水中痕量有机污染物的富集与分离方法

综述水中有机污染物富集与分离方法的原理、优缺点、适用条件 ,探讨各种分析方法的检测限和灵敏度     

新疆典型城-郊-乡梯度带土壤微量元素空间分布与来源

从新疆某地典型城-郊-乡梯度带采集了77个表层(0~20 cm)土壤样品,基于GIS技术与多元统计分析方法,研究各梯度带表层土壤中Hg、As、V、Co、Ni、Cu、Zn、Cd、Pb和Sb等10种微量元素的空间分布特征与主要来源。结果表明:Hg元素在城区、郊区和乡村表层土壤中的平均含量均超出研究区土壤背景值,As元素在城区和郊区表层土壤中的平均含量超出背景值,Zn和Pb元素在城区表层土壤中的平均含量超出背景值,其余元素在3个梯度带表层土壤中的平均含量均低于相应的背景值。研究区表层土壤中,V、Co、Ni、Zn、Cd、Pb和Sb等7种元素的空间分布格局基本相似,均呈现沿城市化梯度带分布的地带性格局;As、Cu和Hg等3种元素的空间分布呈现岛状格局。来源分析结果表明,各梯度带表层土壤中的微量元素的来源各不相同。     

煤矸石中元素Ba、Ni、Sr的淋溶析出

对安徽淮南煤矸石进行了成分分析和淋溶析出实验研究,结果表明：微量元素Ba、Ni、Sr在矸石山底部的含量高于新鲜样品,由此得出这三种元素对周围土壤及水环境的影响可能是有限的。     

武都碾压混凝土重力坝抗震分析与安全评价

武都水库是四川省江油市境内的涪江干流上的大(1)型水利工程。汶川8级地震中,武都水库工程紧邻震中区附近,并正处于施工高峰期,大地震对武都水库工程已建和在建的40多个项目均有不同程度的损坏。分别采用水工建筑物抗震设计规范给定的地震动参数值和地震后复核确定的地震动参数值,对武都大坝进行抗震分析与安全性评价。计算表明,当设计设防加速度256cm/s2时,按规范规定的悬臂梁法进行抗震计算时,均满足现行抗震规范的要求。按平面有限元计算时局部拉应力超出规范的允许值,建议挡水坝段下游坝面折坡附近以及溢流坝段在导墙与边墩交接处附近提高混凝土的强度等级。鉴于坝踵、坝址部位局部范围内仍有较大水平的拉应力,建议自建基面的一定高度内应确保混凝土的浇筑质量,以确保大坝的抗震强度安全。     

邀山阁游客流量控制研究

邀山阁是一座4层砖石结构楼阁,目前西北角墙体倾斜严重且墙体、石柱存在竖向裂缝。基于保护邀山阁的需要,应用等效体积单元(RVE)进行墙体的有限元分析,通过调整弹性模量和优化有限元模型来模拟砌体带裂缝时的工作状态;在应力值及其变化值比较大的关键部位选取了26个控制点,进行应力包络分析;在合理的安全系数和游客荷载最不利工况下,得到了邀山阁游客的合理控制数量。本研究将有益于古建筑的长期保护和合理开发利用。     

钢筋混凝土箱型高墩双向拟静力试验研究

随着高墩大跨桥梁的广泛应用,其抗震问题也越来越突出。本文主要考虑轴压比、长细比的影响,进行了6个钢筋混凝土薄壁箱型高墩缩尺模型的双向拟静力试验,以及反复荷载作用下的非线性分析。研究表明:①钢筋混凝土薄壁箱型高墩柱在多维荷载共同作用下,主要发生典型的弯曲破坏,但剪切作用也不容忽视;②墩柱的破坏受到不同方向耦合作用的显著影响,尤其是抗弯刚度小的一侧受到的影响更大,较早就出现开裂,提前进入塑性发展阶段;③非线性有限元计算的滞回曲线、骨架曲线等与试验结果基本吻合;④建立了考虑轴压比、长细比影响的钢筋混凝土薄壁箱型高墩的双向荷载—位移恢复力模型,该模型基本能够反映钢筋混凝土薄壁箱型高墩的抗震性能,可供钢筋混凝土箱型高墩柱及高墩桥梁结构的抗震设计和动力计算参考。     

