ATR-FTIR investigation of the role of phenolic groups in the interaction of some NOM model compounds with aluminum hydroxide

The role of phenolic groups in the interaction of natural organic matter (NOM) with metal hydroxides was investigated with ATR-FTIR spectroscopy and adsorption tests by employing a series of dihydroxybenzoic acids (DHBAs) as the NOM surrogates and aluminum hydroxide as the adsorbent. All DHBAs examined in this study were found to be adsorbed on aluminum hydroxide by forming inner-sphere complexes. Carboxylic groups governed the complexation of DHBAs with aluminum hydroxide at low pH or in cases when the two hydroxyl groups were not adjacent to each other and neither of them was ortho to the carboxylic group. The involvement of the phenolic groups, ortho to another phenolic group or ortho to the carboxylic groups, in the complexation increased with increasing pH as the deprotonation of phenolic groups was easier at higher pH. The presence of phenolic groups increased the electron density of the carboxylic groups and facilitated the inner-sphere complexation of the carboxylic groups with metal hydroxide. The correlation between the pK_a values and the amount of organic acid adsorbed on the aluminum hydroxide revealed that the adsorption of DHBAs at acidic pH was largely dependent on the surface chelate formation rather than on the electronic effect.     

盐城湿地大米草-芦苇群落对生活污水净化效果的实验研究

大米草、芦苇群落对COD、N、P和NH4-N等污染物有着明显的净化作用,这对潮间带水质稳定起着积极的作用.研究发现在同一淹水深度下,随着群落盖度的增加,芦苇与大米草对有机物、N,P的净化能力也随之增强;而随着淹水深度的增加,大米草对COD的去除率在淹水深度为30 cm时效果最佳;而芦苇群落对COD去除率随淹水深度的增加呈缓慢下降的趋势.光照能够促进湿地植物群落对污染物的净化,但受植物群落垂直结构与淹水深度的影响很大.在群落盖度大于60%、淹水深度为30 cm与当前水质条件下,大米草、芦苇二者联合净化作用在一个潮周期内对有机物、N、P和NH4-N分别可达33.6、24.9、20.8和27.6%以上.     

高等职业技术教育的模式比较

本文分析了我国蓬勃发展的高职教育形势,对国内外主要职业教育的培养模式进行了比较,以期为我国高等职业技术教育的健康发展提供帮助。     

Public opinion and interest group positions on open-space issues in Albuquerque,New Mexico,USA: Implications for resource management

The purpose of this research was to elicit and compare the open-space preferences of citizens and openspace experts in Albuquerque, New Mexico, USA. A randomly selected sample of 492 citizens and 35 open-space experts participated in a telephone survey during May 5–18, 1986. The following hypothesis was tested and used as a guideline for the study:HO1: There is no significant difference between respondents' status and preference for open space in Albuquerque, New Mexico.The hypothesis was rejected. Findings confirmed respondents' status affected preference for open space. Of the eight issues on which the citizen and expert groups were compared, five recorded significant differences in response profiles. The open-space expert group was significantly more supportive of using open space to accommodate offroad vehicle facilities, wildlife preserves, a citywide recreational trail, and a trail system along the arroyos and city ditches. The citizen sample was significantly more supportive of using open space to accommodate overnight camping facilities. Both groups equally supported using open space to accommodate an outdoor amphitheater, outdoor education facilities, and rafting, kayaking, and canoeing facilities.The finding indicated that expert preferences did not represent an aggregate of citizen preferences for managing open-space resources. Understanding both expert and citizen positions will facilitate decision-making processes and help resolve environmental disputes.     

不同污染指示菌对河流的细菌学评价

以细菌学理论为依据，以湖南沅江常德江段水体为实例，说明了用《地表水环境质量标准》（GHZB 1－1999）中粪大肠菌群指标（FC）和《地面水环境质量标准》（GB 3838－88）中总大肠菌群指标（TC）分别评价河流水体的细菌学质量所存在的差异。     

东南沿海陆相多旋回双模式火山岩

以闽东永泰地区为实例,具体阐述东南沿海陆相多旋回双模式火山岩及其区域性分布特点。早白垩世为主要形成期,与世界其它地区以太古代为主体有所不同。区内双模式火山岩为主元结构,Ⅰ旋回(下组合)为沉积岩——玄武岩——流纹质凝灰岩;Ⅱ旋回(上组合)为沉积岩——碱性玄武岩——流纹质凝灰岩;Ⅲ旋回为沉积岩——玄武岩——火山集块岩及钾长流纹岩,其形成的构造环境为活动大陆边缘板内拉张环境,岩浆结晶温度大约在970—1156℃,估算过渡岩浆房形成深度约3.5—5km。     

京津冀区域沙尘暴和群发性强沙尘暴特征分析

利用京津冀区域内102个气象站1954～2002年观测资料,分析了此区域沙尘暴和群发性强沙尘暴的变化特征.结果表明:京津冀区域绝大部分地区是沙尘暴主要影响区,冀北高原是此区域的易发区和多发区.沙尘暴发生时间具有明显的日变化特征和季节差异,沙尘暴呈现整体减少趋势,各分区变化趋势具有相似性,只是在减少幅度上略有不同.近50年此区域共出现了39例群发性强沙尘暴,冀北高原和定州、饶阳一带是此区域群发性强沙尘暴天气的多发区.多发季节为春季(3～5月),占全年总数的76.9%,尤以4月份最多,占全年总数的51.3%.群发性强沙尘暴年代际变化呈现总体减少趋势,其发生次数、覆盖面积均以90年代为最低值.     

21世纪安全工程本科专业课程体系改革与实践

以现代大学的教育理念为指导,以培养高素质人才为目标,充分体现“加强基础、拓宽面向、注重复合、突出特色”的教育教学思想,提出了安全工程本科专业课程体系构建模式。在专业方向模块课程设置方面提出了构建“安全管理课程群”、“安全技术课程群”、“工业卫生课程群”以及“环境保护课程群”。课程群的建设有利于加强不同学科之间的交叉和融合,有利于促进教材建设和师资队伍建设,有利于教学资源的优化配置,提高教学管理水平和教学实践效果。此外,还应加强实验实习基地建设,进一步深化实践环节教学改革,培养适应21世纪社会经济与科技发展的新型高素质人才。     

中国大都市群地区的水灾风险与应急管理研究

在经典风险评价理论模型的基础上,结合自然灾害系统理论,建立了简明水灾综合风险评价模型,完成了中国九大都市群的水灾风险评价.结果表明:我国都市群水灾风险呈现出以都市区中心市为核心的(近)圈层状分布;水灾风险由高到低依次为长三角、珠三角、长江中游、京津唐、吉黑、中原、成渝、辽中南和山东半岛都市群.基于上述研究,强调应建立包含水灾综合风险评价、水灾风险应急预案编制与情景模拟以及水灾风险区划与规划的水灾风险应急管理体系.