Atmospheric fate of non-volatile and ionizable compounds

A modified version of the Multimedia Activity Model for Ionics MAMI, including two-layered atmosphere, air-water interface partitioning, intermittent rainfall and variable cloud coverage was developed to simulate the atmospheric fate of ten low volatility or ionizable organic chemicals. Probabilistic simulations describing the uncertainty of substance and environmental input properties were run to evaluate the impact of atmospheric parameters, ionization and air-water (or air-ice) interface enrichment.The rate of degradation and the concentration of OH radicals, the duration of dry and wet periods, and the parameters describing air-water partitioning (K_AW and temperature) and ionization (pK_a and pH) are the key parameters determining the potential for long range transport. Wet deposition is an important removal process, but its efficiency is limited, primarily by the duration of the dry period between precipitation events.Given the underlying model assumptions, the presence of clouds contributes to the higher persistence in the troposphere because of the capacity of cloud water to accumulate and transport non-volatile (e.g. 2,4-D) and surface-active chemicals (e.g. PFOA). This limits the efficiency of wet deposition from the troposphere enhancing long-range transport.     

Inside-sediment partitioning of PAH, PCB and organochlorine compounds and inferences on sampling and normalization methods

Comparability of sediment analyses for semivolatile organic substances is still low. Neither screening of the sediments nor organic-carbon based normalization is sufficient to obtain comparable results. We are showing the interdependency of grain-size effects with inside-sediment organic-matter distribution for PAH, PCB and organochlorine compounds. Surface sediment samples collected by Van-Veen grab were sieved and analyzed for 16 PAH, 6 PCB and 18 organochlorine pesticides (OCP) as well as organic-matter content. Since bulk concentrations are influenced by grain-size effects themselves, we used a novel normalization method based on the sum of concentrations in the separate grain-size fractions of the sediments. By calculating relative normalized concentrations, it was possible to clearly show underlying mechanisms throughout a heterogeneous set of samples. Furthermore, we were able to show that, for comparability, screening at <125 μm is best suited and can be further improved by additional organic-carbon normalization.     

The impact of nitrogen deposition on acid grasslands in the Atlantic region of Europe

A survey of 153 acid grasslands from the Atlantic biogeographic region of Europe indicates that chronic nitrogen deposition is changing plant species composition and soil and plant-tissue chemistry. Across the deposition gradient (2-44 kg N ha⁻¹ yr⁻¹) grass richness as a proportion of total species richness increased whereas forb richness decreased. Soil C:N ratio increased, but soil extractable nitrate and ammonium concentrations did not show any relationship with nitrogen deposition. The above-ground tissue nitrogen contents of three plant species were examined: Agrostis capillaris (grass), Galium saxatile (forb) and Rhytidiadelphus squarrosus (bryophyte). The tissue nitrogen content of neither vascular plant species showed any relationship with nitrogen deposition, but there was a weak positive relationship between R. squarrosus nitrogen content and nitrogen deposition. None of the species showed strong relationships between above-ground tissue N:P or C:N and nitrogen deposition, indicating that they are not good indicators of deposition rate.     

贵阳市一居民区大气颗粒态汞的污染状况

2004年4、7、8、11、12月采用微型捕集管-冷原子荧光光谱法对贵阳市一个居民区大气中的痕量颗粒态总汞(TPM)进行了测定。结果表明:TPM日均浓度范围是0.149~4.853 ng.m-3,平均值是1.091 ng.m-3,显著高于背景参考值1~86 pg.m-3;TPM浓度采暖期大于非采暖期,夜间通常大于白昼;TPM与大气气态总汞(TGM)可能具有同源性;燃煤、垃圾焚烧以及周边工厂排放的含尘烟气可能是居民区大气颗粒态汞的主要人为来源。     

