Contamination and source differentiation of Pb in park soils along an urban-rural gradient in Shanghai

Urban soil Pb contamination is a great human health risk. Lead distribution and source in topsoils from 14 parks in Shanghai, China were investigated along an urban-rural gradient. Topsoils were contaminated averagely with 65 mg Pb kg⁻¹, 2.5 times higher than local soil background concentrations. HCl-extracts contained more anthropogenic Pb signatures than total sample digests as revealed by the higher ^207/206Pb and ^208/206Pb ratios in extracts (0.8613 ± 0.0094 and 2.1085 ± 0.0121 versus total digests 0.8575 ± 0.0098 and 2.0959 ± 0.0116). This suggests a higher sensitivity of HCl-extraction than total digestion in identifying anthropogenic Pb sources. Coal combustion emission was identified as the major anthropogenic Pb source (averagely 47%) while leaded gasoline emission contributed 12% overall. Urbanization effects were observed by total Pb content and anthropogenic Pb contribution. This study suggests that to reduce Pb contamination, Shanghai might have to change its energy composition to clean energy.     

A Comparison of Single and Multiple Habitat Protocols for Collecting Macroinvertebrates in Wadeable Streams1

Abstract: In 2003, we compared two benthic macroinvertebrate sampling methods that are used for rapid biological assessment of wadeable streams. A single habitat method using kick sampling in riffles and runs was compared to a multiple habitat method that sampled all available habitats in proportion of occurrence. Both methods were performed side‐by‐side at 41 sites in lower gradient streams of the Piedmont and Northern Piedmont ecoregions of the United States, where riffle habitat is less abundant. Differences in sampling methods were examined using similarity indices, two multimetric indices [the family‐level Virginia Stream Condition Index (VSCI) and the species‐level Macroinvertebrate Biotic Integrity Index (MBII)], their component metrics, and bioassessment endpoints based on each index. Index scores were highly correlated between single and multiple habitat field methods, and sampling method comparability, based on comparison of similarities between and within sampling methods, was particularly high for species level data. The VSCI scores and values of most of its component metrics were not significantly higher for one particular method, but relationships between single and multiple habitat values were highly variable for percent Ephemeroptera, percent chironomids, and percent Plecoptera and Trichoptera (Hydropsychidae excluded). A similar level of variability in the relationship was observed for the MBII and most of its metrics, but Ephemeroptera richness, percent individuals in the dominant five taxa, and Hilsenhoff Biotic Index scores all exhibited differences in values between single and multiple habitat field methods. When applied to multiple habitat samples, the MBII exhibited greater precision, higher index scores, and higher assessment categories than when applied to single habitat samples at the same sites. In streams with limited or no riffle habitats, the multiple habitat method should provide an adequate sample for biological assessment, and at sites with abundant riffle habitat, little difference would be expected between the single and multiple habitat field methods. Thus, in geographic areas with a wide variety of stream types, the multiple habitat method may be more desirable. Even so, the variability in the relationship between single and multiple habitat methods indicates that the data are not interchangeable, and we suggest that any change in sampling method should be accompanied by a recalibration of any existing assessment tool (e.g., multimetric index) with data collected using the new method, regardless of taxonomic level.     

Optimal power flow model incorporating wind,solar, and bundled solar-thermal power in the restructured Indian power system

A new optimal power flow model for wind, solar, and solar-thermal bundled power scheduling and dispatch is proposed, incorporating the deviation incentive/penalty charges for renewable energy introduced in India. The multiobjective function is solved using the flower pollination algorithm; the scheme is successfully tested on the IEEE 30-bus and Indian utility 30-bus systems. The forecasting error constraints introduced in renewable energy scheduling and dispatch are demonstrated to be beneficial in several aspects. Solar-thermal bundling is shown to create win-win situations for thermal and solar generators. The effectiveness of the flower pollination algorithm in solving optimal power flow models is proved.     

低压直流电电解剩余活性污泥

采用低压直流电电解剩余活性污泥,优化了支持电解质的种类、加入量及电压梯度等工艺条件,并考察了在最佳工艺条件下SS去除率、污泥中有机物的质量分数（以VSS/SS计）、污泥pH及污泥沉降性能随电解时间的变化情况。实验结果表明,低压直流电电解污泥的最佳工艺条件为：电压梯度7 V/cm;支持电解质Na₂SO₄加入量0.4.0 mmol/g（以每克干污泥计）。在最佳工艺条件下电解pH为5.8、SS=（7 850 ±200）mg/L、VSS=（6 150±150）mg/L、溶解性化学需氧量（SCOD）为（61.2 ±20）mg/L的污泥,电解60 min时污泥的SCOD最大,达393.3 mg/L,SS去除率达14.4%,VSS/SS为58.5%,污泥pH为3.1。电解后污泥中微生物的细胞结构已不完整,污泥絮体被严重破坏。电解时间越长,污泥的沉降速率越快。     

Application of an early warning indicator and CaO to maximize the time–space-yield of an completely mixed waste digester using rape seed oil as co-substrate

