全文获取类型
收费全文 | 2682篇 |
免费 | 254篇 |
国内免费 | 648篇 |
专业分类
安全科学 | 323篇 |
废物处理 | 48篇 |
环保管理 | 185篇 |
综合类 | 1998篇 |
基础理论 | 418篇 |
污染及防治 | 257篇 |
评价与监测 | 214篇 |
社会与环境 | 77篇 |
灾害及防治 | 64篇 |
出版年
2024年 | 47篇 |
2023年 | 86篇 |
2022年 | 110篇 |
2021年 | 124篇 |
2020年 | 96篇 |
2019年 | 92篇 |
2018年 | 65篇 |
2017年 | 89篇 |
2016年 | 92篇 |
2015年 | 114篇 |
2014年 | 189篇 |
2013年 | 118篇 |
2012年 | 160篇 |
2011年 | 159篇 |
2010年 | 156篇 |
2009年 | 138篇 |
2008年 | 157篇 |
2007年 | 135篇 |
2006年 | 143篇 |
2005年 | 176篇 |
2004年 | 136篇 |
2003年 | 179篇 |
2002年 | 97篇 |
2001年 | 93篇 |
2000年 | 68篇 |
1999年 | 71篇 |
1998年 | 71篇 |
1997年 | 58篇 |
1996年 | 69篇 |
1995年 | 64篇 |
1994年 | 49篇 |
1993年 | 48篇 |
1992年 | 34篇 |
1991年 | 42篇 |
1990年 | 31篇 |
1989年 | 19篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 3篇 |
排序方式: 共有3584条查询结果,搜索用时 203 毫秒
171.
Chemical forms of Zn, Ni, Cu, and Pb in municipal sewage sludge were investigated by adding humus soil to sludge and by
performing sequential extraction procedures. In the final sludge mixtures, Zn and Ni were mainly found in Fe/Mn oxide-bound (F3) and
organic matter/sulfide-bound (F4) forms. For Zn, exchangeable (F1), carbonate-bound (F2), and F3 forms were transformed to F4 and
residual forms (F5). For Ni, F1 and F2 forms were transformed to F1, F2, and F3 forms. Both Cu and Pb were strongly associated with
the stable forms F4 and F5. For Cu, F2 and F3 forms were major contributors, while for Pb, F3 and F4 forms were major contributors to
F5. Humus soil dosage and pH conditions in the sludge were strongly correlated with the forms of heavy metals. Five forms were used
to evaluate metal mobilities in the initial and final sludge mixtures. The mobilities of the four heavy metals studied decreased after 28
days. The metal mobilities in the final sludge mixtures were ranked in the following order: Ni > Zn > Cu = Pb. Leaching tests showed
that the mobilities of Zn and Ni in lower pH conditions (pH 4) were higher than those in higher pH conditions (pH 8). 相似文献
172.
Remediation of copper polluted red soils with clay materials 总被引:2,自引:0,他引:2
Attapulgite and montmorillonite were utilized to remediate heavy metal polluted red soils in Guixi City, Jiangxi Province, China.
The e ects of clay minerals on availability, chemical distribution, and biotoxicity of Cu and Zn were evaluated. The results provided
a reference for the rational application of clay materials to remediate heavy metal contaminated soils. From the sorption experiment,
the maximum adsorbed Cu2+ by attapulgite and montmorillonite was 1501 and 3741 mg/kg, respectively. After polluted red soil was
amended with attapulgite or montmorillonite and cultured at 30 and 60 days, soil pH increased significantly compared to the control. An
8% increase in the amount of montmorillonite in soil and 30 days incubation decreased acid exchangeable Cu by 24.7% compared to the
control red soil. Acid exchangeable Cu decreased with increasing amounts of attapulgite and montmorillonite, with best remediation
e ect reached at a dose of 8%. Results also showed that the Cu poisoning e ect on earthworms was reduced with the addition of
attapulgite and montmorillonite. Montmorillonite showed the best e ect, with the addition of a 2% dose the mortality of earthworms
decreased from 60% to zero compared to the control. Our results indicated that the bioavailability of Cu in soils was reduced more
e ectively with the application of montmorillonite than attapulgite. 相似文献
173.