西昌市大气污染现状调查及保护对策

本文对西昌市大气污染现状进行调查分析，揭示了大气环境污染的特征及其变化规律，从宏观上提出了保护大气环境的对策。     

DISTRIBUTION AND GRAIN-SIZE PARTITIONING OF METALS IN BOVFOM SEDIMENTS OF AN EXPERIMENTALLY ACIDIFIED WISCONSIN LAKE1

ABSTRACT: A study of concentrations and distribution of major and trace elements in surficial bottom sediments of Little Rock Lake in northern Wisconsin included examination of spatial variation and grain-size effects. No significant differences with respect to metal distribution in sediments were observed between the two basins of the lake, despite the experimental acidification of one of the basins from pH 6.1 to 4.6. The concentrations of most elements in the lake sediments were generally similar to soil concentrations in the area and were well below sediment quality criteria. Two exceptions were lead and zinc, whose concentrations in July 1990 exceeded the criteria of 50 μg/g and 100 μg/g, respectively, in both littoral and pelagic sediments. Concentrations of some elements, particularly Cu, Pb, and Zn, increased along transects from nearshore to midlake, following a similar gradient of sedimentary organic carbon. In contrast, Mn, Fe, and alkali/alkaline-earth elements were at maximum concentrations in nearshore sediments. These elements are less likely to partition to organic particles, and their distribution is more dependent on mineralogical composition, grain size, and other factors. Element concentrations varied among different sediment grain-size fractions, although a simple inverse relation to grain size was not observed. Fe, Mn, Pb, and Zn were more concentrated in a grain-size range 20–60 tm than in either the very fine or the coarse fractions, possibly because of the aggregation of smaller particles cemented together by organic and Fe/Mn hydrous-oxide coatings.     

玉.玉文化.旅游

开发旅游新产品，是促进我国旅游业不断迈上新台阶需要研究解决的问题之一。本文通过作者实施踏勘和检索有关文献，阐述了玉的种类及其主要产地的状况，并揭示它新蕴涵的文化内容。     

印染废水静电场处理机理分析

本文提出一种利用静电场的印染废水处理方法，印染废水中的污染颗粒在电场的作用下，朝一定的方向迁移，从而发生“强制电中和”作用，这种电中和作用的场能消耗极小，而被中和的污染物颗粒由于凝聚作用，则会不断长大而易于通令过滤去除，这一处理工艺在经“自数”预处理之后，可继续使COD和色度的去除百分数分别达60％和63％以上。     

PHOSPHORUS MANAGEMENT TO PROTECT LAKE WATER QUALITY1

ABSTRACT: The Hallett Quarry gravel pit lakes are an active sand and gravel extraction operation located 0.4 km north of the City of Ames, Iowa. During periods of drought, these lakes serve as a supplemental water supply for Ames. A modified version of the Vollenweider input-output model was used to predict future water quality under various watershed land use, drainage, and lake configurations. The dominant factor controlling the future water quality of the lakes was found to be the nutrient input. It is recommended that a management plan to protect the future water quality should be oriented towards reducing the sources of phosphorus to the lakes.     

THE EFFECTS OF A MOVING RAINSTORM ON DIRECT RUNOFF PROPERTIES1

ABSTRACT: The effects of a moving rainstorm on flood runoff characteristics were investigated. A flood hydrograph simulation model called “FH-Model” and a natural watershed were used. A hypothetical rainstorm of 50 years recurrence interval, 75 mm depth, and 4 hours duration was used to show the effects of velocity and direction of the moving rainstorm on the runoff characteristics. Compared with an equivalent stationary rainstorm (ESRS), the peak flow caused by a rainstorm moving in a downstream direction with a speed equal to channel velocity, V, was 27.5 percent higher and the peak flow caused by the same rainstorm moving in an upstream direction was 21.7 percent smaller. These percentages reduced to 10.5 percent and 8.6 percent for storms moving downstream and upstream, respectively, at three times the channel velocity, 3V. There were negligible differences in the time of peak, T_p between runoff caused by storms moving downstream and runoff produced by ESRS. However, T_p for a storm moving upstream at V velocity was 82 percent higher than that produced by ESRS, but was reduced to 27 percent higher when the storm velocity was 3V.