Emission control for precursors causing acid rain (V): Improvement of acid soil with the bio-briquette combustion ash

The bio-briquette technique which mixes coal, biomass and sulfur fixation agent and bio-briquettes under 3-5 t/cm^2 line pressure has aroused people‘s attention in view of controlling the air pollution and the acid rain. In this paper, the physicochemical properties of bio-briquette and its ash were investigated. And the acid soil was improved by the bio-briquette combustion ash, which contained nutritive substances such as P, N, K and had the acid-neutralizing capacity(ANC). The pH, EC, effective nutrient elements(Ca, Mg, K, P and N), heavy metal elements(AI, Cu, Cd, Cr, Zn and Mn) and acid-neutralizing capacity change of ash-added soils within the range of 0-10%, were also studied. Specially, when 5% bio-briquette combustion ash was added to the tested soil, the content of the effective elements such as Ca, Mg and K rose by 100 times, ? times and twice, respectively. The total nitrogen also increased by about twice. The results showed the oxyanions such as that of AI, Cu, Cd, Cr, Zn and Mn were not potentially dangerous, because they were about the same as the averages of them in Chinese soil. It is shown that the ANC became stronger, though the ANC hardly increases in the ash-added soil. On the basis of the evaluation indices, it is concluded that the best mixture ratio is to add 2.5%--8% of the bio-briquette combustion ash to the tested soil.     

Occurrence and volatility of several trace elements in pulverized coal boiler

The contents of eight trace elements(Mn, Cr, Pb, As, Se, Zn, Cd, Hg) in raw coal, bottom ash and fly ash were measured in a 220 t/h pulverized coal boiler. Factors affecting distribution of trace elements were investigated, including fly ash diameter, furnace temperature, oxygen content and trace elements‘ characters. One coefficient of Meij was also improved to more directly show element enrichment in combustion products. These elements may be classified into three groups according to their distribution: Group 1. Hg, which is very volatile. Group 2: Pb, Zn, Cd, which are partially volatile. Group 3: Mn, which is hardly volatile. Se may be located between groups 1 and 2. Cr has properties of both group ! and 3. In addition, the smaller diameter of fly ash, the more relative enrichment of trace elements (except Mn). The fly ash showed different adsorption mechanisms of trace elements and the volatilization of trace elements rises with furnace temperature. Relative enrichments of trace elements(except Mn and Cr) in fly ash are larger than that in bottom ash. Low oxygen content can not always improve the volatilization of trace elements. Pb is easier to form chloride than Cd during coal combustion. Trace elements should be classified in accordance with factors.     

石化企业应急救援能力评估研究

随着应急能力建设逐步引起我国各行各业的重视,越来越多的石化企业己经开始加大对应急能力建设工作的力度,以尽可能的减少生产事故所带来的损失。作为石化企业应急能力建设的重要组成部分,石化企业生产事故应急救援能力的评价研究具有十分重要的理论和实践意义。本文首先对石化企业生产及事故特点和石化企业应急能力进行了详细的剖析,初步构建了石化企业生产事故应急能力评价指标体系。进而根据物元可拓性理论,结合石化企业的实际情况,运用可拓评判方法建立石化企业应急救援能力综合评判的模型,给出了评价步骤,最终确定企业的生产事故应急能力等级,从而对企业持续改进应急能力建设提供一定的参考。研究结果表明,该方法可应用于多层次的工程风险评价问题,从而为石化工程项目风险管理提供了一种有效的分析方法。     

废弃电器电子产品POPs/PTS减排环境管理实践研究

全球环境基金(GEF)"通过环境无害化管理减少电器电子产品的生命周期内持久性有机污染物和持久性有毒化学品(POPs/PTS)的排放全额示范项目"湖北省作为项目示范省之一.三家废弃电器电子产品拆解企业,分别开展了废弃电器电子产品拆解技术示范、湿法废弃印刷电路板处置BAT/BEP技术示范、利用再生铅连续熔炼炉协同处置阴极射线管含铅锥玻璃项目技术示范.电子废弃物全自动化分类与拆解生产线,为电子废弃物绿色循环与资源化提供了示范模式.