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931.
Empirical and simulated critical loads for nitrogen deposition in California mixed conifer forests 总被引:2,自引:0,他引:2
Fenn ME Jovan S Yuan F Geiser L Meixner T Gimeno BS 《Environmental pollution (Barking, Essex : 1987)》2008,155(3):492-511
Empirical critical loads (CL) for N deposition were determined from changes in epiphytic lichen communities, elevated NO(3)(-) leaching in streamwater, and reduced fine root biomass in ponderosa pine (Pinus ponderosa Dougl. ex Laws.) at sites with varying N deposition. The CL for lichen community impacts of 3.1kg ha(-1) year(-1) is expected to protect all components of the forest ecosystem from the adverse effects of N deposition. Much of the western Sierra Nevada is above the lichen-based CL, showing significant changes in lichen indicator groups. The empirical N deposition threshold and that simulated by the DayCent model for enhanced NO(3)(-)leaching were 17kg N ha(-1) year(-1). DayCent estimated that elevated NO(3)(-) leaching in the San Bernardino Mountains began in the late 1950s. Critical values for litter C:N (34.1), ponderosa pine foliar N (1.1%), and N concentrations (1.0%) in the lichen Letharia vulpina ((L.) Hue) are indicative of CL exceedance. 相似文献
932.
对内置转盘式PVDF膜生物反应器(SRMBR)处理污水工艺及膜清洗进行了研究.SRMBR处理污水可以长期稳定运行,在实验模拟污水COD为180~368 mg/L时,出水COD在运行1d后稳定在20 mg/L以内,COD去除率>93%.增大转盘式平板膜组件转速可以增大SRMBR的平衡水通量,转速从15 r/min增大到25 r/min,平衡水通量从42.5 L/(m2·h)增大到47.5L/(m2·h).在一定自吸泵停抽时间内(0~1 min),延长停抽时间有利于减缓膜污染、提高平衡水通量.对污染的膜进行水洗、水洗 碱洗、水洗 碱洗 酸洗,3种清洗方式分别使膜平衡水通量恢复至新膜平衡水通量的48.4%、83.5%、90.2%. 相似文献
933.
Windblown dust is known to impede visibility, deteriorate air quality and modify the radiation budget. Arid and semiarid areas with unpaved and unvegetated land cover are particularly prone to windblown dust, which is often attributed to high particulate matter (PM) pollution in such areas. Yet, windblown dust is poorly represented in existing regulatory air quality models. In a study by the authors on modeling episodic high PM events along the US/Mexico border using the state-of-the-art CMAQ/MM5/SMOKE air quality modeling system [Choi, Y.-J., Hyde, P., Fernando, H.J.S., 2006. Modeling of episodic particulate matter events using a 3D air quality model with fine grid: applications to a pair of cities in the US/Mexico border. Atmospheric Environment 40, 5181–5201], some of the observed PM10 NAAQS exceedances were inferred as due to windblown dust, but the modeling system was incapable of dealing with time-dependent episodic dust entrainment during high wind periods. In this paper, a time-dependent entrainment parameterization for windblown dust is implemented in the CMAQ/MM5/SMOKE modeling system with the hope of improving PM predictions. An approach for realizing windblown dust emission flux for each grid cell over the study domain on an hourly basis, which accounts for the influence of factors such as soil moisture content, atmospheric stability and wind speed, is presented in detail. Comparison of model predictions with observational data taken at a pair of US/Mexico border towns shows a clear improvement of model performance upon implementation of the dust emission flux parameterization. 相似文献
934.
George P. Ingersoll M. Alisa Mast Donald H. Campbell David W. Clow Leora Nanus John T. Turk 《Atmospheric environment (Oxford, England : 1994)》2008,42(24):6098-6113
Seasonal snowpack chemistry data from the Rocky Mountain region of the US was examined to identify long-term trends in concentration and chemical deposition in snow and in snow-water equivalent. For the period 1993–2004, comparisons of trends were made between 54 Rocky Mountain Snowpack sites and 16 National Atmospheric Deposition Program wetfall sites located nearby in the region. The region was divided into three subregions: Northern, Central, and Southern. A non-parametric correlation method known as the Regional Kendall Test was used. This technique collectively computed the slope, direction, and probability of trend for several sites at once in each of the Northern, Central, and Southern Rockies subregions. Seasonal Kendall tests were used to evaluate trends at individual sites.Significant trends occurred during the period in wetfall and snowpack concentrations and deposition, and in precipitation. For the comparison, trends in concentrations of ammonium, nitrate, and sulfate for the two networks were in fair agreement. In several cases, increases in ammonium and nitrate concentrations, and decreases in sulfate concentrations for both wetfall and snowpack were consistent in the three subregions. However, deposition patterns between wetfall and snowpack more often were opposite, particularly for ammonium and nitrate. Decreases in ammonium and nitrate deposition in wetfall in the central and southern rockies subregions mostly were moderately significant (p<0.11) in constrast to highly significant increases in snowpack (p<0.02). These opposite trends likely are explained by different rates of declining precipitation during the recent drought (1999–2004) and increasing concentration. Furthermore, dry deposition was an important factor in total deposition of nitrogen in the region. Sulfate deposition decreased with moderate to high significance in all three subregions in both wetfall and snowpack. Precipitation trends consistently were downward and significant for wetfall, snowpack, and snow-telemetry data for the central and southern rockies subregions (p<0.03), while no trends were noted for the Northern Rockies subregion. 相似文献
935.
