化学发光流动注射法测定雨水中过氧化氢

用化学发光流动注射分析装置,将16孔阀连接成异步双流路,以过氧化氢-鲁米诺-钴(Ⅱ)为化学发光体系,建立了快速测定雨水中过氧化氢的方法,最低检测限为0.1ng/ml,在0.1—400ppb范围内有良好的线性关系,相对标准差为0.78—3.03％,每小时可分析480个以上的样品.     

灌溉水库群优化调度的AD模型

随着国民经济的不断发展,工农业用水日益增长,但可供利用的水资源有限,使得供水与需水矛盾加剧。因此,对流域内或流域间的水库进行联合调度和管理,将有限的水资源统筹安排、挖掘潜力、充分发挥现有工程的效益、提高供水的保证程度即对水库实施优化调度很有现实意义。本文应用系统分析方法,建立了灌溉水库群优化调度的聚合分解(AD)模型,以保证在系统整体效益最优条件下得出各库的最佳运行策略,从而使水库的运行管理建立在科学的基础之上。     

Spontaneous abortion after transcervical chorionic villus sampling: A case report

A case of spontaneous abortion after transcervical CVS is presented. Despite no evidence of bacteria in the vagina and cervix prior to sampling and the prophylactic use of Metronidazole, pathological evidence of chorioamnionitis was found. The implications of this are discussed.     

Stability analysis of alkaline nitrobenzene-containing wastewater by a catalyzed Fe-Cu treatment process

Iron and copper bimetallic system (catalyzed Fe-Cu process) is a promising technology for alkaline nitrobenzene-containing wastewater treatment. However, little is currently known about the changes of treatment efficiency with time going. This research investigated the long-term performance of the catalyzed Fe-Cu process to reduce nitrobenzene (NB) in alkaline wastewater. In addition, the changes of the metal surfaces morphologies and matters before and after the reaction were analyzed by scanning electron microscopy (SEM) in conjunction with energy-dispersion spectroscopy (EDS) and X-ray diffraction spectroscopy (XRD). The results showed that the surface properties of copper almost remained unchanged after weeks of operation, which spelled its strong chemical stability and resistance to poisoning. Moreover, the results indicated that there were two reasons for the treatment efficiency decreasing with time. One was the gradual iron element consumption due to corrosion. The other was iron reactivity weakened due to the precipitates accumulation on the surfaces that were mainly Fe₃O₄ and FeCO. __________ Translated from Environmental Pollution & Control, 2006, 28(10): 783–785 [译自: 环境污染与防治]     

Influence of no-tillage on the distribution and lability of phosphorus in Finnish clay soils

No-tillage (NT) is a method adopted to reduce erosion and particulate phosphorus (P) load from arable land to watercourses. However, it has been found to increase the loss of dissolved P with surface runoff, but the reasons for that have rarely been examined in detail. The objective of the present study was to determine the chemical factors explaining this response by investigating the impact of NT on the type and distribution of P reserves as well as on organic carbon (C) in the 0–35 cm topsoil layer of clay soil profiles (Vertic Cambisols). Soil samples were taken from two experimental fields (Jokioinen and Aurajoki) at 0–5, 5–20 and 20–35 cm depths in conventionally tilled (CT) and non-tilled (for 4–5 years) plots. The plots had been cultivated and fertilized according to the common field practices in Finland (15–18 kg P and 100–128 kg N ha⁻¹ year⁻¹).Inorganic and organic P reserves characterized by a modified Chang and Jackson fractionation procedure were not significantly affected by the cultivation methods. However, in the uppermost soil layer (0–5 cm) in NT of the Jokioinen field, the labile P determined by water extraction (P_w) increased significantly, whereas the increase in P extracted with acid ammonium acetate (P_AAC) remained statistically insignificant. The increase in labile P coincided with a significant increase in organic carbon (C), which supports the theory that competition between organic anions and phosphate for the same sorption sites on oxide surfaces will enhance the lability of soil P. In the Aurajoki field with distinct soil cracking, P_w and P_AAC were not affected by NT in the uppermost soil layer, but they increased in the deepest soil layer (20–35 cm) concomitantly with an increase in Al-bound P and organic C. However, the increases were not statistically significant. In both fields, soil acidification due to the repeated application of N fertilizers at a shallow soil depth as well as the accumulation of organic C lowered pH of the uppermost soil layer in NT compared to the deeper soil layers. The results indicated that even short-term NT can increase the labile P in clay soil. However, further studies are needed to assess the long-term changes in lability of surface soil P and, consequently, the possible need for readjustment of the fertilization level in NT.     

一种新型复合式生物流化反应器混合特性的研究

对新型蜂窝状断面复合生物流化反应器进行了液体循环速率和水力停留时间分布曲线的测定，实验表明新型反应器具有抗冲击负荷强，接近CSTR反应器的特点，反应器随气量增大、载体投加量减少和进水量减少而更近似于CSTR反应器，通过理论分析，证明了影响液体循环速率的参数主要有气体流量(气含率)、反应器沿程和局部阻力系数以及Ad/Ar，并且得出液体循环速率与反应器高度的0．5次方成正比。     

洗涤剂磷对日本三角涡虫生长的影响

观察了含磷量不同的洗衣粉溶液对日本三角涡虫生长的影响。结果表明:无论洗衣粉含磷量高低对日本三角涡虫生长均有毒害影响,且高磷洗衣粉对涡虫的毒害远大于低磷洗衣粉,磷量的增加与涡虫死亡率呈正相关。实验中,自来水对照组对涡虫生长无影响。     

全国土壤侵蚀量估算及其在吸附态氮磷流失量匡算中的应用

应用土壤流失方程(USLE),根据我国土壤水力侵蚀分类分级标准,建立了大尺度区域土壤侵蚀量的估算模型;基于GIS技术平台,利用土壤普查数据,构建了全国表层土壤氮磷含量数据库,完成了2000年全国境内水土流失影响下吸附态氮磷的流失量估算.经数据合理性分析验证后得出以下结论:(1)全国因水土流失引发的吸附态氮素和磷素的流失总量分别达到104.22×104t和34.65×104t;(2)长江、珠江和黄河三大流域的吸附态氮、磷流失量之和分别占全国总量的83%和89%,单位面积(1km2)吸附态氮、磷的流失量分别介于6.0×10-4～0.53t和2.1×10-4～0.13t之间;(3)吸附态氮的重点流失区主要分布在长江中上游水土易蚀区、黄河中游沟壑区、西辽河上游区、珠江流域红水河、西江等上游区以及怒江、澜沧江下游区.     

Enhanced activity of ZnS(111) by N/Cu co-doping:Accelerated degradation of organic pollutants under visible light

High-efficiency photocatalysts are of great significance for the application of photocatalytic technology in water treatment.In this study,N/Cu co-doped ZnS nanosphere photocatalys(N/Cu-ZnS) is synthesized by a hydrothermal method for the first time.After doping,the tex ture of nanosphere becomes loose,the nanometer diameter is reduced,making the specific surface area of catalyst increased from 34.73 to 101.59 m²/g.The characterization results show that more ZnS (111) crystal planes a...     

关于建设(开发)项目环境影响评价报告书编制两个版本的思考

为充分发挥环境影响评价报告书的作用，提出应在环境影响报告书技术版的基础上编制一个面向领导决策者和公众的参考版。并就参考版的主要内容及编制应注意的问题进行了概述。