洗相废水中银回收技术研究

采用电解法和离子交换法回收洗相废水中的银.结果表明,电解法对高浓度含银洗相废水的银回收处理是一种行之有效的方法.对于中低浓度洗相废水中的银的回收,采用4%硫酸再生IRA-68离子交换树脂,树脂的交换能力可以增加4倍,再生时由于已交换的银被直接固定在树脂上,结果使得再生剂处置和银回收过程更加简单方便.IRA-68离子交换树脂回收中低浓度洗相废水中银的技术具有银回收效率更高、离子交换运行时间更长和操作更为简便等优点,使得传统的离子交换技术得到极大的改进和提高.     

微波消解-分光光度法测定COD的研究

通过试验研究,提出了测定COD的新方法——微波消解-分光光度法。该方法准确度、精密度符合分析要求,与国标中回流法的测定结果没有显著差异。而且采用该方法测定COD可克服回流法、微波消解-滴定法及HACH-COD测定法的操作复杂、耗时长等缺点。     

The determination and matching analysis of pinch point temperature difference in evaporator and condenser of organic rankine cycle for mixed working fluid

Exergo-economic analysis of the pinch point temperature difference (PPTD) in both evaporator and condenser of sub-critical organic Rankine cycle system (ORCs) are performed based on the first and second laws of thermodynamics. Taking mixture R13I1/R601a as a working fluid and the annual total cost per net output power Z as exergo-economic performance evaluation criterion, the effects of PPTD in evaporator ΔT_e, and the PPTD ratio of condenser to evaporator y, on the exergo-economic performance of ORCs are analyzed. Moreover, how some other parameters influence the optimal PPTD in evaporator ΔT_e,opt and the optimal PPTD ratio of condenser to evaporator y_opt are also discussed. It has been found that the exergo-economic performance of ORCs is remarkably influenced by ΔT_e and y, and there exists ΔT_e,opt and y_opt. In addition, ΔT_e,opt and y_opt are affected by heat transfer coefficient ratio of condenser to evaporator ß, the temperature of working fluid at dew point in condenser T_1a, and composition of R13I1/R601a: larger ß and T_1a lead to lower ΔT_e,opt and y_opt; by contraries, larger mass fraction of R13I1 makes ΔT_e,opt and y_opt increase, and y_opt increases linearly. The effects of the temperature of working fluid at bubble point in evaporator T_3a, mass flow rate of exhaust flue gas m_g, and inlet temperature of exhaust flue gas T_gi on ΔT_e,opt and y_opt are very slight. For comparison, three additional working fluids, namely R601a, R245fa, and 0.32R245fa/0.68R601a, are also taken into account.     

Experimental investigation of a 250-kW turbine organic Rankine cycle system for low-grade waste heat recovery

An organic Rankine cycle (ORC) is generally used for converting low-grade heat into electricity. In this study, an extensive literature survey was conducted to identify current research gaps on experimental ORC systems. Specifically, there is limited experimental data and limited details on thermal and expander efficiencies of ORC systems. In order to address these gaps, the objective of this study included developing a turbine ORC with a power output exceeding 50 kW and thermal efficiency exceeding 8% for a heat source temperature < 120°C. The experimental results indicated that the system achieved a net power output of 242.5 kW and a thermal efficiency of 8.3% (the highest value for a turbine ORC system for the heat source temperature below 120°C). Thus, the study addressed the gaps identified in the research area of ORCs.     

Don’t Fight the Site: Three Geomorphic Considerations in Catchment-Scale River Rehabilitation Planning

Three geomorphic considerations that underpin the design and implementation of realistic and strategic river conservation and rehabilitation programs that work with the nature are outlined. First, the importance of appreciating the inherent diversity of river forms and processes is discussed. Second, river dynamics are appraised, framing the contemporary behavioral regime of a reach in relation to system evolution to explain changes to river character and behavior over time. Third, the trajectory of a reach is framed in relation to downstream patterns of river types, analyzing landscape connectivity at the catchment scale to interpret geomorphic river recovery potential. The application of these principles is demonstrated using extensive catchment-scale analyses of geomorphic river responses to human disturbance in the Bega and Upper Hunter catchments in southeastern Australia. Differing implications for reach- and catchment-scale rehabilitation planning prompt the imperative that management practices work with nature rather than strive to ‘fight the site.’     

