多孔不锈钢基氧化铝膜去除水溶液中的Cr(VI)和Cd(II)

通过悬浮粒子浸涂法将合成的γ-Al₂O₃纳米粒子固载于316L多孔不锈钢表面以吸附水溶液中的Cr（VI）和Cd（Ⅱ）.扫描电镜（SEM）和X射线衍射（XRD）测试结果表明,γ相的Al₂O₃纳米粒子均匀地涂在了316L多孔不锈钢基体上,膜体表面沉积厚度约为20 μm.该膜对单一Cr（VI）和Cd（Ⅱ）吸附的最佳pH分别为3.0~4.0和8.0~9.0,吸附均符合动力学准二级模型和Langmuir吸附等温模型,最大吸附量分别为0.603 mg·g^-1和0.399 mg·g^-1.本研究可为水体中的高毒性重金属Cr（VI）和Cd（Ⅱ）去除提供一定的理论和技术参考.     

Environmental and economic benefit of recycling model of packaging waste:a case study on aluminum

In order to achieve sustainable utilization of natural resources, save energy and protect environment and ecosystem, it is important for a region or a nation to develop and implement a viable waste recycling model from both theoretical and practical point of view. Some packaging recycling models operated in developed countries are introduced in this article. Aluminium can recovery and recycling is emphasized. Cost effective, economic and environmental benefit of different models are compared and analyzed. The result shows that all recycling models have their characteristics due to the initial purpose of recovery and the situation of the implementing country. However, all the models contribute to the reduction of municipal solid waste disposal and resources conservation.     

Preparation and characterization of ZnO/ZnS hybrid photocatalysts via microwave-hydrothermal method

The photocatalytic performance of ZnO/ZnS hybrid nanocomposite was largely higher than that of the mere ZnO or ZnS nanoparticles, but the complicated procedure and misdistribution of final products limited its large-scale productions. The exploration of a novel synthesis route of ZnO/ZnS hybrid photocatalysts with high catalytic performance is becoming a crucial step for the large-scale application of ZnO/ZnS hybrid photocatalytic technique. Preparation and characterization of nanosized ZnO/ZnS hybrid photocatalysts were studied in this paper. The photocatalysts were obtained via microwave-hydrothermal crystallization with the help of sodium citrate. The products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), particle size distribution (PSD), and Fourier transformed infrared spectroscopy (FT-IR). The results indicated that so-synthesized ZnO/ZnS samples consisted of the high pure cubic (sphalerite) ZnS and hexagonal ZnO nanocrystallines with a narrow particle size distribution. The possible formation mechanisms of ZnO/ZnS nanocrystallines were mainly attributed to the superficially protective effect of citrate. The photocatalytic experiments demonstrated that the ZnO/ZnS photocatalysts exhibited a higher catalytic activity for the degradation of acid fuchsine than other monocomponents.     

铝暴露对雏鸡免疫功能的影响

以1周龄伊莎雏鸡为实验对象,采用连续腹腔注射的方法,研究了铝暴露对雏鸡免疫功能的影响.实验设对照、低、中、高4个剂量组,暴露剂量分别为0、18.31、27.47、36.62mg·kg-1·d-1(Al3+),暴露60d后,检测雏鸡血清、脾脏和法氏囊中元素Al、Fe、Zn、Mn、Ca、Cu含量及血清补体(C3、C4)、白细胞介素-2(IL-2)和肿瘤坏死因子-α(TNF-α)含量.结果表明,暴露60d后,与对照组雏鸡相比,低、中、高剂量组雏鸡血清、脾脏和法氏囊中Al、血清补体C4和TNF-α含量均有不同程度地升高,而Fe、Zn、Mn、Ca、Cu、C3和IL-2含量均有不同程度地降低;随着铝暴露剂量的增加,Al、C4和TNF-α含量逐渐升高,而Fe、Zn、Mn、Ca、Cu、C3和IL-2含量逐渐降低,均存在一定的剂量-效应关系.上述结果表明,铝暴露对雏鸡免疫功能具有明显的抑制作用.     

玉米铝（Al）胁迫研究初报

通过试验和分析，研究Ａｌ胁迫下的玉米生物性状和主要生理特性，明确活性铝浓度与玉米根系特征及地上部农艺性状之间存在极显著或显著的反比相关；活性铝的存在，降低玉米茎叶Ｎ、Ｐ、Ｋ等养分含量，提高叶片脯氨酸累积量；脯氨酸含量可作为玉米耐Ａｌ性的生理指标．     

番茄柱式无土栽培研究

在立柱密度为 80cm× 80cm的”树林”式柱式无土栽培区种植番茄 (LycopersicumMill) ,品种是洋杂 2号和90 6 ,面积各有 5 4 0m2 (在非自控玻璃温室内 ) ,各含 6 36根立柱 ,每根柱种 3层共 9株 ,总共各有 5 72 4株 .番茄生长期间 ,柱上植株始终保持塔形排列 ,每株留 2穗果约 6只番茄 ,在不影响结果情况下注意去顶、剪叶和去除营养枝 ,以保持柱间有良好透光 .此外 ,在两行立柱之间地面 (除走道外 )铺设中高 10cm倒V字形双面铝 (Al)膜反光体 ,可使柱高 10 0cm以下的光照量增加 5 0 %左右 ,并超过了番茄的光合需要保持量E为 6 0 0～ 70 0 μEm-2 s-1[2 ] 的要求 .立柱由基质型盆钵组成 ,盆钵中的基质有陶粒、用过的香菇菌棒碎料加珍珠岩加有机肥料和难溶磷铁肥 ,于循环水中加入盆钵中没有的成分组成完全的平衡营养系统以循环浇灌 ,结果培养出了粗壮结果良好的的植株 .番茄洋杂 2号亩产为 5 184kg,是对照(深流栽培 )的 2 .4倍 ,又比土栽培的产量高 30 % ;品种 90 6亩产为 5 2 34kg,是对照土栽培的 2 .2倍 .图 2表 3参 2     

Serum and urine monitoring of fluoride exposed workers in aluminium smelting factory

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氧化铝吸附水中腐殖酸的研究

讨论了氧化铝对腐殖酸的吸附性能,以及吸附操作条件的影响。结果表明,500℃以上的热处理,可有效地提高氧化铝水合物对腐殖酸的吸附效果;中性偏酸的溶液和吸附质溶液中铝离子的存在,可明显提高腐殖酸的去除率;氧化铝对腐殖酸有较快的去除速度,在22.3mgTOC/l的浓度范围内,腐殖酸去除量与其浓度呈线性相关。     

提高铝合金压铸模使用寿命的探讨

对影响铝合金压铸模使用寿命的诸多因素 ,如压铸件结构、形状、模具设计、模具材料及加工工艺、模具的正确使用和管理等方面进行了分析和总结 ,阐述了热处理方法对铝合金压铸模使用寿命的重要性 ,探索出了提高模具质量、延长模具使用寿命的途径。     

LC4铝合金呆扳手成形热力学参数的确定

通过试验研究了LC4铝合金呆扳手成形的温度、变形程度、变形速度、加热方式和加热速度等成形热力学参数与成形质量之间的关系。解决了试验过程中出现的一些问题,确定了最佳成形工艺参数为:始锻温度400～450℃、终锻温度350℃左右,第1阶段的变形量为30%～50%,第2阶段的变形量为75%。