金催化剂在活性碳上负载活性的研究

探索了以活性炭为载体制备负载型金催化剂的可行性。大量实验表明,将金直接负载在活性炭上,不能够得到具有很好催化活性的催化剂。而以MOx/C作为复合载体能够制备得到具有较高催化活性的金催化剂。进一步探讨了焙烧条件,以及不同载体材料对金催化剂活性的影响。     

TiO2/活性炭负载光催化剂的制备与光催化性能

以粒状活性炭为载体,钛酸丁酯和乙醇为原料,用溶胶-凝胶法及浸渍法制备负载型TiO2光催化剂.通过加入不同分子量和质量的聚乙二醇降低催化剂表面TiO2的粒径,增大比表面积,提高TiO2/C光催化剂的吸附性和光催化活性.以XDA、SEM、TG-DTA、比表面积、亚甲蓝吸附值、钛的负载量及对亚甲蓝的光催化降解性能对催化剂样品进行了表征.结果表明加入1.0 g PEG2000所制备的TiO2/C前驱体经过450℃焙烧后,TiO2的平均晶粒尺寸为12.9 nm,其晶型为锐钛矿型,其比表面积为997.0m2·g-1,对亚甲蓝的吸附值比活性炭基体增加22.5%,100mg·L-1的亚甲蓝溶液用该催化剂在pH为1.0～9.25范围内,2.5 h的降解率达82.5%～96%.     

新型絮凝剂聚合氯化铝钙中铝形态表征及钙含量测定

以Al2O3和CaCO3为原料经高温焙烧酸溶制备工艺合成新型高效絮凝剂——聚合氯化铝钙。采用Al-Ferron逐时络和比色法研究产品中的铝形态;络合滴定法研究钙含量。结果表明:焙烧工艺对钙含量的影响较大,酸溶工艺对钙含量的影响较小。在最佳配比条件下,生成的Alb为最佳;焙烧温度提高Ala、Alc含量减小,Alb含量增大;增长酸溶反应时间Alb含量减少;增加酸用量,Ala、Alc含量减少,Alb含量增大。     

印染废水处理工艺改进的应用研究

通过对湘潭纺织厂废水处理工艺存在的问题进行研究和分析 ,对其废水处理工艺进行了改进。采用“二级生物接触氧化 砂滤 活性生物炭”工艺后 ,废水经其处理 ,水质各项指标超过国家一级排放标准 ,水质可以完全回收利用 ,废水处理成本下降 1 3左右。     

阴离子表面活性剂测定中不同萃取方法的比较

通过对水中阴离子表面活性剂测定中不同萃取方法的比较，从而简化操作步骤，提高了工作效率。     

遥感技术在大气环境监测中的应用综述

综合论述了近20多年来国内外对大气环境遥感监测的研究现状,介绍了应用于大气环境遥感监测的多种方法并着重阐述了被动式空基遥感和主动式地基遥感在大气环境遥感中的应用以及探测气溶胶的卫星传感器的发展历程和特点。最后,对我国大气环境遥感研究中存在问题和发展前景进行了讨论。     

活性磷酸盐用标准色列快速测定

利用钒磷酸盐相对稳定的特点,采用一种快速测定活性磷酸盐的方法,标准色列稳定时间选定为5天,测定范围为0 5～5 0mg L,该方法具有标准制作简便,测定快速的特点,特别适合于工程调试现场监测。     

Effects of Al doping on the structure and properties of goethite and its adsorption behavior towards phosphate

Al substitution in goethite is common in soils, and has strong influence on the structure and physicochemical properties of goethite. In this research, a series of Al-doped goethites were synthesized, and characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR) and extended X-ray absorption fine structure (EXAFS) spectroscopy. The adsorption behavior of these samples towards PO₄^3 − was also investigated. Characterization results demonstrated that increasing Al content in goethite led to a reduction in crystallinity, increase in specific surface area (SSA), and morphology change from needle-like to granular. Rietveld structure refinement revealed that the lattice parameter a remained almost constant and b slightly decreased, but c was significantly reduced, and the calculated crystal density increased. EXAFS analysis demonstrated that the Fe(Al)–O distance in the structure of the doped goethites was almost the same, but the Fe–Fe(Al) distance decreased with increasing Al content. Surface analysis showed that, with increasing Al content, the content of OH groups on the mineral surface increased. The adsorption of phosphate per unit mass of Al-doped goethite increased, while adsorption per unit area decreased owing to the decrease of the relative proportion of (110) facets in the total surface area of the minerals. The results of this research facilitate better understanding of the effect of Al substitution on the structure and properties of goethite and the cycling of phosphate in the environment.     

The ‘green’ and ‘self’ in green self-governance – a study of 264 green space initiatives by citizens

Scholars observe an increased involvement of citizens in green space governance. This paper focuses on green self-governance, in which citizens play a major role in realizing, protecting and/or managing green space. While existing research on green self-governance focuses mostly on specific cases, we aim to contribute towards a large overview via an inventory of 264 green self-governance practices across The Netherlands. With this, we discuss the relevance of green self-governance for nature conservation and its relationship with authorities. In our analysis, we show that green self-governance practices are very diverse: they pursue a wide variety of physical and social objectives; employ a multitude of physical and political activities; involve different actors besides citizens; mobilize different internal and external funding sources; and are active within and outside of protected areas. While green self-governance can contribute towards protection and management of green space and towards social values, we highlight that this contribution is mostly of a local relevance. Most practices are small scale and objectives do not always match those of authorities. Although we speak of self-governance, authorities play an important role in many practices, for example, as financial donor, landowner or regulatory authority. In this, self-governance is often not completely ‘self’.

Abbreviations: PAA: Policy Arrangement Approach; NNN: National Nature Network; N2000: Natura 2000; NCOs: Nature Conservation Organizations; NGOs: Non-governmental organizations     

建筑拆除垃圾应用于水泥混合材的试验研究

选用赣州地区20世纪90年代建成的现已达到拆除期限的建筑物的废弃混凝土和废弃粘土砖,分析了其化学组分和矿物组分,然后通过不同建筑垃圾掺量混合材试验、活性激发试验以及复合混合材试验。结果表明,掺适量建筑垃圾可有效提高水泥的早期强度;添加Ca O能够激发废弃混凝土活性,可达81%,可提高废弃粘土砖活性39.58%;废弃混凝土和废弃粘土砖相互抑制了彼此活性,不宜混合回用。建议建筑垃圾必须分类和活性激发,有利于提高建筑垃圾水泥的强度。