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91.
大气细颗粒物在线源解析方法研究进展 总被引:4,自引:0,他引:4
基于对国内外关于PM2.5化学组分特征、二次气溶胶生成机理、源解析模型的研究综述,引入实现PM2.5在线源解析的2种可能方法,即气溶胶质谱+解析算法与3类化学组分组合观测+受体模型。重点阐述了气溶胶质谱及在线水溶性离子、EC/OC和金属元素仪器的应用研究现状,并分析了不同仪器测定结果的可靠性、优势及缺陷,在此基础上提出加强城市尺度的大气化学二次反应机理及关键技术参数研究、大气颗粒物化学组分连续观测应用于在线源解析的研究、基于多种信息来源和技术手段的在线源解析方法集成研究等建议。 相似文献
92.
西安是空气污染监控和防治有代表性的西部大型城市。研究了西安市及周边地区上空气溶胶光学厚度与PM10浓度的关系模型。利用2011—2012年MODIS卫星气溶胶光学厚度(AOD)遥感产品,通过数据匹配,利用地面气象观测站点的能见度数据和相对湿度数据对AOD产品进行垂直标高订正和湿度订正,2项订正显著提高了AOD和地面PM10浓度的相关性,相关系数从0.36提高到0.65,按季节分类统计和订正春至冬四季的相关系数分别为0.57、0.71、0.62和0.87,夏季和冬季的订正更为有效,可用性更高,这可能由于受到不同季节气溶胶来源和特征的影响。为研究中国西部大型城市,特别是西安市空气环境监测和区域联防联控提供了一种有效方法。 相似文献
93.
Gan Zhang Jun Li Yue Xu Jian-Hui Tang Xiang Liu 《Environmental pollution (Barking, Essex : 1987)》2010,158(11):3392-3400
Carbonaceous aerosols were studied at three background sites in south and southwest China. Hok Tsui in Hong Kong had the highest concentrations of carbonaceous aerosols (OC = 8.7 ± 4.5 μg/m3, EC = 2.5 ± 1.9 μg/m3) among the three sites, and Jianfeng Mountains in Hainan Island (OC = 5.8 ± 2.6 μg/m3, EC = 0.8 ± 0.4 μg/m3) and Tengchong mountain over the east edge of the Tibetan Plateau (OC = 4.8 ± 4.0 μg/m3, EC = 0.5 ± 0.4 μg/m3) showed similar concentration levels. Distinct seasonal patterns with higher concentrations during the winter, and lower concentrations during the summertime were observed, which may be caused by the changes of the regional emissions, and monsoon effects. The industrial and vehicular emissions in East, Southeast and South China, and the regional open biomass burning in the Indo-Myanmar region of Asia were probably the two major potential sources for carbonaceous matters in this region. 相似文献
94.
95.
Y. M. Kwon C. L. Woodward D. E. Corrier J.A. Byrd S. D. Pillai S.C. Ricke 《Journal of environmental science and health. Part. B》2013,48(4):517-525
Abstract Screening of poultry flocks for foodborne pathogen Salmonella contamination is critical for Salmonella control in preharvest stages of poultry production. In this study, two sampling methods (litter and air filter) were compared for detection of S. typhimurium from experimentally infected chicks some of which had received either a probiotic competitive exclusion culture or transfer of cecal contents from salmonellae‐free adult birds. At 4, 9, and 11 days after inoculation, S. typhimurium samples were enumerated by selective plating. For both types of sampling, the control birds yielded the greatest levels of environmental contamination followed by the samples from the probiotic inoculated birds with the birds receiving the cecal transfer culture having the lowest levels of contamination. Although the two sampling methods responded in a similar fashion, detection sensitivity needs to be increased for air filter sampling. 相似文献
96.
Zhenhao Ling Liqing Wu Yonghong Wang Min Shao Xuemei Wang Weiwen Huang 《环境科学学报(英文版)》2022,34(4):259-285
Secondary organic aerosol(SOA) is a very important component of fine particulate matter(PM2.5) in the atmosphere. However, the simulations of SOA, which could help to elucidate the detailed mechanism of SOA formation and quantify the roles of various precursors, remains unsatisfactory, as SOA levels are frequently underestimated. It has been found that the performance of SOA formation models can be significantly improved by incorporating the emission and evolution of semivolatile and ... 相似文献
97.
K. W. Schatz V. M. Fthenakis 《Journal of Loss Prevention in the Process Industries》1994,7(6):451-456
Fluid bed tests were used to determine overall reaction rates for eight different dry powders of low hazard and toxicity before and after reaction with HF. In flow chamber tests, a representative oxide, hydroxide and carbonate were used to measure the efficiency of mitigation of an HF aerosol cloud. The results show that dry powders provide a valid alternative to water spray mitigation. Powder efficiencies are higher than water efficiencies at constant weight ratio.