The adsorption behaviors of heavy metals onto novel low-cost adsorbent, red loess, were investigated. Red loess was characterized by X-ray diffraction, scanning electron microscopy and Fourier transform infrared spectra. The results indicated that red loess mainly consisted of silicate, ferric and aluminum oxides. Solution pH, adsorbent dosage, initial metal concentration, contact time and temperature significantly influenced the efficiency of heavy metals removal. The adsorption reached equilibrium at 4 hr, and the experimental equilibrium data were fitted to Langmuir monolayer adsorption model. The adsorption of Cu(II) and Zn(II) onto red loess was endothermic, while the adsorption of Pb(II) was exothermic. The maximum adsorption capacities of red loess for Pb(II), Cu(II) and Zn(II) were estimated to be 113.6, 34.2 and 17.5 mg/g, respectively at 25°C and pH 6. The maximum removal efficiencies were 100% for Pb(II) at pH 7, 100% for Cu(II) at pH 8, and 80% for Zn(II) at pH 8. The used adsorbents were readily regenerated using dilute HC1 solution, indicating that red loess has a high reusability. All the above results demonstrated that red loess could be used as a possible alternative low-cost adsorbent for the removal of heavy metals from aqueous solution. 相似文献
174.
175.
176.
177.
根据循环经济理论,针对新疆循环经济的发展,从资源可承载能力、环境发展、社会经济发展三个方面考虑建立新疆循环经济发展的综合评价指标体系,运用熵值法对新疆10年循环经济的发展水平进行综合评价,进而提出了相应的措施,包括完善法律法规体系、加快产业结构调整、加大政策鼓励力度、促进产业集聚等。 相似文献
178.
孙大鹏 《辽宁城乡环境科技》2014,(3):53-55
我国农业土壤重金属污染十分严重,在所有的重金属污染中,Cd以其移动性大、毒性高成为最受关注的重金属污染之一。修复Cd污染的土壤,已成为我国农业可持续发展亟待解决的问题。与传统环境修复技术相比,植物修复技术治理成本低廉,土壤破坏力小,安全性高,是目前发展最快的环境友好、经济、高效的治理技术。介绍了Cd污染现状、超积累植物的概念和特征、土壤重金属污染植物修复国内外研究进展,并对其发展趋势进行了分析。 相似文献
179.
分析2013年大气降水pH值及近10年历史演变的方法分析丹东市酸雨污染现状、特征,并从污染源和气候条件解释酸雨形成的原因,确定酸雨的形成受外来空气污染物影响较大,而酸雨强度的大小具有本地环境条件和环境污染特征。 相似文献
180.
采用AMS14C测年技术建立了哈尼泥炭地的年代序列,以泥炭碱提取液的E4/E6值(400nm和600nm处吸光度比值)来表征泥炭腐殖化度,并探讨其指示的古气候意义。研究结果表明:根据泥炭碱提取液E4/E6值与校正年龄的变化曲线,以及将其与哈尼泥炭400nm处吸光度直接表征腐殖化度的曲线进行对比,发现哈尼泥炭碱提取液的E4/E6值对古气候具有很好的指示意义,对全新世以来的气候突变事件以及前人研究的气候时期划分都能得到很好的对应,即哈尼泥炭碱提取液E4/E6值高,泥炭腐殖化度低,指示气候干冷,其E4/E6值低,泥炭腐殖化度高,指示气候暖湿。在今后的研究中,可结合E4/E6值来表征泥炭腐殖化度,并结合磁化率、孢粉等化学物理生物因子以及温度、湿度、水文、地质条件等其他因素来探讨泥炭腐殖化度对古气候的指示意义。 相似文献