应用电性拓扑状态指数预测烷烃自燃点

建立了一个基于人工神经网络的定量结构-性质相关性模型,用于52种烷烃化合物自燃点的预测研究。应用原子类型电性拓扑状态指数作为表征分子结构特征的描述符。该指数既能表征分子的电子特性,又反映其拓扑特征,同时易于计算,并有较强的同分异构体区分能力。采用误差反向传播（BP）神经网络方法对烷烃自燃点与电性拓扑状态指数间可能存在的非线性关系进行拟合。将52种烷烃样本随机划分为训练集（30种）、验证集（8种）和测试集（14种）,并通过“试差法”确定网络的最优参数。运用最佳网络结构[64—1]对实验样本进行模拟,结果表明,多数样本的自燃点预测值与实验值符合良好,对于测试集,平均预测绝对误差为8．4℃,均方根误差为11．8,优于多元线性回归方法和传统基团贡献法所得结果。该方法的提出为工程上提供了一种根据分子结构预测有机物白燃点的有效方法。     

粒子阻隔效率测试仪串行通信数据处理系统

在GB2626—2006《呼吸防护用品——自吸过滤式防颗粒物呼吸器》中防尘面罩粒子阻隔效率测定是一项评价防尘面罩性能的关键指标。为实现数据通信及处理的自动化操作,提高检测效率,本研究针对装置的串行数据通信的底层接口,开发基于EXCELVB脚本的串行通信数据处理系统。该系统为更好地研究实粒子阻隔效率测定方法和阻隔效率相关规律提供了便利条件。     

消防水幕衰减火灾热辐射的实验研究

通过全尺寸消防水幕衰减火灾热辐射实验,分析了火灾空间烟气温度的分布,探讨了喷头流量和压力、设置高度、喷头类型和布置方式对水幕衰减辐射热能力的影响,获得了不同工况下消防水幕的隔热效率.在此基础上,结合消防水幕的工程设计参数,揭示了消防水幕在不同的设置条件下隔热效率的变化规律.研究结果对于优化消防水幕设计提高隔热效率具有理论和实践上的指导意义.     

我国开发区土地资源配置效率的区域差异研究

应用比较优势理论，以国家级53个经济技术开发区为例。研究了不同区域间开发区土地利用的比较优势。结果表明。按照区域土地利用的比较优势来配置土地资源能够提高土地利用的总福利水平。整体上．中西部国家级开发区的比较优势高于东部地区：而区域内部东部地区的京津苏沪及中西部地区的中心城市在开发区建设用地的利用上具有比较优势。因此，按照开发区土地利用的比较优势度计算结果，在排除开发区自身发育不完善和管理层面因素后，对于确实不适宜进行开发区工业建设的应进行空间布局的调整，恢复其农业生产；而对于比较优势度较高的地区可根据实际需要增设相应的开发区。以实现耕地保护与开发区建设的双赢。     

快速城市化地区土地利用效益评价--以南京市江宁区为例

作为衡量土地利用可持续性的重要标度,土地利用效益评价是近年来国内外城市土地研究的热点之一。从社会、经济、生态与环境等四方面建立了快速城市化地区土地利用效益评价的指标体系,利用层次分析法确定各指标权重,构建各效益子系统的协调度评价模型。并对南京市江宁区2003年的土地利用效益进行了综合评价,结果表明,全区总体土地利用效益适中且基本协调,但各乡镇间土地利用效益及其协调性的区域差异显著。依据各乡镇土地利用总效益及其协调度的聚类分级,可将全区划分为土地利用高效协调区、高效基本协调区、高效不协调区、中效协调区、中效基本协调区、中效不协调区与低效基本协调区等七大土地利用效益类型区,并分析了其区域差异的空间特征。     

Analysis of bacterial community structures in two sewage treatment plants with different sludge properties and treatment performance by nested PCR-DGGE method

The bacterial community structures in two sewage treatment plants with different processes and performance were investigated by denaturing gradient gel electrophoresis （DGGE） of nested polymerase chain reaction （nested PCR） amplified 16S rRNA gene fragments with group-specific primers. Samples of raw sewage and treated effluents were amplified using the whole-cell PCR method, and the activated sludge samples were amplified using the extracted genomic DNA before the PCR products were loaded on the same DGGE gel for bacterial community analysis. Ammonia-oxidizing bacterial and actinomycetic community analysis were also carried out to investigate the relationship between specific population structures and system or sludge performance. The two plants demonstrated a similarity in bacterial community structures of raw sewage and activated sludge, but they had different effluent populations. Many dominant bacterial populations of raw sewage did not appear in the activated sludge samples, suggesting that the dominant bacterial populations in raw sewage might not play an important role during wastewater treatment. Although the two plants had different sludge properties in terms of settleability and foam forming ability, they demonstrated similar actinomycetic community structures. For activated sludge with bad settling performance, the treated water presented a similar DGGE pattern with that of activated sludge, indicating the nonselective washout of bacteria from the system. The plant with better ammonium removal efficiency showed higher ammonia-oxidizing bacteria species richness. Analysis of sequencing results showed that the major populations in raw sewage were uncultured bacterium, while in activated sludge the predominant populations were beta proteobacteria.     

