境科学学报(英文版)》2013,25(5):849-856
Live cell imaging methods provide important insights into the dynamics of cellular processes that cannot be derived easily from population-averaged datasets.In the bioenergy field,much research is focused on fermentation of cellulosic biomass by thermophilic microbes to produce biofuels;however,little effort is dedicated to the development of imaging tools to monitor this dynamic biological process.This is,in part,due to the experimental challenges of imaging cells under both anaerobic and thermophilic conditions.Here an imaging system is described that integrates confocal microscopy,a flow cell device,and a lipophilic dye to visualize cells.Solutions to technical obstacles regarding suitable fluorescent markers,photodamage during imaging,and maintenance of environmental conditions during imaging are presented.This system was utilized to observe cellulose colonization by Clostridium thermocellum under anaerobic conditions at 60℃.This method enables live cell imaging of bacterial growth under anaerobic and thermophilic conditions and should be widely applicable to visualizing different cell types or processes in real time. 相似文献
163.
基于知识图谱的土壤重金属快速监测技术进展 总被引:1,自引:0,他引:1
为了解当前国际土壤重金属快速监测研究现状及趋势,以Web of science数据库为基础,以X射线荧光光谱法(XRF)为例利用CiteSpace进行知识图谱可视化分析,并在此基础上对国际土壤重金属快速监测进行研究综述.结果表明,从Web of science数据库资料来看,当前对土壤重金属快速监测的研究机构以中国科学院和西班牙国家科学研究委员会发文量最多,而发文从属国家以美国为最多,中国和德国居其次;研究热点主要集中于快速监测仪器的技术开发、实际应用、定量化监测影响因素的识别及校正等方面;针对土壤重金属污染快速监测的未来研究趋势主要集中于监测仪器的小型化智能化研发、农田土壤重金属快速监测、区域土壤重金属空间分布监测等方面.认清和了解当前国际土壤重金属快速监测研究状况,可为国内相关研究提供参考. 相似文献
164.
Changchun Huang Yixin Bai Kunlin Shi Heyu Yu Nana Shang Weiyue Hao Chuan Wang Tao Huang Hao Yang 《环境科学学报(英文版)》2022,34(11):224-233
Receptor models are a useful tool for identifying sources of polycyclic aromatic hydrocarbons (PAHs) in multiple environmental media. In this study, three different receptor models (including the principal component analysis-multiple linear regression (PCA-MLR), positive matrix factorization (PMF), and Unmix models) were used to apportion the sources of 16 priority PAHs in a sediment core of Lake Dagze Co. The ∑PAHs (sum of all 16 measured PAHs) concentrations ranged from 51.89 to 132.82 ng/g with an average of 80.39 ng/g. The ∑PAHs were dominated by 2-3 ring PAHs, accounting for 80.12% on average, thereby indicating that they mainly originated from biomass and coal combustion and/or from long-range atmospheric transportation. The three models produced consistent source apportionment results. The greatest contributor to ∑PAHs was biomass combustion, followed by coal combustion, vehicle emissions, and petrogenic sources. Moreover, the temporal variation of the common sources was well-correlated among models. The multi-method comparison and evaluation results showed that all three models were useful tools for source apportionment of PAHs, with the PMF model providing better results than the PCA-MLR and Unmix models. The temporal trends of factor contributions were verified by PAHs with different ring numbers. Significant correlations were found between the simulated concentrations of each source factor and the PAHs with different ring numbers (P<0.01), except for the petrogenic source identified by the Unmix model (P>0.05). This study can provide useful information for further investigation of source apportionment of PAHs in the sediment cores. 相似文献
165.
利用臭氧观测仪(OMI)和扫描成像大气吸收光谱仪(SCIAMACHY)传感器反演的臭氧总量数据,结合从世界臭氧与紫外线辐射数据中心(WODUC)获取的地面观测臭氧总量数据进行验证,对比2种不同卫星遥感反演的臭氧总量产品优缺点,并分析亚洲地区臭氧总量的时空特征.结果表明,OMI反演的结果比SCIAMACHY的结果更好,而且具有更高的时间和空间分辨率.臭氧总量存在明显的季节变化,在低纬度地区最大值出现在4或5月,最小值在11或12月,而在高纬度地区则分别出现在2月或3月和8月或9月.臭氧总量纬度地带性分布明显,并随着纬度增加而逐渐上升,在10°N~30°N之间,臭氧总量增长平缓,在30°N~50°N之间,臭氧总量快速增大.在青藏高原地区出现臭氧低值区,并在青藏高原东面的横断山脉向低纬度延伸,隔断了臭氧总量的纬度地带性分布.臭氧总量变化在不同纬度呈现不同的模式,距平值随纬度的增大波动随之增大.纬度最低的站点(216)臭氧总量距平值变化最小,最大只有30 DU;而纬度最高的站点(326)臭氧总量距平值变化可达180 DU以上. 相似文献
166.
