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31.
酸碱复合改性海泡石亚结构特征及其对Cd(Ⅱ)吸附性能 总被引:2,自引:1,他引:1
为强化海泡石(Sep)对溶液中Cd2+的吸附性能,采用酸碱复合改性处理获得改性海泡石(ABsep),借助氮气吸脱附等温线、SEM-EDS、TEM、FTIR和XRD等技术分析了改性前后海泡石的结构特征,采用静态吸附实验研究了时间、ABsep/Cd2+质量比、温度、吸附剂用量、pH及共存离子等因素对ABsep吸附Cd2+的影响.结果表明,ABsep孔隙结构发达,比表面积、平均孔径和孔容分别较改性前增加66.1%、15.7%和34.8%,可交换性离子含量有所增加,主要成分为SiO2和Mg(OH)2.改性前后海泡石对Cd2+吸附过程能较好地以准二级动力学方程和Langmuir模型进行拟合,且均为自发吸热反应,以化学吸附为主并伴有物理性吸附;最佳ABsep/Cd2+质量比为3:1;298 K时Sips拟合ABsep对Cd2+最大饱和吸附量为142.43 mg·g-1,为改性前海泡石的3.55倍;随着吸... 相似文献
32.
研究了处理TNT酸性废水的铁还原中和方法。该法用铁将硝基苯类还原成苯胺类,然后通过石灰乳中和生成Fe(OH)2胶体,吸附苯胺类,达到去除硝基苯类的目的。在过量铁还原60min,中和沉淀pH8—9的最佳条件下,可将废水中的硝基苯类从82.0mg/L降到未检出程度(<0.2mg/L),CODcr从394.0mg/L降到94.8mg/L。处理后的废水中的苯胺类也未检出(<0.03mg/L)。该法的物料消耗费用约为传统的活性碳吸附法的17.5%。 相似文献
33.
我国东部七省生态系统对酸沉降的相对敏感性 总被引:1,自引:0,他引:1
周修萍 《生态与农村环境学报》1996,(1)
讨论了影响亚热带生态系统对酸沉降敏感性的生态因子,提出了敏感性等级划分的指标体系,根据大量资料编制了我国东部7省1市生态系统对酸沉降相对敏感性分区图。结果表明,在研究区域内生态系统的敏感性有相当大的差别,极敏感区和敏感区面积占全区总面积的1/3以上,主要分布在福建、浙江、江西3省。 相似文献
34.
Jeffrey R. Brook Alan H. Wiebe Sandra A. Woodhouse Celine V. Audette Tom F. Dann Sandra Callaghan Maria Piechowski Ewa Dabek-Zlotorzynska Joseph F. Dloughy 《Atmospheric environment (Oxford, England : 1994)》1997,31(24):4223-4236
The Canadian Acid Aerosol Measurement Program (CAAMP) was established in 1992 to gain a better understanding of the atmospheric behaviour of fine particle strong acidity (“acid aerosols”) and to facilitate an assessment of the potential health risks associated with acid aerosols and particles in general. During 1992. 1993 and 1994, annular denuder and filter measurements were taken at four sites in Ontario, two in Quebec, three in the Atlantic Provinces and one in the greater Vancouver area. Mean fine particle sulphate concentrations (SO42−) were highest in southern Ontario (annual average ranged from 40–70 nmol m−3), lowest at a site in the Vancouver area (average = 16 nmol m−3) and second lowest in rural Nova Scotia. However, mean fine particle strong acid concentrations (H+) were geographically different. The highest mean concentrations were at the east coast sites (annual average of up to 30 nmol m−3). Acidities were lower in areas where the fine particle acidity experienced greater neutralization from reaction with ammonia. This included the major urban centres (i.e. Toronto and Montréal) and areas with greater amounts of agricultural activity, as in rural southern Ontario. On average, ambient concentrations of fine and coarse particle mass were larger in the urban areas and also in areas where SO42− levels were higher. All the particle components were episodic. However, compared to SO42− and fine particles (PM2.5 or PM2.1, depending upon inlet design), episodes of H+ tended to be less frequent and of shorter duration, particularly in Ontario. Saint John, New Brunswick, had the highest mean annual H+ concentration, which was 30 nmol m−3. H+ episodes (24 h concentration > 100 nmol m−3) were also the most frequent at this location. The high levels in Saint John were partially due to local sulphur dioxide sources and heterogeneous chemistry occurring in fog, which, on average, led to a 50% enhancement in sulphate, relative to upwind conditions.There was a substantial amount of intersite correlation in the day to day variations in H+, SO42− , PM2.5 and PM10 (fine + coarse particles) concentrations, which is due to the influence of synoptic-scale meteorology and the relatively long atmospheric lifetime of fine particles. Sulphate was the most regionally homogenous species. Pearson correlation coefficients comparing SO42− between sites ranged from 0.6 to 0.9, depending on site separation and lag time. In many cases, particle episodes were observed to move across the entire eastern portion of Canada with about a two-day lag between the SO42− levels in southern Ontario and in southern Nova Scotia. 相似文献
35.