At present, no attempt has been made to provide any technical designs or layouts for powder mitigation systems. However, the technology for smaller systems is available through manufacturers of dry powder chemical fire extinguisher equipment. When these powders are kept dry and under nitrogen atmosphere, a shelf life of several years can be expected. 相似文献
98.
Plumes of atmospheric aerosol have been studied using a rangeof satellite and ground-based techniques. The Sea-viewing WideField-of-view Sensor (SeaWiFS) has been used to observe plumesof sulphate aerosol and Saharan dust around the coast of theUnited Kingdom. Aerosol Optical Thickness (AOT) was retrievedfrom SeaWiFS for two events; a plume of Saharan dusttransported over the United Kingdom from Western Africa and aperiod of elevated sulphate experienced over the Easternregion of the UK. Patterns of AOT are discussed and related tothe synoptic and mesoscale weather conditions. Furtherobservation of the sulphate aerosol event was undertaken usingthe Advanced Very High Resolution Radiometer instrument(AVHRR). Atmospheric back trajectories and weather conditionswere studied in order to identify the meteorologicalconditions which led to this event. Co-located ground-basedmeasurements of PM10 and PM2.5 were obtained for 4sites within the UK and PM2.5/10 ratios were calculatedin order to identify any unusually high or low ratios(indicating the dominant size fraction within the plume)during either of these events. Calculated percentiles ofPM2.5/10 ratios during the 2 events examined show thatthese events were notable within the record, but were in noway unique or unusual in the context of a 3 yr monitoringrecord. Visibility measurements for both episodes have beenexamined and show that visibility degradation occurred duringboth the sulphate aerosol and Saharan dust episodes. 相似文献
99.
本文简述了大气污染与气溶胶的关系,论述了平流层气溶胶对地球辐射收支的影响,从而说明平流层气溶胶的光学性质的变化将影响全球大气环境,在此基础上,计算了不同背景平流层气溶胶的光学常数和光学特性参数。并使用模式光学常数计算了3种火山模工气溶胶的光学特性参数。同时,考察了这些特性参数对光学常数的敏感性。结果表明,后向散射系数对光学常数的变化最敏感,对于某些波长,它的相对变化可比光学常数的相对变化大一个数量 相似文献
100.
Chung-Ming Liu 《Chemistry and Ecology》1996,12(1):147-161
In this paper, three sensitivity studies are designed to analyze the effect of the NMHC (Non-Methane HydroCarbon) composition, the aerosol back-scattering and the high chimney NOx emission to the photochemical prodution of ozone by using a one-dimensional photochemistry-diffusion model under a favourable meteorological condition. Measurements of the NMHC composition in Taipei indicated that the percentage of iso-butene, cis-2-butene, trans-2-butene and benzene in a unit volume was much higher than of those observed in other major cities. the high ratio of benzene was directly linked to its high percentage in gasoline. As to the unusually high amount of iso-butene, cis-2-butene and trans-2-butene, more researches are needed to identify their source. Concerns are raised as to how productive is NMHC composition is to the photochemical production of the surface ozone. A rough estimate shows that the total reactivity of the Taipei NMHC composition is about 1.21 × 10-9 cm3 s-1 which is 1.6 times that of the Los Angeles (LA) NMHC composition, while the simulated noon peak will be different by 28 ppbv, i.e. 18% more than that simulated with a LA composition.
Meanwhile, high aerosol loading is a serious problem in Taipei. the attenuation of the UV radiation by aerosols cannot be ignored. A numerical simulation shows that the noon ozone level will decrease from 178 to 141ppbv, i. e. about 21% reduction, with deterioration of the visual range from 85 to 5 km.
In the southern Taiwan, industry parks are mixed with the populated Kaohsiung city, hence the large emission of NOx from high chimneys cannot be ignored. in this study, NOx is assumed to be emitted in the layer between 235-460 m high with an emission rate of 0.05 or 0.145 ppbv/sec. the results show that the NOx emitted from the elevated stack lead to a considerable reduction of surface ozone. Such conclusion is obtained due to the fact that a one-dimensional model is used in this paper. Whereas, if a three-dimensional regional model was used, then a higher productivity of ozone downstream would be simulated. 相似文献
Meanwhile, high aerosol loading is a serious problem in Taipei. the attenuation of the UV radiation by aerosols cannot be ignored. A numerical simulation shows that the noon ozone level will decrease from 178 to 141ppbv, i. e. about 21% reduction, with deterioration of the visual range from 85 to 5 km.
In the southern Taiwan, industry parks are mixed with the populated Kaohsiung city, hence the large emission of NOx from high chimneys cannot be ignored. in this study, NOx is assumed to be emitted in the layer between 235-460 m high with an emission rate of 0.05 or 0.145 ppbv/sec. the results show that the NOx emitted from the elevated stack lead to a considerable reduction of surface ozone. Such conclusion is obtained due to the fact that a one-dimensional model is used in this paper. Whereas, if a three-dimensional regional model was used, then a higher productivity of ozone downstream would be simulated. 相似文献