In order to increase the organic loading rate (OLR) and hereby the performance of biogas plants an early warning indicator (EWI-VFA/Ca) was applied in a laboratory-scale biogas digester to control process stability and to steer additive dosing. As soon as the EWI-VFA/Ca indicated the change from stable to instable process conditions, calcium oxide was charged as a countermeasure to raise the pH and to bind long-chain fatty acids (LCFAs) by formation of aggregates. An interval of eight days between two increases of the OLR, which corresponded to 38% of the hydraulic residence time (HRT), was sufficient for process adaptation. An OLR increase by a factor of three within six weeks was successfully used for biogas production. The OLR was increased to 9.5 kg volatile solids (VS) m^?3 d^?1 with up to 87% of fat. The high loading rates affected neither the microbial community negatively nor the biogas production process. Despite the increase of the organic load to high rates, methane production yielded almost its optimum, amounting to 0.9 m³ (kg VS)^?1. Beneath several uncharacterized members of the phylum Firmicutes mostly belonging to the family Clostridiaceae, a Syntrophomonas-like organism was identified that is known to live in a syntrophic relationship to methanogenic archaea. Within the methanogenic group, microorganisms affiliated to Methanosarcina, Methanoculleus and Methanobacterium dominated the community.     

沱江源森林群落生物多样性垂直格局研究

在野外样带调查的基础上,分析了沱江源头九顶山植被生物多样性随海拔而变化的规律,并简要分析了植被生物多样性垂直格局的影响因子。从河谷到林线,乔木占据群落上层,其郁闭度对林下灌草层群落发育影响很大,生物多样性体现出乔木层与灌草层的相互关系：乔木盖度大的群落其灌木和草本层稀疏,而盖度小的次生林和林线上的高海拔区域灌木和草本种类与个体都迅速增加。多样性指数Hill指数及N1、N2指数变化规律基本相似：林线以下乔木层多样性指数最高,灌木层次之,草本层多样性指数最小,尤其在中度海拔体现明显,海拔3 500 m以上,草本多样性指数最高,灌木次之,而乔木已退出竞争。     

Diffusive gradient in thin FILMS (DGT) compared with soil solution and labile uranium fraction for predicting uranium bioavailability to ryegrass

The usefulness of uranium concentration in soil solution or recovered by selective extraction as unequivocal bioavailability indices for uranium uptake by plants is still unclear. The aim of the present study was to test if the uranium concentration measured by the diffusive gradient in thin films (DGT) technique is a relevant substitute for plant uranium availability in comparison to uranium concentration in the soil solution or uranium recovered by ammonium acetate. Ryegrass (Lolium perenne L. var. Melvina) is grown in greenhouse on a range of uranium spiked soils. The DGT-recovered uranium concentration (C_DGT) was correlated with uranium concentration in the soil solution or with uranium recovered by ammonium acetate extraction. Plant uptake was better predicted by the summed soil solution concentrations of UO₂²⁺, uranyl carbonate complexes and UO₂PO₄⁻. The DGT technique did not provide significant advantages over conventional methods to predict uranium uptake by plants.     

城市污水分段进水A/O脱氮工艺试验研究

对分段进水A/O脱氮工艺技术的经济性进行了分析:与单级A/O工艺相比,该工艺在运行中无需混合液内回流、反应器中平均污泥浓度高,具有脱氮效率高、基建投资和运行费用省等特点.并以西安市北石桥污水净化中心城市污水为处理对象,在有效容积为1.2 m3的四级分段进水A/O反应器中进行了试验研究.试验在各级进水流量分配比例依次为40%,30%,20%和10%,以及污泥回流比为50%的工况下,连续运转了70 d.结果表明:采用分段进水A/O脱氮工艺处理城市污水具有较强的耐冲击负荷能力,出水水质稳定.在水力停留时间为7.5 h,污泥龄为15 d时,其COD_Cr,NH₄++-N和TN的去除率分别为93%,95.8%和68.5%;反应器中的平均污泥浓度比单级A/O工艺提高约30%以上.      

基于梯度塑性理论的岩石等间距破坏分析

等间距断裂属应变局部化范畴,这是传统的宏观连续介质理论无法预测和解释的。应变梯度理论是传统塑性理论的推广和完善,本文在屈服函数中引用应变梯度项分析了岩石等间距破坏问题。首先建立了平面应力状态下应变梯度塑性理论模型,通过解析岩样边界在水平压应力作用下的塑性应变场,得出其曲面的分布具有等间距规律,其网络的分布格局及幅值大小受岩样尺度、边界应力、降模量等多种因素的影响。这一结论不仅与一些文献结果相吻合,而且说明用梯度塑性理论能够近似描述等间距现象。本文对深入研究等间距断裂提供了一个新思路。     

低渗透非达西流场中的一维溶质运移模拟

为了准确地研究低渗介质中地下水污染问题,在充分考虑地下水在低渗介质中渗流时存在启动压力梯度和动边界的基础上,建立了低渗介质中地下水污染和地下水渗流的耦合数学模型。采用有限差分法和混合有限分析法对耦合模型进行数值求解,并分析了启动压力梯度对地下水污染浓度的影响。结果表明启动压力梯度对地下水污染浓度的分布有着重要的影响,在研究低渗介质中的污染问题时不容忽视。