总有机碳测定仪用于测定气体样品

用总有机碳测定仪测定了气体样品中总碳、无机碳和总有机碳等，取得了较好的结果，并应用到了实际测定中．     

硫磺回收装置酸性气配风控制方案探讨

主要介绍采用克劳斯制硫工艺的硫磺回收装置制硫转化炉配风调节的几种控制方案以及气体分析仪对稳定操作。提高硫回收率所起的重要作用。     

凯氏定氮仪在固废全氮测定中的应用研究

固体废物中全氮的测定一般采用半微量开式法(CJ/T 103-1999),此方法存在效率低下、操作困难等问题。对半微量开氏法测定城市生活垃圾中全氮方法进行了研究和改进。一是以数控消解炉替代调温电炉进行样品消解,大大缩短了消解时间;二是以自动凯氏定氮仪替代开氏蒸馏器进行自动蒸馏,方便清洗和样品加入,并和数控消解炉配合使用,提高实验效率。经过实际样品的测定,并与国标测定方法进行对比,证明改进后的测定方法准确可行、实验操作方便,实验效率得到提高,效果良好。     

Grubbs检验法在SERES高锰酸盐指数校准中的应用

SERES高锰酸盐指数分析仪的空白参数V0、V2,以及校准系数K等对仪器的测量的准确性非常重要.本文采用格拉布斯检验法(Gnubbs检验法)对几台不同SERES高锰酸盐指数分析仪的空白参数进行检验,以判断仪器的V0、V2,校准系数K是否在正常的范围内波动,是否为异常值,并以此来指导我们以后对仪器的校准工作.     

测量不确定度在水质自动监测仪器中的应用

不确定度是反映某一测量方法,在一定置信概率条件下测量所产生的不确定度量。文章对水质自动监测仪器中氨氮全自动分析仪在测量过程中影响结果的各不确定度分量进行了分析,并计算出仪器示值误差的扩展不确定度。     

Multi N/C2100S总有机碳分析仪校准方法的建立

以德国Analytikjena公司Multi N/C 2100S分析仪为例,研究建立了合理可行的总有机碳分析仪校准方法.在总有机碳分析仪检定规程JJG 821-2005的基础上,增加零点漂移、直线性、标准曲线线性和检出限4项特性指标,改变了准确性特性的判定方法.根据仪器的使用频率和稳定性,建议校准周期不超过2年.     

Quantification, morphology and source of humic acid, kerogen and black carbon in offshore marine sediments from Xiamen Gulf, China

Three types of macromolecular organic matters (MOMs), i.e. humic acid (HA), kerogen+black carbon (KB), and black carbon (BC) were extracted from marine sediments of Xiamen Gulf, southeast of China. The chemical composition, morphological property and source of the three extractions were characterized by elemental analyzer/isotope ratio mass spectrometry (EA/IRMS) and scanning electron microscope (SEM). The results showed that KB was the predominant fraction in MOMs, which accounted for 61.79%-89.15% of the total organic content (TOC), while HA consisted less than 5%. The relative high contents of kerogen and BC, and low contents of HA in the samples indicated that anthropogenic input might be the major source of organic matter in marine sediments near the industrial regions. The characterization of SEM, not only revealed morphological properties of the three fractions, but also allowed a better understanding of the source of MOMs. The δ 13 C values of the three fractions suggested that materials from terrestrial C 3 plants were predominant. Furthermore, the anthropogenic activities, such as the discharge of sewage, coal and biomass combustion from industry nearby and agricultural practices within drainage basin of the Jiulong River, were remarkably contributed to the variations in δ 13 C values of MOMs in the offshore marine sediments.     

Hygroscopicity of ambient submicron particles in urban Hangzhou, China

In this study, hygroscopicity of size-segregated ambient submicron particles in urban Hangzhou was studied from 28th December 2009 to 18th January 2010, using a hygroscopicity-tandem differential mobility analyzer (H-TDMA). The submicron particles in Hangzhou showed a minor hygroscopic growth at 73% relative humidity (RH), and then grew significantly between 77% and 82% RH. Monomodal distribution accounted for 90% for 30 nm particles, 17% for 50 nm particles, and less than 7% for particles larger than 50 nm at 82% RH. Deconvolution of the bimodal distribution indicated a less hygroscopic group and a more hygroscopic group, with the fraction of the more hygroscopic group increasing with the initial dry particle size and then remaining almost constant for accumulation mode particles. Our results imply that submicron particles in urban Hangzhou were almost entirely externally mixed, and the hygroscopic properties of ambient particles in urban Hangzhou were mainly a function of their size and chemical composition.     

流动注射分析仪快速测定水中氰化物方法研究

用流动注射分析仪和723S分光光度计（光度法）测定水中氰化物,进行了一系列的比对实验,结果表明,与GB/T7486-1987异烟酸—吡唑啉酮光度法相比,流动注射分析法测定水中氰化物具有高灵敏度、高精密度、高准确度、分析速度快、不需要人工蒸馏等特点。     

Comparisons of TGA and DSC approaches to evaluate nitrocellulose thermal degradation energy and stabilizer efficiencies

This study investigated the thermal degradation energy (activation energy, E_a) for nitrocellulose (NC) with low nitrogen content of 11.71 mass%, so-called NC3, by using two different kinds of thermal analysis instruments: thermogravimetric analyzer (TGA) and differential scanning calorimetry (DSC). A comparison of E_a for various nitrogen content NC samples at two scanning rates (5 and 10 °C min^?1) tested by TGA and DSC is also discussed in this paper. Meanwhile, our aim was to analyze the anti-degradation of E_a for NC with high nitrogen content, as so-called NC1. Thermal stability for NC1 with diphenylamine (DPA) was tested via DSC with 10 DPA concentrations in weights of 0, 0.25, 0.50, 0.75, 1.0, 1.25, 1.50, 1.75, 2.0, and 3.0 mass%. Experimental results indicated that E_a of NC3s was 319.91 kJ mol^?1. Moreover, that while dosing DPA into NC1 the best recipe could be employed to avoid any violent NC1 runaway and also can be used to distinguish the differences of thermal decomposition E_a between NC with different nitrogen contents. This study established a fast and efficient procedure for thermal decomposition properties of NC, and could be applied as an intrinsically safer design during relevant operations.