为了对比3321型空气动力学粒径谱仪(APS)、3081/3085型气溶胶粒径谱仪(SMPS)和宽范围粒径谱仪(WPS)对气溶胶数浓度的观测性能,于2010年夏季在南京信息工程大学校内使用上述三台仪器进行了同步观测.将得到的数据进行对比,并结合校内自动气象站的气象资料对0.01~10μm气溶胶粒子的数浓度、日变化规律及谱分布特征进行分析.结果表明,3台仪器在总体数浓度变化趋势上表现出较好的一致性,但相同粒径段的粒子浓度NSMPS>NWPS>NAPS.SMPS比WPS尺度分辨率高,粒径范围在0.02~0.2μm时,SMPS与WPS相关性较好;APS测量气溶胶数浓度谱的连续性较WPS好.3种仪器在观测日变化趋势上都表现出双峰型,但SMPS的峰值浓度和出现峰值的粒径范围均高于或大于WPS.各类气象条件及降水对仪器间的测量误差影响不大. 相似文献
167.
山西晋中焦化基地多环芳烃排放对周边大田卷心菜的影响 总被引:1,自引:0,他引:1
饮食摄入是多环芳烃(PAHs)人体暴露的主要途径之一,探究PAHs污染对农产品安全和人体健康的影响具有重要意义。山西晋中拥有大型焦化企业,也是北方重要的大田蔬菜种植基地,当地PAHs污染的特征和影响具有相当的典型性。研究选取修文工业基地周边的大田蔬菜基地作为研究区域,分别采集大气(含气相和颗粒相)、菜地表土和卷心菜菜心样品,确定各类样品中母体PAHs的浓度水平、组成比例和分布特征。结果表明,蔬菜基地周边大气中母体PAHs的平均浓度为301 ng·m-3。大气母体PAHs主要存在于气相,低环(2~3环)组分占据优势。利用同分异构体特征比值和主成分分析对大气PAHs进行初步源解析,炼焦、燃煤和生物质燃烧、以及交通尾气排放是当地PAHs的主要排放源。菜地表土母体PAHs的中位数浓度为236ng·g-1,范围为130~703 ng·g-1,以中、高环(4~6环)组分为主,菜地表土母体PAHs浓度与土壤总有机碳(TOC)分数呈现显著正相关关系。当地大田种植卷心菜菜心的PAHs中位数浓度为12.9 ng·g-1,范围为0.9~47.6 ng·g-1,低环组分所占比例最大,其组分谱分布与大气相似。偏相关分析显示周边大气PAHs对卷心菜菜心PAHs的传输贡献要大于表土PAHs。 相似文献
168.
169.
Two-photon laser confocal scanning microscopy (TPLCSM) was first used to visualize the uptake and movement of naphthalene (NAP), phenanthrene (PHE), and pyrene (PYR), from separately contaminated hydroponics solutions into living Kandelia candel (L.) Druce seedlings. With this non-destructive and non-chemical extraction technique, the experimental results revealed that three types of polycyclic aromatic hydrocarbons (PAH) were observed moving into the K. candel and its translocation to radicle, hypocotyl and leaf, and the transmission rates of these PAH in the K. candel were in the order of NAP?>?PHE?>?PYR. Data demonstrate the manner in which PAH enter, transport, and distribute within the K. candel, and provided us some valuable information on uptake and translocation mechanism of PAH. These findings may help to optimize the phytoremediation strategies of PAH in mangrove wetlands. 相似文献
170.
The effects of Cd++ concentration increment in soil and/or in atmosphere, on germination, growth and alkaloid contents of Datura metel L. were investigated. We observed a significant reduction of growth following addition of Cd++ in soil. Minor effects on growth were evident when the plants were sprayed with CdCl2 solution (10mgCd++/l). Scanning electron microscope observation showed stomata widely open and conspicuous cuticular striations in the foliar epidermis of polluted plants. GLC analysis of extracts evidenced a significant variation in active principle content among plants undergoing different treatments. 相似文献