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311.
Kocí V Ocelka T Dragoun D Vit M Grabic R Sváb M 《Environmental science and pollution research international》2007,14(2):94-101
Background, Aim and Scope
The article is focused on dioxin, furan, PCB and organochlorine pesticide monitoring in the surface waters of the Central
European, protected natural reserve Krivoklatsko, under the UNESCO programme Man and Biosphere. Persistent compounds are presently
transported via different means throughout the entire world. This contamination varies significantly between sites. This raises
the question of what constitutes the naturally occurring background levels of POPs in natural, unpolluted areas, but which
are close to industrialised regions. Information of real background POP contamination can be of high value for risk assessment
management of those sites evidently polluted and for the defining of de-contamination limits.
Preserved areas should not be seen as isolated regions in which the impacts of human activities and natural factors are either
unexpected or overlooked. Every ambient region, even those protected by a law or other means, are still closely connected
to neighbouring human developed and impacted areas, and are therefore subject to this anthropogenic contamination. These areas
adjacent to natural reserves are sources of diverse substances, via entry of air, water, soil and/or biota. After an extended
period of industrial activities, organochlorine pollutants, even those emitted in trace concentrations have reached detectable
levels. For future research and for the assessment of environmental changes, present levels of contamination would be of high
importance. This work publishes data of the contamination with organochlorine pollutants of this natural region, where biodiversity
and ecological functions are of the highest order.
Materials and Methods:
Semipermeable membrane devices (SPMDs) were utilised as the sampling system. SPMDs were deployed in two small creeks and one
water reservoir selected in the central part of the Krivoklatsko Natural Reserve, where it could be expected that any possible
contamination by POPs would be lowest. The exposed SPMDs were analysed both for chemical contents of POPs and for toxicity
properties. The chemical analyses of dibenzo-dioxins, dibenzo-furans, PCBs and OCPs were analysed by GC/MS/MS on GCQ or PolarisQ
(Thermoquest). Toxicity bioassays were performed on the alga Desmodesmus subspicatus, bacteria Vibrio fischeri and crustacean
Daphnia magna. All toxicity data were expressed as the effective volume Vtox. Vtox is a toxicity parameter, the determination
of which is independent of SPMD deployment time and pre-treatment dilution (unlike, for example, the EC50 of the SPMD extract).
Results:
The following chemical parameters were monitored: 1) tetra, penta, hexa and hepta dibenzo-p-dioxins and furans; 2) all those
detectable from tri- through deca-polychloriated biphenyls (PCBs) and 3) a group of organochlorine pesticides: hexachlorobenzene
and isomers of hexachlorocyclohexane, DDE, DDD and DDT. The concentrations of dioxins and furans on the assessed sites varied
from under detection levels up to 7 pg.l-1; PCBs were detected in a sum concentration up to 2.8 ng.l-1; and organochlorine
pesticides up to 346 pg.l-1. The responses of bioassays used were very low, with the values obtained for Vtox being under
0.03 l/d.
Discussion:
Toxicity testing showed no toxicity responses, demonstrating that the system used is in coherence with the ecological status
of the assessed sites. Values of Vtox were under the critical value – showing no toxicity. The PCA of chemical analysis data
and toxicity responses resulted in no correlations between these two groups of parameters. This demonstrated that the present
level of contamination has had no direct adverse effects on the biota.
Conclusions:
The concentration values of six EPA-listed, toxic dioxins and sums of tetra-hepta dioxins; nine EPA toxic dibenzofurans and
the sums of tetra-hepta bibenzofurans are presented together with all tri-deka PCBs and organochlorine pesticides (alfa-,
beta-, gama-, delta-HCH, HCB, opDDE, ppDDE, opDDD, ppDDD, opDDT, ppDDT). These values represent possible current regional
natural background values of these substances monitored within the Central European region, with no recorded adverse effects
on the freshwater ecosystem (up until the present time).
Recommendations and Perspectives:
Assessment of dioxins, furans and other organochlorine compounds within natural reserves can be important for the monitoring
of human-induced impacts on preserved areas. No systematic monitoring of these substances in areas not directly affected by
industry has generally been realised. There is a paucity of data of the presence of any of these substances within natural
regions. Further monitoring of contamination of both soil and biota by dioxins and furans in preserve regions is needed and
can be used for future monitoring of man-made activities and/or accidents.
