国外热塑性树脂基复合材料低轨原子氧环境效应研究进展

针对具有良好应用前景的热塑性树脂基复合材料,调研并分析了国外飞行试验获得的数据,从原子氧反应率、力学性能退化、微裂纹等多个方面分析研究了原子氧环境对热塑性树脂基复合材料作用效应,为空间站等低轨道航天器结构材料的设计和选择提供依据。     

The effects of arm posture and holding time on holding capability and muscle activity

The aim of this study was to examine the effects of arm posture and holding time on human holding capability and resulting muscle activity. Fifteen healthy young males were recruited as participants. Maximum holding capacity was examined at 0 (degrees of shoulder forward flexion angle)/90 (degrees of elbow angle), 30/120 and 90/180 arm postures. Maximum acceptable weight of holding was evaluated in three arm postures (0/90, 30/120, 90/180) by three holding times (10?s, 20?s, 30?s). The greatest and lowest maximum holding capacity or maximum acceptable weight of holding occurred at 0/90 and 90/180 arm postures, respectively. Maximum acceptable weight of holding decreased with increasing holding time. While holding maximum acceptable weights, the % of maximum voluntary contraction of brachioradialis, biceps brachii and erector spinae ranged from 14 to 44%, from 14 to 53% and from 25 to 36%, respectively.     

Global anthropogenic tellurium cycles for 1940–2010

Tellurium is increasingly used in solar photovoltaics in the form of cadmium–telluride (CdTe) thin films. There are concerns regarding whether tellurium availability could be a constraint on large-scale deployment of CdTe photovoltaics. The present work brings a new perspective to the discussion of tellurium availability by providing the first extant global tellurium cycles constructed with material flow analysis principles. The tellurium cycles, for 1940–2010, present information on the production, fabrication and manufacturing, use, and resource management stages during this period. The results of the analysis show that during 1940–2010 approximately 11 Gg of refined tellurium was produced. This represents about 4.5% of the tellurium that was extracted from the ground during copper mining. Almost 80% of the refined tellurium, 8.5 Gg, was dissipated into end-uses such as metallurgical additives to iron, steel, and nonferrous metals, and thereby lost to potential reuse. As of 2010, the in-use tellurium stock is estimated at 1.1 Gg, which mainly accumulated after 1990s with the increasing tellurium use in electronics, specifically photovoltaic and thermoelectric devices. Because tellurium is a byproduct of copper ores, its supply can be enhanced by more attention to recovery during processing of the copper parent. Tellurium can also, in principle, be recovered from end-of-life electronics; the increasing in-use stock indicates the potential for significant end-of-life recycling in the coming decades.     

A hybrid approach using AHP–TOPSIS–entropy methods for sustainable ranking of structural materials

Nowadays, many countries are looking towards sustainability as a goal because our world has limited resources and serious environmental impacts. In the construction industry, the process of sustainable selection of structural material is considered one of the keys to achieve more sustainable construction. In this paper, the theories of decision making are utilised to develop an approach for evaluation and ranking the structural materials over their total life based on sustainability criteria using multi-attribute decision-making methods. One of them is Analytical Hierarchy Process which is utilised to build the problem hierarchical structure and assign weights of the predetermined sustainable factors. The other is Technique for Order Preference by Similarity to the Ideal Solution which is utilised to rank the structural materials within both each material life cycle phase and the complete material life cycle phases. The third is the concept of entropy by Shannon to evaluate the weight factor for each phase of material life cycle. The proposed approach presents an objective, systematic and comprehensive method for the sustainable ranking of materials that links between the structural element design and the sustainable selection of materials.     

南京市化学原料及化学制品制造业能源消耗预测

化学原料及化学制品制造业作为南京市高能耗、高污染产业,对其能源消耗总量及能源消耗结构进行预测,对节能减排具有重要意义。以2002—2012年能源消耗量弱化之后的数据为原始数据,运用灰色GM(1,1)模型对2013—2020年南京市化学原料及化学制品制造业能源消耗总量以及主要能耗进行了预测。由于部分原始数据序列光滑性较差,所建预测模型的精度较低,使用平均弱化缓冲算子对其进行处理。结果表明,处理之后建模精度提高,预测的结果更加准确。     

Interfacial mechanisms of heterogeneous Fenton reactions catalyzed by iron-based materials: A review

