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411.
412.
花生壳活性炭对水中荧光素钠的吸附及动力学 总被引:2,自引:1,他引:1
H3PO4活化花生壳炭(750℃)为吸附剂,荧光素钠为吸附质.考察了炭化温度、投加量、pH、离子强度、吸附时间以及初始浓度对花生壳活性炭吸附荧光素钠的影响.重点研究了花生壳活性炭对荧光素钠的等温吸附特征,并利用准一级、准二级动力学模型和颗粒内扩散方程对花生壳活性炭吸附荧光素钠的动力学过程进行了分析.结果表明,本实验条件下,Langmuir等温吸附模型能很好地描述花生壳活性炭对荧光素钠的吸附效果,吸附强度因子a为正值,表明吸附过程在本实验条件下可自发进行.通过带入实验数据校对得出准二级动力学方程能更好地描述花生壳活性炭对水中荧光素钠的吸附动力学过程. 相似文献
413.
童远林 《防灾减灾工程学报》2000,(3)
以大华北地区 (2 9°~ 4 2°N ,10 9°~ 12 4°E) 1970年以来发生的 11次ML6 0以上地震为研究对象 ,从地震的空间分布入手 ,来研究强震的发生位置与活动断裂带的关系。结果表明 :(1)强震往往发生在地震带发生明显拐折或相互交汇的部位。 (2 )断裂带对于强震的位置有较好的控制作用。 (3)强震前 1~ 5年内主震所在地震带上b值普遍有高值的过程。 相似文献
414.
Preparations of TiO2 film coated on foam nickel substrate by sol-gel processes and its photocatalytic activity for degradation of acetaldehyde 总被引:1,自引:0,他引:1
HU Hai XIAO Wen-jun YUAN Jian SHI Jian-wei CHEN Ming-xi SHANG GUAN Wen-feng 《环境科学学报(英文版)》2007,19(1):80-85
Anatase TiO2 films were successfully prepared on foam nickel substrates by sol-gel technique using tetrabutyl titanate as precursor. The characteristics of the TiO2 films were investigated by XPS, XRD, FE-SEM, TEM and UV-Vis absorption spectra. The photocatalytic activities of TiO2 films were investigated by photocatalytic degradation reactions of gaseous acetaldehyde, an indoor pollutant, under ultraviolet light irradiation. It was found that Ni^2+ doping into TiO2 films due to the foam nickel substrates resulted in the extension of absorption edges of TiO2 films from UV region to visible light region. The pre-heating for foam nickel substrates resulted in the formation of NiO layer, which prevented effectively the injection of photogenerated electrons from TiO2 films to metal nickel. The TiO2 films displayed high photocatalytic activity for the degradation of acetaldehyde, and were enhanced by calcining the substrates and coating TiO2 films repeatedly. The high activity was mainly attributed to the improvement of the characteristics of substrate surface and the increase of active sites on photocatalyst. 相似文献
415.
Metal phthalocyanine has been extensively studied as a catalyst for degradation of carbamazepine (CBZ). However, metal phthalocyanine tends to undergo their own dimerization or polymerization, thereby reducing their activity points and affecting their catalytic properties. In this study, a catalytic system consisting of O-bridged iron perfluorophthalocyanine dimers (FePcF16-O-FePcF16), multi-walled carbon nanotubes (MWCNTs) and H2O2 was proposed. The results showed MWCNTs loaded with FePcF16-O-FePcF16 can achieve excellent degradation of CBZ with smaller dosages of FePcF16-O-FePcF16 and H2O2, and milder reaction temperatures. In addition, the results of experiments revealed the reaction mechanism of non-hydroxyl radicals. The highly oxidized high-valent iron-oxo (Fe(IV)=O) species was the main reactive species in the FePcF16-O-FePcF16/MWCNTs/H2O2 system. It is noteworthy that MWCNTs can improve the dispersion of FePcF16-O-FePcF16, contributing to the production of highly oxidized Fe(IV)=O. Then, the pathway of CBZ oxidative degradation was speculated, and the study results also provide new ideas for metal phthalocyanine-loaded carbon materials to degrade emerging pollutants. 相似文献
416.
椰壳基活性炭吸附高氯酸盐污染物的研究 总被引:1,自引:0,他引:1
为确定高氯酸盐污染物椰壳基活性炭吸附的最佳工艺参数,以高氯酸铵模拟废水为处理对象,通过L25(5)4正交试验考察活性炭投加量、温度、pH值、高氯酸盐初始浓度等参数对活性炭吸附率的影响规律。结果表明,ClO4-的去除率随着活性炭投加量的增加、ClO4-初始浓度的增大而增大,在偏中性的环境中具有较高的去除率,高温不利于活性炭的吸附反应。最佳工艺参数:活性炭投加量为0.4 g/L,pH为中性,温度为25℃,高氯酸盐初始质量浓度为2 mg/L。在最佳工艺参数条件下对ClO4-的吸附率为74.87%。 相似文献
417.
在研究大量地热地质资料的基础上,发现秦皇岛地区存在以断裂构造活动为主要特征的地下热水,区内地下热水的赋存受区域构造、断裂活动、盖层等因素的影响。根据地热资源分布及热储特征,提出秦皇岛地区地热资源开发利用可优先考虑的方向:抚宁县温泉堡、北戴河机场、卢龙县刘田各庄乡赵官庄、黄金海岸及北戴河新城七里海团组。 相似文献
418.
419.
Air quality nearby road traffic tunnel portals: BTEX monitoring 总被引:3,自引:0,他引:3
Fabio Murena 《环境科学学报(英文版)》2007,19(5):578-583
A monitoring campaign of BTEX (benzene, toluene, ethylbenzene, o- m- and p-xylene) was carried out nearby two tunnel portals in the urban area of Naples with the aim to verify air quality in this kind of urban sites. Sampling was carried out using the active adsorption technique. Sampling time was 1 h. Ambient temperature and traffic flow measurements were carried out during each sampling operation. The results indicate that average benzene concentrations at both sites exceed the limit value of 10 μg/Nm^3 established by the European Community (EC) (Dir. 2000/69). Concentration levels of other BTEX are relatively high as well. A correlation between BTEX concentration and two wheeler vehicle flow was observed. 相似文献
420.