36.
铁矿酸性排水的人工湿地处理 总被引:34,自引:2,他引:34
在排放酸性重金属废水的铁矿排土场建设人工湿地处理系统,面积130m~2,废水流量0.5m~3/h,经过两个月的运行测试结果表明:人工湿地系统能有效地处理酸水.酸水pH值由2.6升高到6.1;铜离子由25.79×10~(-6)减少到0.099×10~(-6),去除率为99.7%;铁离子由36.50×10~(-6)降到0.031×10~(-6),去除率为99.8%;锰离子从393.6×10~(-6)降低到107.20×10~(-6),去除率为70.9%. 相似文献
37.
增施磷肥对提高强酸性高硒茶园土壤硒有效性的效果 总被引:3,自引:0,他引:3
通过大田试验,研究了增施钙镁磷肥、过磷酸钙及与生物有机肥混施共6种调控措施对强酸性高硒茶园土壤基本化学性质、土壤有效硒和茶叶中硒质量比的调控效果.结果表明,不同磷肥及不同用量处理对土壤有效硒质量比增加均有效果,高用量的3种处理(钙镁磷肥高用量与生物有机肥混施、钙镁磷肥高用量和过磷酸钙高用量)效果好于正常用量的处理(钙镁磷肥正常用量与生物有机肥混施、钙镁磷肥正常用量、过磷酸钙正常用量),且用量相同的情况下,伴有生物有机肥的磷肥处理效果最好.增施磷肥调控均不同程度地增加了茶叶硒质量比,6种处理的增幅均达到极显著水平(p<0.01). 相似文献
38.
讨论了升流式膨胀滤池的反应过程,导出物料消耗,出水水质及反应时间等在有关理论公式,并根据物料流化理论确定了滤池几何尺寸及工艺提高参数的计算方法。 相似文献
39.
膨润土与PAM联用处理含重金属离子废水 总被引:10,自引:1,他引:10
本文以酸性膨润土与PAM联用处理含重金属离子废水,探讨了去除Cu^2+、Zn^2+、Ni^2+的适宜条件。处理实际废水,达到国家排放标准。 相似文献
40.
Katrin Wendt-Potthoff René Frömmichen Peter Herzsprung Matthias Koschorreck 《Water, Air, & Soil Pollution: Focus》2002,2(3):81-96
To elucidate the role of Fe(III) reduction in mining lake sediments amended with organic substrates, we performed a large (10 m diameter) enclosure experiment in which sediments were amended with Carbokalk, a waste product from sugar industry containing organic carbon and lime. Fe(III) reduction rates were determined monthly by measuring the accumulation of Fe(II) in the sediments in the field. Fe(III) reduction rates were also determined by incubating sediment samples with synthetic Fe(III) oxyhydroxide under in situ temperature in the laboratory. Sulfate reduction was selectively inhibited in the Fe(III) reduction experiments by addition of sodium molybdate. Sulfate reduction was measured by accumulation of reduced inorganic sulfides in the field and by 35S radiotracer using a core injection technique. Sediment incubation and determination of sulfate reduction rates with radiotracer showed that sulfate reduction and direct microbial Fe(III) reduction occured simultaneously in the upper centimeters of the sediments and that both processes contributed to alkalinity generation. However, Fe(III) reduction was the initial process and rates were at least 3.5 fold higher than sulfate reduction rates. The results indicate that the presence of suitable anions for Fe(II) precipitation as carbonate or sulfide is needed in order to prevent loss of potential alkalinity by Fe(II) diffusion and reoxidation in the water column. 相似文献