Utilization of calcite and waste glass for preparing construction materials with a low environmental load

In this study, porous calcite materials are hydrothermally treated at 200 °C using powder compacts consisting of calcite and glasses composed of silica-rich soda-lime. After treatment, the glasses are converted into calcium aluminosilicate hydrates, such as zeolite phases, which increase their strength. The porosity and morphology of new deposits of hydrothermally solidified materials depend up on the chemical composition of glass. The use of calcite and glass in the hydrothermal treatment plays an important role in the solidification of calcite without thermal decomposition.     

起居室典型材料的火灾温度场实验研究

就建筑火灾发生频率较高的起居室为研究对象,主要对该类住宅中的一些常见和使用广泛的典型家具及装修材料,纸张（报纸）、多层胶合板以及软垫分别进行了火灾燃烧实验,对火场中重要参数温度场进行了测试与分析。对由典型装修材料组成的单室,既起居室火灾进行了全尺寸火灾实验,目的是掌握起居室内火灾的发生发展、燃烧过程和火灾蔓延特点。研究表明,住宅火灾中聚合材料、人工填充泡沫等人造材料的热释放速率最大,最高可达305kW,是火灾前期起居室升温的主要热源;全尺寸火灾实验过程中火焰蔓延较快,扩展幅度较大,蔓延过程中多股火焰交叉处温度可达250％左右,容易造成火势火场传播,同时释放出大量深色烟气,火场能见度极低。全尺寸起居室实验表明,短短3min27s内火场温度达到850℃。     

外军皮肤防护器材化学防护性能测试与评价用标准物质研究进展

本文简迷了皮肤防护器材--化学防护服(衣)化学防护性能试验与评价用标准物质的重要性,系统地概述了外军化学防护服(衣)化学防护性能试验与评价用标准物质的研究现状,并提出了我国化学防护服(衣)防护性能试验与评价用标准物质研制过程中应注意的一些问题.     

施用农药人员的安全与防护——ASTMF2669《旋用农药人员用防护服性能标准》介绍

本文主要介绍了ASTMF2669-2009《施用农药人员用防护服性能标准》的分级和检测要求、防护服材料性能要求、材料的抗渗透性指标等,并就施药人员的安全与防护以及完善防护服标准体系提出建议．以为我国广大相关领域人员了解标准和应用标准提供帮助．     

Advances in the treatment of multi-pollutant flue gas in China's building materials industry

In most of the world's building material industries, the control of flue gas pollutants mainly focuses on a single pollutant. However, given the large capacity and high contribution of China's building materials industry to global air pollution, the need to develop multi-pollutant emission reduction technology is urgent. Recently, China has focused on reducing the emissions of flue gas pollutants in the building materials industry, established many key research and development projects, and gradually implemented more stringent pollutant emission limits. This project focuses on the most recent advances in flue gas emission control technology in China's building materials industry, including denitration, dust removal, desulfurization, synergistic multi-pollutant emission reduction, and the construction of pilot research and demonstration projects for pollutant removal in several building material industries. On this basis, revised pollutant limits in flue gas emitted in China's building material industry are proposed.     

典型舰船用金属材料腐蚀与防护研究进展

针对舰船用金属材料在复杂海洋环境下存在的腐蚀问题,概述了舰船用金属材料腐蚀与防护的相关研究进展。介绍了合金钢、铜合金、钛合金和铝合金这些典型舰船用金属材料的常用类型和使用场所,阐述了舰船用金属材料所处不同海洋区带内的腐蚀环境特征,以及点蚀、缝隙腐蚀、电偶腐蚀、微生物腐蚀和应力腐蚀开裂等舰船用金属材料常发生的腐蚀类型。综述了目前对舰船用金属材料腐蚀防护采取的措施,重点关注了表面涂镀层和改性技术的研究进展。最后,提出了舰船用金属材料腐蚀防护未来的研究方向,需从加强腐蚀机理研究、建立腐蚀数据库和发展新型表面腐蚀防护技术3方面入手。     

过硫酸钠缓释胶囊反应带修复苯胺污染地下水

针对有机污染地下水原位化学氧化修复中普遍存在的氧化剂过量使用、污染物反弹和二次污染问题,以苯胺（AN）为特征污染物,以活化过硫酸盐为氧化剂,采用硬脂酸为胶结剂,制备过硫酸钠（PS）和硫酸亚铁（FeSO₄）缓释胶囊,构建基于PS和FeSO₄缓释胶囊的可渗透反应屏障（PS-FeSO₄-PRB）,考查了缓释胶囊组分、地下水流速对PRB中活性物质释放和AN去除的影响.结果表明,当缓释胶囊中活性物质/硬脂酸为1/2,地下水流速为0.1mL/min时,48h后PRB中PS和Fe²⁺累计释放率分别为43.18%和14.98%.当PRB中FeSO₄/PS为1/9时,AN累计去除率达到95.37%,TOC累计去除率为57.07%.采用砂柱模拟AN污染地下水,比较了直接注射PS和FeSO₄与PS-FeSO₄-PRB两种处理方式的修复性能,4d内两者的AN累计去除率分别为35.22%和69.74%,TOC累计去除率分别为15.83%与14.88%.PS-FeSO₄-PRB修复效果明显高于直接注射处理.GC/MS分析表明,处理后产生了对苯醌、偶氮苯以及长链烷烃等产物,导致AN矿化率不高.pH值和Eh连续记录结果表明,PS-FeSO₄-PRB处理能够保持反应体系氧化还原电位和酸碱性的相对稳定.相比直接注射氧化剂,基于PS和FeSO₄-缓释胶囊的PRB处理中地下水的急性毒性更低,二次污染风险更小.     

有证标准样品的应用及其管理方法探讨

介绍了有证标准样品的定义和主要作用,详细阐述了有证标准样品在检测实验室的7个主要应用领域、正确使用指南和科学管理方法,以保证检测实验室检测结果的准确和量值溯源性。     

High performance of multi-layered alternating Ni–Fe–P and Co–P films for hydrogen evolution

Judiciously engineering the electrocatalysts is attractive and challenging to exploit materials with high electrocatalytic performance for hydrogen evolution reaction. Herein, we successfully perform the interface engineering by alternately depositing Co–P and Ni–Fe–P films on nickel foam, via facile electroless plating and de-alloying process. This work shows that there is a significant effect of de-alloying process on alloy growth. The electronic structure of layered alloys is improved by interface engineering. The multilayer strategy significantly promotes the charge transfer. Importantly, the Co–P/Ni–Fe–P/NF electrode fabricated by interface engineering exhibits excellent electrocatalytic hydrogen evolution activity with an overpotential of 43.4 mV at 10 mA cm-2 and long-term durability for 72 h in alkaline medium (1 mol L-1 KOH). The innovative strategy of this work may aid further development of commercial electrocatalysts.     

一种新型旋风气幕式排风罩数值模拟研究

利用Fluent计算流体力学软件对新型旋风气幕式排风罩工作流场及有害物分布进行了数值模拟,并与传统排风罩进行了对比。结果表明:旋转射流屏蔽作用下的抽吸流场具有中部压力较低和提高抽吸能力的作用;新型旋风气幕式排风罩不仅能有效地控制有害物扩散,而且可以实现远距离捕集有害物及以较小的排风速度排放有害物。