液-固流化床回收印刷线路板中金属的研究

根据废弃印刷线路板中材料密度不同,采用水介质流化床对印刷线路板粉末中的金属进行回收,对0.25～0.177、0.177～0.104、0.104～0.074和-0.074 mm 4个粒级范围内的物料进行分选试验。试验结果表明,在上述4个粒级范围内,随介质流速的增大,金属回收率降低;金属回收率η与实际操作速度（ua）和颗粒终端沉降速度（ut）的比值φ（ua/ut）存在一定线性关系,分析模拟了η与φ之间的相关性方程,外推试验的结果证明了相关性方程的可靠性;在合适的操作条件下,各粒级范围内金属的回收率分别为95.02%、90.07%、87.5%和92.68%。     

三级串联人工快渗系统处理养殖废水

人工快速渗滤系统（constructed rapid infiltration,CRI）是在传统的污水快速渗透系统上发展起来的一种新的生物处理方法。采用猪粪浸泡污水模拟实际猪场处理系统的厌氧出水,研究三级串联人工快渗系统对其污染物的去除效果。试验结果表明,三级串联系统对废水COD、NH3N的去除率稳定在81%和94.5%,出水均满足了《畜禽养殖行业污染物排放标准》（GB18596-2001）的要求,同时三级串联系统还可以有效预防系统的堵塞。     

反渗透处理稀土氨氮废水试验研究

根据稀土冶炼厂排放的碳铵沉淀洗涤废水的水质情况,采用NH4Cl和 NaCl模拟废水进行了反渗透可行性对比实验。模拟实验发现,在相同条件下反渗透对NaCl 较NH₄Cl 有着更高的去除率,而NH₄Cl 相对NaCl则有着更高的产水速率。实际废水试验结果表明,在恒定操作压力范围内回收率为65%的条件下,NH₄Cl浓度为2.85 g/L的碳铵沉淀洗涤废水经反渗透处理其NH₄Cl去除率为77.3%,可作为氨氮废水的预处理。对该废水处理成本进行了分析,得出其约为2.7元/m³,比相近浓度氨氮废水的氨吹脱处理成本节省约26%。     

基于超临界水氧化过程的能源环境系统设计

阐述了超临界水氧化过程的工艺路线,介绍了超临界水氧化过程的特点,提出了基于超临界水氧化过程的能源环境系统,设计了几种热量与能量回收系统程的耦合工艺,为提高超临界水氧化过程的经济性奠定了基础。     

Platinum (IV) recovery from chloride solution by functionalized acrylic copolymers

Two acrylic adsorbents with different morphological structures and bearing amidoethylenamine and thiol groups were obtained and used for platinum sorption from chloride solution by the batch method. Physico-chemical parameters that influence adsorption such as initial Pt(IV) concentration, stirring time, pH, and adsorbent amount were investigated. The thermodynamic parameters of Pt(IV) sorption on the synthesized adsorbent were also evaluated based on Langmuir and Freundlich isotherms. Thermodynamic parameters estimated from Langmuir constants indicated that the adsorption is spontaneous, exothermic and there is a disordered state at the molecular level. The models used to analyze the sorption rate led to the conclusion that the most important step in the sorption of Pt(IV) could be both particle diffusion and chemical reaction of [PtCl₆]⁻ with amine functional groups. Thus, both the ion exchange and complex formation mechanisms can occur via nitrogen atoms in the recovery of Pt(IV) on the studied adsorbent.