Flower-, wire-, and sheet-like MnO2-deposited diatomites: Highly efficient absorbents for the removal of Cr(VI)

Flower-, wire-, and sheet-like MnO₂-deposited diatomites have been prepared using a hydrothermal method with Mn(Ac)₂, KMnO₄ and/or MnSO₄ as Mn source and diatomite as support. Physical properties of the materials were characterized by means of numerous analytical techniques, and their behaviors in the adsorption of chromium(VI) were evaluated. It is shown that the MnO₂-deposited diatomite samples with different morphologies possessed high surface areas and abundant surface hydroxyl groups (especially the wire-like MnO₂/diatomite sample). The wire-like MnO₂/diatomite sample showed the best performance in the removal of Cr(VI), giving the maximum Cr(VI) adsorption capacity of 101 mg/g.     

Flower-, wire-, and sheet-like MnO2-deposited diatomites: Highly efficient absorbents for the removal of Cr(VI)

Flower-, wire-, and sheet-like MnO₂-deposited diatomites have been prepared using a hydrothermal method with Mn(Ac)₂, KMnO₄ and/or MnSO₄ as Mn source and diatomite as support. Physical properties of the materials were characterized by means of numerous analytical techniques, and their behaviors in the adsorption of chromium(VI) were evaluated. It is shown that the MnO₂-deposited diatomite samples with different morphologies possessed high surface areas and abundant surface hydroxyl groups (especially the wire-like MnO₂/diatomite sample). Thewire-like MnO₂/diatomite sample showed the best performance in the removal of Cr(VI), giving the maximum Cr(VI) adsorption capacity of 101 mg/g.     

Abatement of SO2-NOx binary gas mixtures using a ferruginous active absorbent: Part I. Synergistic effects and mechanism

A novel ferruginous active absorbent, prepared by fly ash, industrial lime and the additive Fe(VI), was introduced for synchronous abatement of binary mixtures of SO2–NOx from simulated coal-fired flue gas. The synergistic action of various factors on the absorption of SO2 and NOx was investigated. The results show that a strong synergistic effect exists between Fe(VI) dose and reaction temperature for the desulfurization. It was observed that in the denitration process, the synergy of Fe(VI) dose and Ca/(S + N) had the most significant impact on the removal of NO, followed by the synergy of Fe(VI) and reaction temperature, and then the synergy of reaction temperature and flue gas humidity. A scanning electron microscope(SEM) and an accessory X-ray energy spectrometer(EDS)were used to observe the surface characteristics of the raw and spent absorbent as well as fly ash. A reaction mechanism was proposed based on chemical analysis of sulfur and nitrogen species concentrations in the spent absorbent. The Gibbs free energy, equilibrium constants and partial pressures of the SO2–NOx binary system were determined by thermodynamics.     

生态文明视域下技术创新、产业升级与污染控制的互作效应研究

随着工业化和城市化进程的加快,环境污染问题已成为生态文明建设亟需解决的重要问题.生态文明是对农业文明和工业文明的超越,代表了更为高级的人类文明形态.生态文明建设是体现经济、社会、环境可持续发展以及人与自然和谐共存的重要战略决策.本文从环境质量改善及污染控制的有效性方面,深入剖析了技术创新、产业升级与污染控制之间的互作效应关系,并探讨了有效的实现方式.研究结果旨在为生态文明建设的有效实施和顺利展开提供借鉴和参考价值.     

固戍污水处理厂再生回用水工程论证研究

宝安区域污水处理厂出水水质基本是执行城镇污水处理厂污染物排放标准(GB 18918-2002)中一级B标准,需进行深度处理才能再生回用.以固戍污水处理厂为例,分析了实施固戍污水处理厂再生回用水工程的必要性,论证了再生回用水水质、规模和工艺方案,介绍了工程实施后的实际效果.论证的结果表明,采用二级处理加混凝、沉淀、过滤、消毒工艺,来改造宝安区域内的污水处理厂尾水成为再生回用水切实可行.     

丁香蓼对Cu富集效应的研究

通过盆栽实验研究不同浓度的Cu胁迫对丁香蓼响应和富集效应的影响,结果表明,随着Cu的浓度增加,丁香蓼的株高和生物量降低,长势减弱,但在低浓度(ω(Cu)为125 mg/kg)时降低不明显,与对照组差异性不显著,高浓度与对照组差异性显著。根茎叶中Cu含量随着添加的Cu浓度增加而增加,Cu的含量和富集系数都表现为根叶茎,对Cu的积累量表现为根、茎叶,丁香蓼不是Cu的超富集植物,但对Cu具有较好富集作用和忍耐能力。     

双甘膦废水处理技术研究

双甘膦废水中含有高浓度总磷、有机磷、甲醛、氰化物、氨氮、COD,运用三效蒸发＋强氧化＋两级化学除磷＋UASB＋兼氧＋好氧组合处理双甘膦废水。研究结果表明双甘膦废水排放满足《污水综合排放标准》（G88978—1996）二级排放标准。     

典型环境中三种自然环境加速试验方法的环境强化效果分析

目的研究自然环境加速试验方法的环境强化效果。方法通过分析实时监测获得的典型环境不同自然环境加速试验装置中,温湿度环境因素变化数据,找出典型环境中不同自然环境加速试验装置内部的温湿度环境因素变化规律,计算得到典型环境中不同自然环境加速试验方法对温湿度环境因素的强化效果。结果得到了典型环境中不同自然环境加速试验装置的特征温湿度变化规律曲线图。结论玻璃框、黑箱、强制通风玻璃框等3种自然环境加速试验装置对自然环境的光照热效应有明显的强化作用,其内部温度变化梯度大小与环境中太阳辐射量大小相关。     

火炮系统高原环境适应性及防护措施分析

在分析高原环境特点和高原对装备典型环境效应的基础上,结合火炮结构特点和部件类型,从不同部件受高原环境影响因素和影响结果不同的角度,对火炮的动力部分、机械部件、电子器件、液压密封部件和弹簧器件等进行了分类分析,分析了高原环境对火炮各部件的影响情况,并针对性地分析提出了火炮在高原环境下的防护措施。     

某铝厂熔铸项目职业病危害控制效果评价

采用职业卫生调查、职业卫生检测、检查表分析法等方法对某铝厂熔铸项目存在的职业病危害进行了识别、分析,提出了职业病危害防护措施方面的建议。