Polyoxometalates for photocatalytic degradation of aqueous dyestuff solutions and quantitative structure–property relationship study on photolysis rate constants

Polyoxometalate, K₆TiW₁₁O₃₉Sn·7H₂O (TiW₁₁Sn), was synthesized and characterized. TiW₁₁Sn and K₆ZrW₁₁O₃₉Sn·12H₂O (ZrW₁₁Sn) were evaluated for their photocatalytic degradation of triarylmethane (brilliant green and acid blue 9), bisazo (C.I. reactive black 5), and monoazo dyestuffs (C.I. reactive red 24, C.I. reactive red 194, and C.I. reactive orange 5) with natural sunlight in homogeneous aqueous solutions. TiW₁₁Sn and ZrW₁₁Sn effectively and photocatalytically decolorized the dyestuffs. The TiW₁₁Sn- and ZrW₁₁Sn-mediated photocatalytic degradation of the dyestuffs involved a pseudo-first-order reaction and was modeled by Langmuir–Hinshelwood-type kinetics. The observed pseudo-first-order rate constants (K^/) of triarylmethane dyestuffs were generally bigger than that of the azo dyestuffs. Quantitative structure–property relationship models of the K^/ of the dyestuffs were developed using partial least-square regression. The cumulative variance of the dependent variable explained by the partial least-square components was > 0.753 for each optimal model. This value indicated that the model had good predictive ability and robustness. The K^/ values of the dyestuffs were related to the energy of the lowest unoccupied molecular orbital, and the most positive net atomic charges on a sulfur atom of dyestuffs. The linear correlation coefficients between the predicted and experimental values were all > 0.9950.     

36种典型除草剂对绿藻的毒性研究

近年来,农药对生态系统的初级生产者——藻类的毒性及其生态毒理学研究引起了国内外学者的广泛关注。除草剂在生产中广泛应用,对藻类的毒性作用最强,其毒性效应远高于杀虫剂和杀菌剂。论文选择市场上具有典型代表性的36种除草剂原药,分析解读除草剂在国内的登记情况,以及在作物、旱田和水田的使用情况;明晰对藻类生长抑制急性毒性效应。结果表明:1)除草剂的作用方式和化学类别对绿藻毒性影响显著;对于抑制植物细胞分裂和作用于植物叶绿体的除草剂对绿藻毒性均较高,以人工合成植物生长素为代表的除草剂对绿藻毒性均较低;2)相同作用方式,不同化学类别的除草剂,对单一绿藻的毒性差异明显。在水稻上获得登记的除草剂对藻类毒性整体低于在旱田获得登记的除草剂对藻类的毒性。开展多种农药对水生生态毒性的研究,为农药的合理安全使用、农药在淡水环境中的生态效应评价以及保护淡水生态系统提供科学依据。     

Fabrication and characterization of electrospun porous cellulose acetate nanofibrous mats incorporated with capric acid as form-stable phase change materials for storing/retrieving thermal energy

Electrospun cellulose acetate (CA) nanofibrous mats incorporated with capric acid was studied to fabricate form-stable phase change materials (PCMs) for storing/retrieving thermal energy. Electrospun CA nanofibrous mats with different porous structures and specific surface areas were firstly prepared through regulating the volume ratio of mixture solvent of acetone/dichloromethane (DCM). Effects of different volume ratio of mixture solvent and mat thickness on the morphological structure, specific surface area, and absorption capacity of CA nanofibrous mats were systematically investigated. The results indicated that CA nanofibrous mats were highly porous on the surface; hence, they were capable of absorbing a large amount of capric acid. The maximum absorption capacity of CA mats via electrospinning with volume ratio of acetone/DCM being 5/5 was ~95.8 wt%, due to its higher specific surface area of ~17.1 m²/g. The specific surface area and capric acid absorption capacity of CA nanofibrous mats increased with the increases of mat thickness. As the thickness of nanofibrous mats increased from 10 to 85 μm, the corresponding specific surface area and capric acid absorption capacity of mats increased respectively from 7.2 to 29.0 m²/g and 92.1 to 98.5%. Morphological structures, as well as the properties of thermal energy storage and thermal insulation of the fabricated form-stable PCMs, were studied by scanning electron microscopy, differential scanning calorimetry, and measurement of freezing times, respectively. The results indicated that the resulting form-stable PCMs could well maintain their phase transition characteristics and demonstrated great thermal energy storage capability and temperature regulation ability.     

