锅炉废气流化床污泥干化塔的热力计算与分析

利用锅炉尾部废烟气(120～190℃)干化市政污泥,降低污泥含水率可达到后继合理利用。从三方面对污泥干化进行了分析:1)干燥后污泥含水率与污泥处理量关系;2)入口烟温、流量与污泥处理量关系;3)干燥后烟气相对湿度影响因素分析。结果表明:提高入口烟温、流量,污泥出口含水率都可以提高污泥处理量,高入口烟温、流量下,污泥处理量受含水率的影响更大;污泥出口含水率高时,入口烟温提高使污泥处理量提高增大显著;入口烟气流量愈高,入口烟温提高对污泥处理量的增加愈大。干燥后烟气相对湿度与入口烟温有关,干燥之后的烟气的相对湿度离饱和状态较远,此温度范围内的出口烟气湿度还有较大的余量。     

Computational investigation of the effects of knee airbag design on the interaction with occupant lower extremity in frontal and oblique impacts

Objective: The lower extremity of the occupant represents the most frequently injured body region in motor vehicle crashes. Knee airbags (KABs) have been implemented as a potential countermeasure to reduce lower extremity injuries. Despite the increasing prevalence of KABs in vehicles, the biomechanical interaction of the human lower extremity with the KAB has not been well characterized. This study uses computational models of the human body and KABs to explore how KAB design may influence the impact response of the occupant's lower extremities.

Methods: The analysis was conducted using a 50th percentile male occupant human body model with deployed KABs in a simplified vehicle interior. The 2 common KAB design types, bottom-deploy KAB (BKAB) and rear-deploy KAB (RKAB), were both included. A state-of-the-art airbag modeling technique, the corpuscular particle method, was adopted to represent the deployment dynamics of the unfolding airbags. Validation of the environment model was performed based on previously reported test results. The kinematic responses of the occupant lower extremities were compared under both KAB designs, 2 seating configurations (in-position and out-of-position), and 3 loading conditions (static, frontal, and oblique impacts). A linear statistical model was used to assess factor significance considering the impact responses of the occupant lower extremities.

Results: The presence of a KAB had a significant influence on the lower extremity kinematics compared to no KAB (P <.05) by providing early restraint and distributing contact force on the legs during airbag deployment. For in-position occupants, the KAB generally tended to decrease tibia loadings. The RKAB led to greater lateral motion of the legs compared to the BKAB, resulting in higher lateral displacement at the knee joint and abduction angle change (51.2 ± 21.7 mm and 15° ± 6.0°) over the dynamic loading conditions. Change in the seating position led to a significant difference in occupant kinematic and kinetic parameters (P <.05). For the out-of-position (forward-seated) occupant, the earlier contact between the lower extremity and the deploying KAB resulted in 28.4° ± 5.8° greater abduction, regardless of crash scenarios. Both KAB types reduced the axial force in the femur relative to no KAB. Overall, the out-of-position occupant sustained a raised axial force and bending moment of the tibia by 0.8 ± 0.2 kN and 21.1 ± 8.7 Nm regardless of restraint use.

Conclusions: The current study provided a preliminary computational examination on KAB designs based on a limited set of configurations in an idealized vehicle interior. Results suggested that the BKAB tended to provide more coverage and less leg abduction compared to the RKAB in oblique impact and/or the selected out-of-position scenario. An out-of-position occupant was associated with larger abduction and lower extremity loads over all occupant configurations. Further investigations are recommended to obtain a full understanding of the KAB performance in a more realistic vehicle environment.     

九龙江流域生态环境需水量计算

九龙江流域降雨量和径流量在流域空间和年内分配上明显不均,使枯水季节生态环境用水量在局部河段无法得到满足,导致局部河段水体出现富营养化。根据研究需要,将流域分为12个计算区域。将生态环境需水量分为湿地生态环境需水量和旱地环境生态需水量进行计算,分别为60.431×108m3和84.622×108m3,流域生态环境需水总量合计145.053×108m3。流域多年平均降水量为235.856×108m3,盈余量为90.803×108m3,总体可以满足流域经济社会发展和维护生态系统平衡的需要。但是,生态环境用水量保证程度不但与天然径流量有直接关系,也在很大程度上受人为因素的影响。     

碳排放核算方法概述与比较研究

全球气候变化是当今全球关注的焦点和研究热点,碳排放核算对温室气体减排和控制具有重要意义。对当前碳排放核算方法进行了概述,介绍了各核算方法的基本原理和方法,并分析了各核算方法的特点,将为碳排放核算及其方法的选取提供参考依据。     

产品生命周期可得性水足迹计算方法

水足迹方法试图量化评价人类活动对水资源可得性的影响,从而为水资源可持续利用提供科学的依据.水足迹的评价方法尚未统一,目前全球应用最为广泛的是WFN（water footprint network,水足迹协作网络）水足迹计算方法.基于LCA（life cycle assessment,生命周期评价）方法的基本框架,围绕水资源可得性的水量、水质和空间分布3个因素,在分析现有水足迹计算公式的基础上,指出了WFN水足迹计算方法的不足.根据国际水足迹标准（ISO 14046）的原则和要求,改进了WFN的水足迹计算公式,提出了产品生命周期WAF（water availability footprint,可得性水足迹）定义和评价方法,其中包括单元过程数据计算、背景过程数据处理和生命周期汇总.通过方法对比和案例研究得到:WAF方法统一了水消耗量与水污染量定义中的水质基准,可以明确区分水污染和水净化两类过程,还可以反映区域水资源稀缺程度的影响;采用WAF方法,在现有LCA数据库和软件的支持下可以更为规范地完成生命周期水足迹建模与计算但目前单元过程数据计算中各种污染物的基准浓度选取有不可避免的主观性,将直接影响到水足迹计算结果及其客观性,有待进一步研究.      