Semipermeable membrane devices proved to be a very good sampling system for the monitoring of trace concentrations of ambient
organochlorine compounds. Toxicity evaluation using the Vtox concept demonstrated that those localities assessed expressed
no toxicity. 相似文献
312.
阀门的操作不当,可以导致安全事故的发生.通过数字减影技术,并考虑了背景模型对背景变化的响应速度和背景模型对运动目标要有较强的抗干扰能力等因素,研究开发出基于数字减影技术的阀门动态监控系统,对设备的安全运行起到一定的保障作用. 相似文献
313.
2013年北京市不同方位PM2.5背景浓度研究 总被引:2,自引:2,他引:0
利用2013年北京市6个站点PM_(2.5)浓度及5个站点气象监测数据,综合采用数理统计、物理识别、数值模拟的方法分析了2013年北京市不同方位PM_(2.5)的背景值.结果表明,2013年北京市西北、东北、东、东南、南、西南这6个方向边界点位的背景浓度在40.3~85.3μg·m-3之间,按由低到高顺序依次为密云水库、八达岭、东高村、榆垡、永乐店和琉璃河;2013年北京市PM_(2.5)北风时段背景值最低,西风时段次之,南风、东风时段明显偏高,不同风向下背景浓度的平均值分别在6.5~27.9、22.4~73.4、67.2~91.7、40.7~116.1μg·m-3之间,表现出北京东、南方向PM_(2.5)背景浓度较高分布特点;模拟的2013年北京市PM_(2.5)背景浓度空间分布呈现出南高北低的特征,周边区域对北京市PM_(2.5)背景浓度空间分布影响显著. 相似文献
314.
依托国家海洋局三沙海洋环境监测中心站,基于激光大气温室气体分析仪(GLA331-GGA),搭建了一套全自动、连续、高精度观测大气CH4的观测系统.通过气团后向轨迹输送特征,结合数值统计方法(局部近似回归法),对西沙永兴岛区域2013年12月~2017年11月期间的观测数据进行了数据筛分和分析.结果显示:西沙海域大气CH4季节变化与北半球大气本底变化状况类似,冬季高、夏季低,年平均增长率约为11.9×10-9,年平均季节振幅为81.1×10-9;其日变化呈现中午低、凌晨高的单周期正弦变化特征;该区域风场数据和气团后向轨迹分析表明:季风是影响该区域CH4浓度变化的最主要因素. 相似文献
315.
认为节约型社会的理论前提和基础有生态政治理论、环境资源承载能力理论、资源生态经济理论、资源生态化和环境资源化理论等。对节约型社会的目标、节约型社会的理念、基本原则等进行了探讨。对节约型社会的法律问题进行了界定。 相似文献
316.
317.
A background precipitation in Lijiang, China was investigated. Results showed that the chemical composition of atmospheric background precipitation mainly comes from fly ash and continental atmospheric transfer, and does not have any obvious correlation with oceanic aerosol, taking Amsterdam in the Pacific ocean and St. Georges in the Atlantic ocean and Katherine,Australia as examples for analysis. 相似文献
318.
319.
320.
神农架大九湖亚高山湿地环境背景与生态恢复 总被引:4,自引:1,他引:3
针对神农架林区大九湖亚高山湿地退化问题,在联合科学考察基础上,分析区域环境背景状况及生态退化原因,提出湿地保护、利用和生态恢复相关建议。调查内容包括:区域地形地貌状况,地质构造、地层、岩溶发育规律和落水洞分布状况,河流水系的分布、流量变化和水质状况,沼生植被的分布和演替规律,湿地演变过程及人类活动对湿地影响等方面。〖JP2〗研究发现:神农架大九湖湿地演变和土地利用结构变化受水利工程直接影响,1986年以来大规模开挖人工沟渠、疏通落水孔、排干沼泽开垦种植等活动,是湿地生态环境退化的重要因素;湿地退化主要反映为湖泊水面消失、沼泽湿地退化、湿地生态系统向陆生生态系统演化,生物多样性减少,泥炭资源遭受破坏,水质下降。根据调查结果,从原则、措施方案、管理机构、产业、资金等方面对大九湖湿地的保护、利用和生态恢复提出建议。 相似文献