新型湿法离心式油烟净化器及技术经济分析

采用湿法和离心法等净化原理,研制了一种复合式油烟净化装置;该装置结构简单,制作成本每1000m3烹调油烟废气在800～1500元左右,运行维护简单,不需要人工清洗,试验结果显示,油烟净化效率在80%以上,最高可达到92%,与相同效率的油烟净化设备相比,初投资和运行费用都较低。     

钠钙双碱法烟气脱硫主要影响因素的实验研究

采用纤维栅洗涤器在实验室对钠钙双碱法烟气脱硫效率的主要影响因素 :洗涤器的风速、烟气SO2 初始浓度、吸收液 p H值及 [Na+ ]浓度、液气比等进行了模拟实验 ,得出了它们与烟气脱硫效率的关系。     

钢棒去皮机除尘器设计

钢棒去皮机是通过砂轮磨削除去钢棒表面铁锈的一种设备,在去皮过程产生的大量金属粉尘,导致环境污染,为此设计喷淋塔式除尘器作为钢棒去皮机的除尘装置。通过选择和计算的运行参数,设计了喷淋塔的结构和尺寸。对设计的除尘器效率验算结果表明:该除尘器可以满足去皮机环保要求,除尘效率达99.7%。     

焦化厂粗苯排渣废气污染的处理

针对洗油器排渣废气污染问题,介绍了水洗器选择依据及原理,设计要点及在本厂应用的效果.     

尿素生产中Hydro流化床造粒工艺及其粉尘处理

介绍了海南富岛化工有限公司Ｈｙｄｒｏ流化床造粒工艺及其粉尘处理技术,将该工艺与传统塔式造粒工艺作了比较,并对运行中的一些问题提出了解决办法。     

Method of removal of volatile organic compounds by using wet scrubber coupled with photo-Fenton reaction - Preventing emission of by-products

The photo-Fenton reaction was applied as a novel method for the removal of volatile organic compounds (VOCs) in the gas phase, and its effectiveness was experimentally examined. In conventional VOCs removal methods using a photocatalyst or ozone, VOCs are oxidized in the gas phase. Therefore, incompletely oxidized intermediates, which may have adverse effects on health, are likely to contaminate the treated air. On the other hand, in the VOCs removal method developed in this study, because the VOCs are oxidized in the liquid phase by the photo-Fenton reaction, any incompletely oxidized intermediates produced are confined to the liquid phase. As a result, the contamination of the treated air by these harmful intermediates can be prevented. Using a semi-batch process, it was found that the removal efficiency for toluene in a one-pass test (residence time of 17 s) was 61%, for an inlet toluene gas concentration of 930 ppbv, an initial iron ion concentration of 20 mg L⁻¹, and an initial hydrogen peroxide concentration of 630 mg L⁻¹. The removal efficiency was almost constant as long as H₂O₂ was present in the solution. Proton transfer reaction mass spectrometry analysis confirmed the absence of any incompletely oxidized intermediates in the treated air.     

Assessment and optimisation of VOC mass transfer enhancement by advanced oxidation process in a compact wet scrubber

Dimethyl disulphide (DMDS) removal was investigated in a compact scrubber (hydraulic residence time ≈20 ms), composed of a wire mesh packing structure where liquid and gas flow at co-current and high gas superficial velocity (>12 m s⁻¹). In order to regenerate the scrubbing liquid and to maintain a driving force in the scrubber, ozone and hydrogen peroxide were added to water since they allow the generation of nonselective and highly reactive species, hydroxyl radicals HO. Three ways of reagent distribution were tested. The influence of several parameters (liquid flow rate(s), ozone flow rate, pH and reagent concentrations) was investigated. The best configuration was obtained when ozone is transferred in the scrubbing liquid before introduction at the top of the scrubber simultaneously with the hydrogen peroxide solution, allowing to generate hydroxyl radical in the scrubber. With this configuration, DMDS removal could be increased from 16% with water to 34% at the same gas and liquid flow rates in the scrubber showing the potentiality of advanced oxidation process.     

pH对过一硫酸氢盐湿法氧化去除甲硫醇恶臭气体的影响

以过一硫酸氢盐(PMS)作为氧化剂,利用化学吸收氧化法去除甲硫醇(CH3SH)恶臭气体.研究了p H(2~13)对CH3SH吸收过程、PMS氧化降解CH3SH过程的影响.结果表明,PMS不同于H2O2,在p H小于CH3SH p Ka(10.3)的弱碱性条件(p H=8~10)下,也可以有效去除CH3SH,而此时H2O2对CH3SH没有去除效果.可能的原因是,在弱碱性条件(p H=8~10)下PMS或可能产生的活性物种在气液相界面直接快速氧化CH3SH分子.     

过二硫酸盐降解碱液吸收的甲硫醇恶臭

甲硫醇(CH3SH)是一种高毒、高腐蚀性的酸性气体,是恶臭的重要组成部分.碱液吸收是最常用的CH3SH处理方法之一,但吸收液需要进一步处理.过二硫酸盐(persulfate,PS)作为氧化剂用于降解碱液吸收的CH3SH尚鲜见报道.为此,建立一连续循环的吸收降解体系,进行CH3SH的碱液吸收及PS降解实验,并探讨了PS在碱性条件下的稳定性,及反应条件对CH3SH吸收和降解动力学的影响.结果表明,PS在碱液中的稳定性较好,能够有效地降解碱液吸收的CH3S-;随着PS浓度的增加,CH3SH的吸收速率呈先增加后减小的趋势,CH3S-的降解速率不断增大;随着pH的增加,CH3SH的吸收和降解效果均明显增加.在pH为12,CH3SH进气浓度80 mg·m-3,进气速率1.5 L·min-1,PS浓度为1.4 g·L-1时,碱液吸收的CH3S-90%被降解.     

文丘里喷射器用于饮食业油烟雾处理的实验研究

将文丘里喷射器用于饮食业油烟雾的湿法处理，实验对喷射器的结构进行了系统的研究，找出了喷射器的最佳结构参数，并进行了该装置的净化性能应用试验。结果表明：该湿法洗涤装置净化效率高，运行稳定，具有较高的应用推广价值。