Performances of biological aerated filter employing hollow fiber membrane segments of surface-improved poly （sulfone） as biofilm carriers

Using the surface of poly （sulfone） hollow fiber membrane segments as grafted layer, the hydrophilic acrylamide chain was grafted on by UV-photoinduced grafting polymerization. The gained improvement of surface wettability for the modified membrane was tested by measuring the contact-angle as well as FTIR spectra. Then correlation between the hydrophilic ability of support material and the biofilm adherence ability was demonstrated by comparing the pollutant removal rates from urban wastewater via two identical lab-scale up-flow biological aerated filters, one employed the surface wettability modified poly （sulfone） hollow fiber membrane segment as biofilm carder and the other employed unmodified membrane segment as biofilm carder. The experimental results showed that under the conditions of influent flux 5 L/h, hydraulic retention time 9 h and gas to liquid ratio （G/L） 10： 1, the removal rates of chemical oxygen demand （COD） and ammonium nitrogen （NH4^＋-N） for the modified packing filter and the unmodified packing filter was averaged at 83.64% and 96.25%, respectively, with the former filter being 5%-20% more than the latter. The effluent concentration of COD, NH4^＋-N and turbidity for the modified packing filter was 25.25 mg/L, 2 mg/L and 8 NTU, respectively. Moreover, the ammonium nitrogen removal performance of the filter packing the modified PSF was compared with the other bioreactor packing of an efficient floating medium. The biomass test indicated that the modified membrane matrixes provided better specific adhesion （3310-5653 mg TSS/L support）, which gave a mean of 1000 mg TSS/L more than the unmodified membrane did. In addition, the phenomenon of simultaneous denitrification on the inner surface of the support and nitrification on the outer surface was found in this work.     

Effect of copper on the degradation of pesticides cypermethrin and cyhalothrin

The influence of coexisting copper (Cu) ion on the degradation of pesticides pyrethroid cypermethrin and cyhalothrin in soil and photodegradation in water system were studied.Serial concentrations of the pesticides with the addition of copper ion were spiked in the soil and incubated for a regular period of time,the analysis of the extracts from the soil was carried out using gas chromatography (GC).The photodegradation of pyrethroids in water system was conducted under UV irradiation.The effect of Cu~(2 ) on the pesticides degradation was measured with half life (t_(0.5)) of degradation.It was found that a negative correlation between the degradation of the pyrethroid pesticides in soil and Cu addition was observed.But Cu~(2 ) could accelerate photodegradation of the pyrethroids in water.The t_(0.5) for cyhalothrin extended from 6.7 to 6.8 d while for cypermethrin extended from 8.1 to 10.9 d with the presence of copper ion in soil.As for photodegradation,t_(0.5) for cyhalothrin reduced from 173.3 to 115.5 rain and for cypermethrin from 115.5 to 99.0 min.The results suggested that copper influenced the degradation of the pesticides in soil by affecting the activity of microorganisms.However, it had catalyst tendency for photodegradation in water system.The difference for the degradation efficiency of pyrethroid isomers in soil was also observed.Copper could obviously accelerate the degradation of some special isomers.     

Effect of Sb dopant amount on the structure and electrocatalytic capability of Ti/Sb-SnO2 electrodes in the oxidation of 4-chlorophenol

Ti/Sb-SnO_2 anodes were prepared by thermal decomposition to examine the influence',of the amount of Sb dopant on the structure and electrocatalytic capability of the electrodes in the oxidation of 4-chlorophenol.The physicochemical properties of the Sb-SnO_2 coating were markedly influenced by different amounts of Sb dopant.The electrodes,which contained 5% Sb dopant in the coating, presented a much more homogenous surface and much smaller mud-cracks,compared with Ti/Sb-SnO_2 electrodes containing 10% or 15% Sb dopant,which exibited larger mud cracks and pores on the surface.However,the main microstructure remained unchanged with the addition of the Sb dopant.No new crystal phase was observed by X-ray diffraction(XRD).The electrochemical oxidation of 4-chlorophenol on the Ti/SnO_2 electrode with 5% Sb dopant was inclined to electrochemical combustion;while for those containing more Sb dopant,intermediate species were accumulated.The electrodes with 5% Sb dopant showed the highest efficiency in the bulk electrolysis of 4-chlorophenol at a current density of 20 mA/cm~2 for 180 min;and the removal rates of 4-chlorophenol and COD were 51.0% and 48.9%,respectively.     

具有超压/负压防护功能的急救车防生物污染的安全性试验研究

采用粘质沙雷菌气溶胶,对具有超压/负压防护功能的急救车防生物污染的安全性进行试验考核。分别测试气溶胶发生后30s,1min,5min,10min时,车厢在超压防护和负压防护下的过滤效率,其结果表明:急救车在超压防护状态下开启空调时的平均过滤效率能达到99.99%,不开空调时的平均过滤效率能达到99.95%;在负压防护状态下开启空调时的平均过滤效率能达到99.93%,不开空调时的平均过滤效率能达到99.95%。证明急救车能够通过生物污染区域安全运送、急救伤病员,也能够运送、急救生物污染伤病员或烈性传染病员确保沿途环境不受污染,该研究成果为应对生物恐怖袭击和突发公共卫生事件(烈性传染病)提供了一种安全可靠的机动医疗救治平台。