Wetherbee GA Gay DA Brunette RC Sweet CW 《Environmental monitoring and assessment》2007,131(1-3):49-69
The National Atmospheric Deposition Program/Mercury Deposition Network (MDN) provides long-term, quality-assured records of
mercury in wet deposition in the USA and Canada. Interpretation of spatial and temporal trends in the MDN data requires quantification
of the variability of the MDN measurements. Variability is quantified for MDN data from collocated samplers at MDN sites in
two states, one in Illinois and one in Washington. Median absolute differences in the collocated sampler data for total mercury
concentration are approximately 11% of the median mercury concentration for all valid 1999–2004 MDN data. Median absolute
differences are between 3.0% and 14% of the median MDN value for collector catch (sample volume) and between 6.0% and 15%
of the median MDN value for mercury wet deposition. The overall measurement errors are sufficiently low to resolve between
NADP/MDN measurements by ±2 ng·l−1 and ±2 μg·m−2·year−1, which are the contour intervals used to display the data on NADP isopleths maps for concentration and deposition, respectively. 相似文献
936.
Demirak A 《Environmental monitoring and assessment》2007,129(1-3):189-196
In this study, the chemical composition of the rainwater in Yatağan, which is a region surrounding a coal power plant was
investigated from February to April 2002. Rainwater samples were obtained from Yatağan, located northwest of Muğla City in
Turkey. pH values and concentrations of major ions (Ca2+, Na+, K+, , , ) in the rainwater samples were analyzed. The pH varied from 5.1 to 7.9 with an average of 6.7 which was in alkaline range
considering 5.6 as the neutral pH of cloud water in equilibrium with atmospheric CO2. In the total of 30 rain events, only three events were observed with water in the acidic range (<5.6), which occurred after
continuous rains. The equivalent concentration of components followed the order: Ca2+ > > Na+ > > > K+ > H+. The anion and cation concentrations in the rainwater samples showed a high sulphate concentration (131 μEq/l), as well as
high sodium (40 μEq/l) and calcium (298 μEq/l) concentrations. These values indicate that one probable source of the high
sodium concentration is fly ash, after the coal burning process and the power plant can be effective on level concentrations in rainwater. In addition, the dust-rich local and surrounding limestone environment might have caused the
high concentration of Ca2+ in rainwater of the Yatağan Basin. Due to a large contribution of these cations to the sulphate neutralization action, the
rainwater of this region displays only a moderate acidity, which does not cause significant environmental impact. 相似文献
937.
小麦在与水杨酸诱导的应答过程中PGIP的积累 总被引:7,自引:1,他引:6
以SW89-2589小麦品系为材料,利用自制的小麦抗PGIP血清和dot-immunobinding assay,并结合PGIP粗提液对endo-PG的抑制实验,研究了小麦内源多聚半乳糖醛酸酶抑制蛋白(PGIP)水平与水杨酸之间的应答关系。发现用水杨酸处理过的PGIP粗提液在NC膜上的显色斑点颜色均较H2O处理的PGIP粗提液深,而且对en-do-PG的抑制程度也高于未用水杨酸处理的PGIP粗提液 相似文献
938.
在湖北农村 10个地点 ,利用澳大利亚集雨器自 1996年 1月至 1998年 6月 ,按季度采集大气降水样品测定SO2 - 4浓度 ,并对数据进行统计分析。研究结果表明 ,各地 1997年降水中SO2 - 4浓度年均值比 1996年显著升高 ;大多数地点 1996、1997、1998年 1季度和 2季度降水中SO2 - 4浓度呈逐年升高趋势 ;大多数地点每年 1、4季度降水中SO2 - 4浓度高 ,2、3季度降水中SO2 - 4浓度低 ,说明湖北农村降水中的硫对秋冬作物影响比对春夏作物影响大 ;湖北农村降水中SO2 - 4浓度近两年不仅有时间变化规律 ,而且同一季度内的地区差异也很明显 ,在 1996年和 1997年 8个季度 10个点的降水SO2 - 4浓度最大值中 ,有 4个最大值出现在襄樊 ,它是目前湖北继宜昌市区、恩施市区之后又一个酸雨发展较快的地区 相似文献
939.
940.
负载型固体超强酸催化剂上的烷基化反应 总被引:3,自引:0,他引:3
本文利用Pt/SO^2-4/ZrO2,Pt/WO3/ZrO2负载于大比表面Al2O3固体强酸催化剂,进行异丁烷和丁烯的烷基化反应。 相似文献