The heterogeneous Fenton reaction can generate highly reactive hydroxyl radicals(·OH)from reactions between recyclable solid catalysts and H_2O_2 at acidic or even circumneutral pH.Hence,it can effectively oxidize refractory organics in water or soils and has become a promising environmentally friendly treatment technology.Due to the complex reaction system,the mechanism behind heterogeneous Fenton reactions remains unresolved but fascinating,and is crucial for understanding Fenton chemistry and the development and application of efficient heterogeneous Fenton technologies.Iron-based materials usually possess high catalytic activity,low cost,negligible toxicity and easy recovery,and are a superior type of heterogeneous Fenton catalysts.Therefore,this article reviews the fundamental but important interfacial mechanisms of heterogeneous Fenton reactions catalyzed by iron-based materials..OH,hydroperoxyl radicals/superoxide anions(HO_2./O_2~-.)and high-valent iron are the three main types of reactive oxygen species(ROS),with different oxidation reactivity and selectivity.Based on the mechanisms of ROS generation,the interfacial mechanisms of heterogeneous Fenton systems can be classified as the homogeneous Fenton mechanism induced by surface-leached iron,the heterogeneous catalysis mechanism,and the heterogeneous reaction-induced homogeneous mechanism.Different heterogeneous Fenton systems catalyzed by characteristic iron-based materials are comprehensively reviewed.Finally,related future research directions are also suggested.     

基于生命周期评价的钢结构与混凝土结构建筑环境性能比较

评价一个建筑的环境性能的好坏,必须充分考虑它的生命周期中的每一个阶段。建立了建筑物的生命周期清单分析模型,并对某钢结构建筑和某混凝土建筑的生命周期清单分析结果进行了比较,结果表明,单从结构的生命周期清单分析结果,钢结构建筑相对于混凝土结构建筑有着较大的优越性,单位面积的建材生命周期环境排放仅为混凝土结构建筑的1/2左右,但是结构在建筑的整个生命周期里面只不到10%的比例,比例最大的是建筑使用阶段,影响建筑使用阶段空调能耗的主要因素是外围护结构的材料和形式,因此优化外围护结构的热工性能是当前我国建筑节能最主要的问题。     

基于建筑材料物化环境影响的建筑结构形式选择

不同结构形式的建筑在环境影响方面存在差异。对砖混结构和框架结构的两种不同形式的建筑物,因使用建筑材料而造成的环境影响差异,依据建筑材料生命周期环境影响评价模型进行了定量分析。结果表明:从建筑物使用的建筑材料造成的环境影响角度分析,多层砖混结构单位建筑面积的资源耗竭系数为0.045、环境影响负荷为5.87;多层框架结构则分别为0.071、10.49。     

Radon remediation of a two-storey UK dwelling by active sub-slab depressurisation: effects and health implications of radon concentration distributions

Radon concentration levels in a two-storey detached single-family dwelling in Northamptonshire, UK, were monitored continuously throughout a 5-week period during which active sub-slab depressurisation remediation measures were installed. Remediation of the property was accomplished successfully, with both the mean radon levels and the diurnal variability greatly reduced both upstairs and downstairs. Following remediation, upstairs and downstairs radon concentrations were 33% and 18% of their pre-remediation values respectively: the mean downstairs radon concentration was lower than that upstairs, with pre- and post-remediation values of the upstairs/downstairs concentration ratio, R(U/D), of 0.81 and 1.51 respectively. Cross-correlation between upstairs and downstairs radon concentration time-series indicates a time-lag of the order of 1 h or less, suggesting that diffusion of soil-derived radon from downstairs to upstairs either occurs within that time frame or forms a relatively insignificant contribution to the upstairs radon level. Cross-correlation between radon concentration time-series and the corresponding time-series for local atmospheric parameters demonstrated correlation between radon concentrations and internal/external pressure difference prior to remediation; this correlation disappears following remediation. Overall, these observations provide further evidence that radon concentration levels within a dwelling are not necessarily wholly determined by the effects of soil-gas advection, and further support the suggestion that, depending on the precise content of the building materials, upstairs radon levels, in particular, may be dominated by radon exhalation from the walls of the dwelling, especially in areas of low soil-gas radon.     

Small-scale fire performance assessment of intumescent coatings on metal tubes containing ammonium nitrate. A stepping-stone towards their application as a fire safety measure on road transportation tanks?

Ammonium nitrate is used in vast amounts globally, first and foremost as a component of fertilizers and explosive formulations. This usage necessitates its transportation which, as for most hazardous materials, involves certain risks. For oxidizing materials such as ammonium nitrate, the ultimate consequence of road transportation incidents is usually considered to be fire followed by explosion. Even though the probability in general is low, substantial reduction in its risk is a great gain for public safety. Thus, identifying novel and improving current safety measures for risk reduction, is an important aspect in the field of hazardous materials. Herein, a series of experiments are reported, which demonstrate the fire protection performance of two state-of-the-art intumescent passive fire protection materials on small-scale metal test tubes containing ammonium nitrate. Albeit being initial experiments on laboratory-scale, these results provide a promising starting point for further investigations on the potential of these materials for the fire protection of ammonium nitrate when carried in metal tanks. At its best, a prominent protection of ammonium nitrate from heat exposure was observed, as the temperature was kept well below its boiling point for more than 2.5 h. Successively, it resulted in a complete recovery of the sample material. This was in large contrast to the observed results for the unprotected test tubes, which led to complete decomposition of the sample after 11 min.