Theoretical insights into the degradation mechanisms, kinetics and eco-toxicity of oxcarbazepine initiated by OH radicals in aqueous environments

As an anticonvulsant, oxcarbazepine (OXC) has attracted considerable attention for its potential threat to aquatic organisms. Density functional theory has been used to study the mechanisms and kinetics of OXC degradation initiated by OH radicals in aqueous environment. A total of fourteen OH-addition pathways were investigated, and the addition to the C8 position of the right benzene ring was the most vulnerable pathway, resulting in the intermediate IM8. The H-abstraction reactions initiated by OH radicals were also explored, where the extraction site of the methylene group (C14) on the seven-member carbon heterocyclic ring was found to be the optimal path. The calculations show that the total rate constant of OXC with OH radicals is 9.47 × 10⁹ (mol/L)⁻¹sec⁻¹, and the half-life time is 7.32 s at 298 K with the [·OH] of 10⁻¹¹ mol/L. Moreover, the branch ratio values revealed that OH-addition (89.58%) shows more advantageous than H-abstraction (10.42%). To further understand the potential eco-toxicity of OXC and its transformation products to aquatic organisms, acute toxicity and chronic toxicity were evaluated using ECOSAR software. The toxicity assessment revealed that most degradation products such as OXC-2OH, OXC-4OH, OXC-1O-1OOH, and OXC-1OH' are innoxious to fish and daphnia. Conversely, green algae are more sensitive to these compounds. This study can provide an extensive investigation into the degradation of OXC by OH radicals and enrich the understanding of the aquatic oxidation processes of pharmaceuticals and personal care products (PPCPs).     

区域人均基本农田需求面积测算模型及应用——以江苏省为例

为估计一定区域内基本农田保护面积,论文在探讨基本农田涵义的基础上,提出了区域人均基本农田需求面积的计算模型。该模型综合考虑了城乡居民对农产品的消费、复种指数、粮食作物播种面积比例、单产水平以及城市化水平等因素。以江苏省为例,计算1985-2004年江苏省城乡居民人均粮食消耗总当量。在此基础上,计算1985-2004年江苏省人均基本农田需求面积以及估计2005-2020年江苏省人均基本农田需求面积。结果表明,1985-2004年之间,江苏省人均基本农田需求面积平均值为0.054hm₂,考虑在外饮食情况时,该值为0.059hm₂;2005-2020年之间江苏省人均基本农田需求面积平均值为0.057hm₂。     

火灾下匀质防火保护钢构件温度计算(Ⅰ):理论与公式

介绍了火灾下有匀质防火层保护的钢构件温度计算的一维传热模型。给出了求解该模型的相关边界条件和假定,并给出求解该一维传热模型在不同边界条件下的解。通过分析三种典型防火材料保护下、截面系数不同的三种截面的升温,比较了由我国规范CECS200、欧洲规范、欧钢协标准、美国规范及其他学者推荐的方法得到的结果,并对照有限元结果,考察了不同计算方法的有效性。结果表明,CECS200与国外规范给出的结果符合良好且略微偏高。通过计算典型截面在不同耐火极限要求下的最小保护层厚度,比较了各国规范的设计结果。结果显示,由不同规范推荐的公式计算得到的最小保护层厚度相差不大。CECS200计算的最小保护层厚度与国外规范一致,与欧洲规范得到的结果基本相同。研究表明,在标准火灾环境中我国规范给出的方法合理有效且形式简单便于工程运用。     

采煤工作面漏风通道参数研究与应用

采煤工作面漏风会导致采空区缓慢自燃氧化以及有毒有害气体涌入工作面,造成采空区自然发火及工作面工作人员中毒窒息的可能性.工作面不同进风风量下工作面漏风情况会不同.为了具体研究工作面不同进风风量下的漏风情况,测定了元堡煤矿1901工作面停采期间各漏风通道的漏风量,建立了工作面漏风通道网络模型;根据风网解算原理及风阻计算公式计算出各分支风阻及风量值;利用风网解算软件计算出不同风量下工作面漏风通道的风量值.结果发现:元堡煤矿1901工作面风量在500 - 1500m3/min范围内变化时各漏风通道风量占工作面总进风量的比重几乎不变;采空区两巷由于已经打好密闭,漏风较小;工作面中部由于老顶来压漏风量较大,是堵漏风重点.     

基于二次能源省际调配的中国分省CO2排放量计算

节能减排目标任务的制定需要依据科学合理的CO2排放量测算。现有的IPCC提供的CO2排放量计算方法仅考虑一次能源燃料所产生的CO2,未考虑到二次能源省际调配的情况,不能真实反映各省CO2排放情况。本研究提出了考虑二次能源省际调配情况下CO2排放量的计算方法,并以2009年的数据为例,对各省能源消费CO2排放量进行了计算。考虑二次能源省际调配后,传统的能源大省如内蒙古、山西的CO2排放总量下降,东部沿海省份的CO2排放总量上升。中西部地区的CO2排放强度仍显著高于东部地区。中西部地区存在能源利用效率低、能源加工技术设备落后的情况,导致了西部地区的CO2排放强度偏高。建议中央在实施西部大开发"十二五"规划时,应当加强对中西部地区能源加工行业的投资,改善能源加工技术,改良加工设备,提高能源加工效率,降低CO2排放强度。建议由能源调入省向能源调出省份实施补偿。该部分补偿资金用于调出省的能源产业升级改造,以顺利实现节能减排的目标。