上海浦东新区农业发展环境规划研究

基于在发展农业的同时有效地控制农业环境污染的目的,综合环境、经济和社会等方面的因素,建立了浦东新区农业结构优化调整的灰色线性规划模型。该模型将农业结构调整与经济预测、化肥与农药的流失控制以及畜禽粪便污染联系起来,动态地分析规划年份的浦东新区农业生产结构,确定了农业内部结构调整的方针。     

酸化水体中的藻类研究

为研究酸沉降对水生生态系统的影响,1991年至1992年间,对地处我国重酸雨区域的重庆市郊6个水体中的藻类进行了比较研究,结果表明,绿藻门的种类最多,占种类总数的50％以上,其次是蓝藻或硅藻。藻类的细胞密度、生物量和叶绿素ａ,在酸化水体中（pH值<5.0）分别为23.3～49.9万个/L,0.59～1.05mg/L和0.65～3.01mg/m3;在轻度酸化水体（6.0＞pH值＞5.0）分别为433.9～680.0万个/L,6.6～21.75mg/L和14.66～25.19mg/m3。三项指标均随水体酸度的增加而减少。酸化水体中的藻类生长潜力（AGP）很弱,低pH值和可给态磷的不足是造成AGP低的主要限制因素。     

砼芯水泥土复合桩在基坑支护工程中的应用与研究

砼芯水泥土复合桩是一种新型的基坑支护方法,即在水泥土搅拌桩中插入钢筋混凝土预制小方桩,形成一种新的复合桩体,兼有受力和止水的双重作用,并采用两排中间用圈梁相连的门型结构提高了支护结构的受力特性。该支护方案在南京某深基坑工程中得到了成功应用。本文分析了该新方法的结构特点、简要介绍了其设计计算方法,并结合有限元数值模拟和实际的监测数据与排桩方案进行分析比较。研究结果表明,该新型基坑支护形式取得了良好的支护和经济效果,具有重要的应用前景。     

基于小波包分析的框架结构损伤识别

损伤将引起结构动力特性和动力响应的变化,反过来,可以通过结构动力性能或动力响应的变化识别结构损伤,但它们对结构局部损伤并不十分敏感。而小波包分析具有优越的时-频局部化性能,可以在时—频域以任意精度进行信号分析。本文在小波包分析基础上,提出了基于小波包分析的损伤检测和识别方法:首先将结构响应信号分解为小波包组分,然后通过考察各组分小波信号的变化情况识别损伤。该方法仅利用结构响应数据识别损伤,实测方便,计算简单,并通过3层钢框架结构的模型试验成功地识别出损伤时刻和损伤位置,验证了其可行性。     

小型污水处理系统设计建议

针对小型污水处理系统的特点,着眼于提高处理效率、降低能耗、减少产泥、方便管理、节省占地等原则,对其构筑物、设备及工艺的设计经验和发展趋势进行了较为全面的总结,并提出了相应的具体设计建议.     

矿用旋流除尘器用子午加速除尘风机的研制

针对国内煤矿掘进工作面用湿式过滤式旋流除尘器配套除尘风机的工作特点,指出了解决矿用除尘风机安全可靠性的关键技术.特别介绍了新研制的矿用子午加速除尘风机的除尘原理、结构特点、性能指标以及配套除尘器使用效果.     

混凝土结构使役环境中温度智能模拟LabVIEW软件设计

本项目结合湖北省科技计划自然科学基金项目“混凝土结构使役环境的智能模拟”,在WTST-150试验机硬件平台基础上,以LabVIEW8．5为开发平台,设计了一套混凝土结构使役环境中温度智能模拟LabVIEW软件,主要包括能初始化程序、温度采集与显示子程序、温度PID控制子程序、温度存储和查询子程序。经投入实验验证,该软件能实现实时曲线显示、温度控制、试验状态和保存试验数据、数据查询、手动加热、分配温度通道、PID控制参数整定、制冷、读入温度曲线等功能。具有实时在线循环检测、采集数据、响应快速等优点,并具有良好的故障诊断能力和可维护性以及超强的纠错能力。本软件完善了WTST-150试验机的温度控制系统,使其更加符合实际工况。